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Synthesis, structural and multinuclear natural abundance (C-13, P-31, Pt-195) CP/MAS NMR studies of crystalline O,O '-dialkyldithiophosphate platinum(II) complexes
Luleå University of Technology, Department of Civil, Environmental and Natural Resources Engineering, Sustainable Process Engineering.
Russian Adademy of Sciences.
Russian Adademy of Sciences.
Russian Adademy of Sciences.
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2008 (English)In: Russian journal of coordination chemistry, ISSN 1070-3284, E-ISSN 1608-3318, Vol. 34, no 8, p. 584-593Article in journal (Refereed) Published
Abstract [en]

Platinum(II) O,O'-dicyclohexyl dithiophosphate [Pt{S2P(O-cyclo-C6H11)(2)}(2)] (I) and platinum(II) O,O'-diisopropyl dithiophosphate [Pt{S2P(O-iso-C3H7)(2)}(2)] (II) complexes were obtained and studied by solidstate C-13, P-31, and Pt-195 CP/MAS NMR spectroscopy. The dithiophosphate (Dtph) ligands in molecular structure I were found to be coordinated by platinum in S,S'-bidentate fashion to form the planar chromophore [PtS4] (single-crystal X-ray diffraction data). For complex II, a new alpha-form (alpha-II) was obtained and identified by P-31 MAS NMR spectroscopy. The P-31 chemical shift anisotropy delta(aniso) and the asymmetry parameter eta of the P-31 chemical shift tensor were calculated from the whole MAS spectra.

Place, publisher, year, edition, pages
2008. Vol. 34, no 8, p. 584-593
National Category
Physical Chemistry
Research subject
Chemistry of Interfaces
Identifiers
URN: urn:nbn:se:ltu:diva-3025DOI: 10.1134/S1070328408080058ISI: 000258285800005Scopus ID: 2-s2.0-49249083644Local ID: 0c645b50-7049-11dd-8151-000ea68e967bOAI: oai:DiVA.org:ltu-3025DiVA, id: diva2:975880
Note
Validerad; 2008; 20080822 (bajo)Available from: 2016-09-29 Created: 2016-09-29 Last updated: 2023-09-05Bibliographically approved

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Ivanov, Alexander V.Antzutkin, Oleg

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