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Binuclear cadmium dithiophosphate crystals: 13C, 31P, and 113Cd CP/MAS NMR studies
Luleå University of Technology, Department of Civil, Environmental and Natural Resources Engineering, Sustainable Process Engineering.
Luleå University of Technology, Department of Civil, Environmental and Natural Resources Engineering, Sustainable Process Engineering.ORCID iD: 0000-0003-1067-7990
Blagoveshchensk State Pedagogical University.
2003 (English)In: Russian journal of coordination chemistry, ISSN 1070-3284, E-ISSN 1608-3318, Vol. 29, no 5, p. 301-306Article in journal (Refereed) Published
Abstract [en]

31P NMR signals for the terminal and bridging ligands of the complexes were differentiated. The experimental NMR spectra show 31P-111,113Cd and 113Cd-31 P spin-spin couplings only for the terminal ligands. The chemical shift anisotropy δ and the asymmetry parameter η were calculated for 31P and 113Cd NMR signals. It was found that the 31P chemical shifts for the terminal and bridging dithiophosphato groups differ in anisotropy character.

Place, publisher, year, edition, pages
2003. Vol. 29, no 5, p. 301-306
National Category
Physical Chemistry
Research subject
Chemistry of Interfaces
Identifiers
URN: urn:nbn:se:ltu:diva-5073DOI: 10.1023/A:1023611415080ISI: 000183119900001Scopus ID: 2-s2.0-1642423933Local ID: 316cae40-ce3b-11db-89ed-000ea68e967bOAI: oai:DiVA.org:ltu-5073DiVA, id: diva2:977947
Note
Validerad; 2003; 20070309 (bajo)Available from: 2016-09-29 Created: 2016-09-29 Last updated: 2023-09-05Bibliographically approved

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Ivanov, Alexander V.Antzutkin, OlegForsling, Willis

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