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Structure, EPR, and 13C and 15N NMR of Clathrates of Bis(diethyldithiocarbamato)pyridinezinc(II) and Bis(diethyldithiocarbamato)pyridinecopper(II) with 1,2-Dichloroethane
Luleå University of Technology, Department of Civil, Environmental and Natural Resources Engineering, Sustainable Process Engineering.
Arrhenius Laboratory, University of Stockholm.
Luleå University of Technology, Department of Civil, Environmental and Natural Resources Engineering, Sustainable Process Engineering.ORCID iD: 0000-0003-1067-7990
University of Linköping.
1999 (English)In: Russian Journal of Inorganic Chemistry, ISSN 0036-0236, E-ISSN 1531-8613, Vol. 44, no 10, p. 1605-1614Article in journal (Refereed) Published
Abstract [en]

The structural organization of the clathrates of bis(diethyldithiocarbamato)pyridinezinc(II) and -copper(II) with 1,2-dichloroethane, M(Edtc)2Py · L, was studied by EPR, high-resolution solid-state 13C and 15N NMR, and X-ray crystallography. The clathrates contain typical molecular channels and cavities, which accommodate chemically unbound dichloroethane molecules. At the molecular level, the geometry of the zinc and copper coordination polyhedra is intermediate between a trigonal bipyramid and a square pyramid. The ground state of the unpaired electron of copper(II) is a result of mixing the dx2-y2 and dz2 orbitals. The Edtc ligands incorporated in the zinc(II) clathrate are somewhat nonequivalent, both magnetically and structurally. The chlorine atoms of the 1,2-dichloroethane molecule are disordered over two structural positions with different occupancies, which may point to the occurrence of several conformations. The 13C and 15N NMR signals were assigned based on combined analysis of available structural and NMR data

Place, publisher, year, edition, pages
1999. Vol. 44, no 10, p. 1605-1614
National Category
Physical Chemistry
Research subject
Chemistry of Interfaces
Identifiers
URN: urn:nbn:se:ltu:diva-4673Local ID: 2a7530c0-3fb4-11de-bc0c-000ea68e967bOAI: oai:DiVA.org:ltu-4673DiVA, id: diva2:977547
Note
Godkänd; 1999; 20090513 (andbra)Available from: 2016-09-29 Created: 2016-09-29 Last updated: 2017-11-24Bibliographically approved

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Ivanov, Alexander V.Antzutkin, Oleg

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