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Preparation and characterization of hollow fibers of silicalite-1
Luleå tekniska universitet.
Luleå University of Technology, Department of Civil, Environmental and Natural Resources Engineering, Sustainable Process Engineering.
Luleå tekniska universitet.
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1996 (English)In: Zeolites, ISSN 0144-2449, Vol. 17, no 5-6, p. 408-415Article in journal (Refereed) Published
Abstract [en]

Hollow fibers consisting solely of silicalite-1 were prepared by a novel method consisting of four basic steps. Carbon fibers were first surface modified to facilitate adsorption of colloidal seed crystals of silicalite-1. Such particles were then adsorbed as a monolayer on the fiber surface and induced to grow into a continuous film of intergrown crystals of silicalite-1. Finally, the carbon fiber used as a template was removed by calcination in air, yielding hollow fibers of silicalite-1. Hollow fibers were prepared in two experimental series employing different synthesis conditions resulting in two different modes of growth. The first experimental series was performed with a clear homogeneous TPAOH/silica solution crystallizing at 100°C, and the second series with a NaOH-TPABr/silica gel crystallizing at 150°C. Materials produced in the first series showed a smooth and homogeneous surface and a relatively uniform fiber wall with a final thickness of 1.1 μm. In these materials the film was formed by crystals growing outward from the surface of the carbon fiber. Materials produced in the second series were less uniform with a final thickness of the fiber wall of about 3.2 μm. The crystal growth in these materials appeared to take place both in an inward and outward direction starting from the seed crystals adsorbed on the carbon fiber. The hollow fibers prepared were characterized by SEM, XRD, FT i.r., and nitrogen adsorption measurements.

Place, publisher, year, edition, pages
1996. Vol. 17, no 5-6, p. 408-415
National Category
Chemical Process Engineering
Research subject
Chemical Technology
Identifiers
URN: urn:nbn:se:ltu:diva-3585DOI: 10.1016/S0144-2449(96)00089-9ISI: A1996VP43300001Local ID: 1698d250-a5fb-11db-9811-000ea68e967bOAI: oai:DiVA.org:ltu-3585DiVA, id: diva2:976443
Note

Godkänd; 1996; 20070117 (bajo)

Available from: 2016-09-29 Created: 2016-09-29 Last updated: 2018-07-10Bibliographically approved

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Hedlund, JonasSterte, Johan

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