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Trace metals and nutrients in Baltic Sea cyanobacteria: Internal and external fractions and potential use in nitrogen fixation
Department of Ecology, Environment and Plant Sciences, Stockholm University.
Luleå University of Technology, Department of Civil, Environmental and Natural Resources Engineering, Geosciences and Environmental Engineering.
Luleå University of Technology, Department of Civil, Environmental and Natural Resources Engineering, Geosciences and Environmental Engineering.ORCID iD: 0000-0003-2276-0564
2014 (English)In: Marine Chemistry, ISSN 0304-4203, E-ISSN 1872-7581, Vol. 158, p. 27-38Article in journal (Refereed) Published
Abstract [en]

Even though the availability of trace metals influences nitrogen fixation and growth of cyanobacteria, field data on their cellular metal composition are scarce. In this study, contents of Al, Ti, V, Mn, Fe, Co, Ni, Cu, Zn, Mo, Cd, and the major elements C, N, P and Si were studied in filamentous, nitrogen-fixing cyanobacteria sampled over the growth season March-October at two locations in the Baltic proper (years 2004 and 2007) and one location in the Bothnian Sea (2006). The Al and Ti contents indicated that lithogenic Fe was an important Fe fraction associated with Nodularia spumigena, but not with Aphanizomenon sp. Treatment with an oxalate-EDTA solution indicated that less than 5% of total Fe was adsorbed as oxides, but relatively high adsorbed fractions were found for Mn and Cu. Despite large variation in biomass and dissolved Fe concentrations, the Fe:C ratio of Aphanizomenon was highly consistent within years and across sampling stations (76 ± 13 μmol mol- 1 C, average ± 1SD), indicating growth controls other than Fe. Species-mixed samples corrected for lithogenic metals indicate similar Fe content in Nodularia as in Aphanizomenon. Calculations based on the use efficiency of Mo for N2 fixation indicates that most Mo in Nodularia and at least a third of the Mo in Aphanizomenon is used in nitrogenase, corresponding to 5-24% of the Fe content. The high Ni content suggests excess storage or extensive use in enzymes such as Ni superoxide dismutase or in Fe-dependent Ni-hydrogenases. The trace metal composition of the investigated Baltic cyanobacteria was similar to that reported for the oceanic genus Trichodesmium, suggesting common physiological requirements of these filamentous nitrogen-fixing cyanobacteria.

Place, publisher, year, edition, pages
2014. Vol. 158, p. 27-38
National Category
Geochemistry
Research subject
Applied Geology
Identifiers
URN: urn:nbn:se:ltu:diva-4504DOI: 10.1016/j.marchem.2013.11.002ISI: 000330912300004Scopus ID: 2-s2.0-84889648676Local ID: 271b610d-8121-4bf8-83b2-39bf4d1d6bd0OAI: oai:DiVA.org:ltu-4504DiVA, id: diva2:977378
Note
Validerad; 2014; 20131119 (andbra)Available from: 2016-09-29 Created: 2016-09-29 Last updated: 2018-07-10Bibliographically approved

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Gelting, JohanIngri, Johan

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