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Complexation of lead(II) with O,O′-dialkyldithiophosphate ligands: 31P and 13C CP/MAS NMR and single-crystal X-ray diffraction studies
Luleå University of Technology, Department of Civil, Environmental and Natural Resources Engineering, Sustainable Process Engineering.
Luleå University of Technology, Department of Civil, Environmental and Natural Resources Engineering, Sustainable Process Engineering.
Luleå University of Technology, Department of Civil, Environmental and Natural Resources Engineering, Sustainable Process Engineering.ORCID iD: 0000-0003-1067-7990
Far Eastern Branch of the Russian Academy of Sciences, Vladivostok.
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2004 (English)In: Inorganica Chimica Acta, ISSN 0020-1693, E-ISSN 1873-3255, Vol. 357, no 9, p. 2510-2518Article in journal (Refereed) Published
Abstract [en]

Polycrystalline lead(II) complexes with O,O′-dipropyl- and O,O′-di-cyclo-hexyldithiophosphate ions were prepared and studied by means of 31P, 31C CP/MAS NMR spectroscopy and single-crystal X-ray diffraction. Prepared complexes are characterised by polynuclear structures, in which pairs of dithiophosphate groups asymmetrically link neighbouring lead atoms, forming infinite linear zigzag chains. In spite of the same combined structural function, dithiophosphate ligands in both complexes display structural inequivalence. To characterise the combined structural state of the dialkyldithiophosphate ligands, 31P chemical shift anisotropy parameters, δaniso and η, were estimated from spinning sideband patterns in experimental CP/MAS NMR spectra for each of the two prepared complexes as well as the initial potassium O,O′-dipropyl- and O,O′-di-cyclo-hexyldithiophosphate salts.

Place, publisher, year, edition, pages
2004. Vol. 357, no 9, p. 2510-2518
National Category
Physical Chemistry
Research subject
Chemistry of Interfaces
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URN: urn:nbn:se:ltu:diva-5887DOI: 10.1016/j.ica.2003.12.045ISI: 000222745900012Scopus ID: 2-s2.0-3042579594Local ID: 41354dd0-81f3-11db-aabe-000ea68e967bOAI: oai:DiVA.org:ltu-5887DiVA, id: diva2:978763
Note
Validerad; 2004; 20061202 (ysko)Available from: 2016-09-29 Created: 2016-09-29 Last updated: 2018-07-10Bibliographically approved

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Larsson, Anna-CarinIvanov, Alexander V.Antzutkin, OlegForsling, Willis

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