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Transport and vibrational properties of pressure polymerised C60
1998 (English)In: Molecular crystals and liquid crystals science and technology, ISSN 1058-7276, E-ISSN 1563-5295, Vol. 11, no 1-2, p. 1-6Article in journal (Refereed) Published
Abstract [en]

The vibrational spectrum of polycrystalline C-60 polymerized at 1.1 GPa and 585 K was studied by inelastic neutron scattering. We find drastic changes in the spectrum compared with the vibrational spectrum of pristine C-60: the appearance of a new, bread vibrational band at low energies, and splining and significant changes in the peak positions of various modes. The thermal conductivity lambda of polymerized C-60 was measured in the temperature range 150-320 K and was found to increase with a rise temperature, which reflects strong phonon scattering. A high degree of structural disorder in the crystalline lattice of the polymeric phase is most probably responsible for the glass-like behaviour of lambda(T).

Place, publisher, year, edition, pages
1998. Vol. 11, no 1-2, p. 1-6
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Fysik
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URN: urn:nbn:se:ltu:diva-5421Local ID: 384f35c0-f104-11db-bb1b-000ea68e967bOAI: oai:DiVA.org:ltu-5421DiVA, id: diva2:978295
Note
Upprättat; 1998; 20070422 (ysko)Available from: 2016-09-29 Created: 2016-09-29 Last updated: 2018-04-25Bibliographically approved

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Soldatov, Alexander

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