Light-induced yellowing of selectively 13C-enriched dehydrogenation polymers (DHPs). Part 2. NMR assignments and photoyellowing of aromatic ring 1-, 3-, 4-, and 5-13C DHPsShow others and affiliations
2004 (English)In: Nordic Pulp & Paper Research Journal, ISSN 0283-2631, E-ISSN 2000-0669, Vol. 19, no 1, p. 44-52Article in journal (Refereed) Published
Abstract [en]
Light-induced yellowing of lignocellulosic materials has been studied using 13C-enriched DHP (dehydrogenation polymer), selectively 13C-enriched at positions 1, 3, 4, and 5 in the aromatic ring, and quantitative solution state 13C NMR spectroscopy. The NMR study confirmed the results of previous studies using side-chain labeled DHP, mainly that coniferyl alcohol end groups are degraded with the subsequent formation of α-carbonylic structures, e.g. vanillin end groups. The developed technique renders the potential to follow chemical changes of aromatic carbons 1, 3, 4, and 5, independently from each other. Although a drastic photoyellowing of the sheets was observed, definitive chemical shifts corresponding to quinoid carbons could not be discerned in the spectra. The reasons for this may be that the amount of quinoid carbons formed was too low to be detected, with the experimental setup used, or that the quinoid photo-products, if formed, were not extractable with the solvent used or had reacted further forming non-quinoid structures.
Place, publisher, year, edition, pages
2004. Vol. 19, no 1, p. 44-52
National Category
Bio Materials
Research subject
Wood Physics
Identifiers
URN: urn:nbn:se:ltu:diva-3733DOI: 10.3183/npprj-2004-19-01-p044-052ISI: 000220880800007Scopus ID: 2-s2.0-1942443161Local ID: 1914fcc0-0dc0-11dc-8745-000ea68e967bOAI: oai:DiVA.org:ltu-3733DiVA, id: diva2:976593
Note
Validerad; 2004; 20070529 (cira)
2016-09-292016-09-292022-01-14Bibliographically approved