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Statistical associating fluid theory coupled with restricted primitive model to represent aqueous strong electrolytes: multiple-salt solutions
University of Wyoming.
University of Wyoming.
University of Wyoming.
2005 (English)In: Industrial & Engineering Chemistry Research, ISSN 0888-5885, E-ISSN 1520-5045, Vol. 44, p. 7584-7590Article in journal (Refereed) Published
Abstract [en]

Statistical associating fluid theory coupled with the restricted primitive model (SAFT1-RPM), previously proposed for representing single-salt solutions in water, is extended to multiple-salt solutions using a mixing rule for the hydrated diameter. A binary adjustable parameter in this mixing rule, for a pair of salts, is obtained from experimental osmotic coefficients of the corresponding ternary system. The ternary systems considered contain water and all pairs of NaCl, KCl, NaBr, and KBr. LiCl + NaCl and LiCl + KCl pairs are also correlated. The adjustable parameters are used to predict the density of the ternary systems with or without common ions, the solubility of two ternary systems, and the osmotic coefficient of a quaternary NaCl-KCl-LiCl-H2O solution.

Place, publisher, year, edition, pages
2005. Vol. 44, p. 7584-7590
National Category
Energy Engineering
Research subject
Energy Engineering
Identifiers
URN: urn:nbn:se:ltu:diva-4100DOI: 10.1021/ie050488iLocal ID: 1f862d50-0d77-11de-9d3e-000ea68e967bOAI: oai:DiVA.org:ltu-4100DiVA, id: diva2:976963
Note
Upprättat; 2005; 20090310 (xiajix)Available from: 2016-09-29 Created: 2016-09-29 Last updated: 2017-11-24Bibliographically approved

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Ji, Xiaoyan

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