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Molecular rotation in C70 at high pressures: a thermal conductivity study
1996 (English)In: Journal of Physics and Chemistry of Solids, ISSN 0022-3697, E-ISSN 1879-2553, Vol. 57, no 9, p. 1371-1375Article in journal (Refereed) Published
Abstract [en]

We have measured the thermal conductivity ε and the heat capacity per unit volume ρcp of highly pure C70 in the temperature interval 100-450 K under pressures up to 1 GPa. Anomalies indicating freezing of uniaxial molecular rotation were observed in λ and ρcp upon both cooling and increasing pressure. The phase boundary for this transition has an approximate slope dT/dp = 70 K Gpa-1. The temperature and pressure dependence of λ indicate a substantial amount of structural defects in the sample and strong metastability effects.

Place, publisher, year, edition, pages
1996. Vol. 57, no 9, p. 1371-1375
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Fysik
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URN: urn:nbn:se:ltu:diva-3958DOI: 10.1016/0022-3697(96)00030-3ISI: A1996VC87900026Scopus ID: 2-s2.0-0030241238Local ID: 1cda4ad0-f174-11db-bb1b-000ea68e967bOAI: oai:DiVA.org:ltu-3958DiVA, id: diva2:976820
Note
Upprättat; 1996; 20070423 (ysko)Available from: 2016-09-29 Created: 2016-09-29 Last updated: 2023-05-08Bibliographically approved

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