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Effects of zeolite addition on the manganese catalyzed decomposition of hydrogen peroxide
Luleå tekniska universitet.
1999 (English)In: Journal of porous materials, ISSN 1380-2224, E-ISSN 1573-4854, Vol. 6, no 4, p. 275-282Article in journal (Refereed) Published
Abstract [en]

Manganese catalyzed decomposition of hydrogen peroxide in the presence of various zeolites was investigated at different pH values, Mn concentrations and zeolite: Mn ratios. Depending upon the level of these parameters the zeolites studied displayed both catalytic and inhibitive effects on the rate of decomposition. At a high pH (10.8) Mordenite 10A in a twofold excess on an ion-exchange capacity basis acted as an inhibitor whereas the other zeolites had little or no effect on the reaction rate. At a lower pH (9.0) zeolite A when added in large excess resulted in a remarkable inhibitive effect whereas the same zeolite resulted in a promotion of the catalytic action of manganese at an intermediate pH (9.9). The complex catalytic nature of zeolite-peroxide-Mn systems is discussed.

Place, publisher, year, edition, pages
1999. Vol. 6, no 4, p. 275-282
National Category
Chemical Process Engineering
Research subject
Chemical Technology
Identifiers
URN: urn:nbn:se:ltu:diva-5658DOI: 10.1023/A:1009680521692ISI: 000081303100002Scopus ID: 2-s2.0-0032687192Local ID: 3d2bafd0-2d5b-11dd-9c9b-000ea68e967bOAI: oai:DiVA.org:ltu-5658DiVA, id: diva2:978532
Note
Godkänd; 1999; 20080529 (cira)Available from: 2016-09-29 Created: 2016-09-29 Last updated: 2018-07-10Bibliographically approved

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Sterte, Johan

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