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Characterization of W-Ta-N hard films synthesized by direct current magnetron sputtering
Luleå University of Technology, Department of Applied Physics and Mechanical Engineering. Key Laboratory of Materials Physics, Institute of Solid State Physics, Chinese Academy of Sciences, China.
Key Laboratory of Materials Physics, Institute of Solid State Physics, Chinese Academy of Sciences, China.
Key Laboratory of Materials Physics, Institute of Solid State Physics, Chinese Academy of Sciences, China.
Key Laboratory of Materials Physics, Institute of Solid State Physics, Chinese Academy of Sciences, China.
2013 (English)In: Surface & Coatings Technology, ISSN 0257-8972, E-ISSN 1879-3347, Vol. 231, p. 19-23Article in journal (Refereed) Published
Abstract [en]

WTaN hard films with Ta/(W+Ta)=46at.% were deposited on single crystal Si (111) substrates using direct current magnetron sputtering. The effect of nitrogen partial pressure (pN2) on crystal structure, surface topography, adhesion strength, and hardness of WTaN films was investigated. With increasing pN2, the phase composition changes from pure fcc W-Ta-N phase to a mixture of fcc WTaN phase and hexagonal δ-W(Ta)N phase, and then to pure hexagonal δ-W(Ta)N phase; the average grain size decreases monotonously; the surface becomes more and more smooth; the hardness initially increases and then decreases after passing a maximum of 41GPa at pN2=0.5Pa, while the adhesion strength varies in an opposite trend to the hardness. The maximum hardness could be due to the combined effect of reduced crystallite size and the coexistence of two phases.

Place, publisher, year, edition, pages
2013. Vol. 231, p. 19-23
Keywords [en]
Adhesion strength, AFM, Hard films, Hardness, Magnetron sputtering
National Category
Materials Chemistry
Identifiers
URN: urn:nbn:se:ltu:diva-102287DOI: 10.1016/j.surfcoat.2012.06.082ISI: 000328094200006Scopus ID: 2-s2.0-84882859208OAI: oai:DiVA.org:ltu-102287DiVA, id: diva2:1809568
Note

Funder: National Natural Science Foundation of China (51101152, 51101152);

Available from: 2023-11-04 Created: 2023-11-04 Last updated: 2024-03-07Bibliographically approved

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Yang, J. F.

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