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Mechanism of coadsorption of long-chain alkylamines and alcohols on silicates. Fourier transform spectroscopy and X-ray photoelectron spectroscopy studies
Luleå University of Technology.
Luleå University of Technology, Department of Civil, Environmental and Natural Resources Engineering, Sustainable Process Engineering.
2001 (English)In: Langmuir, ISSN 0743-7463, E-ISSN 1520-5827, Vol. 17, no 9, p. 2711-2719Article in journal (Refereed) Published
Abstract [en]

Coadsorption of long-chain primary amines and alcohols on silicates (quartz and albite) at pH 6-7 was studied using Fourier transform (DRIFTS and IRRAS) and X-ray photoelectron spectroscopy. The ionization state of the amino headgroups, the molecular orientation, and packing in the adsorbed mixed monolayers were determined. The results were interpreted in terms of the modified model of 2D-3D precipitation, where the elementary adsorbing species from the solution is the amine-alcohol-water association.

Place, publisher, year, edition, pages
2001. Vol. 17, no 9, p. 2711-2719
National Category
Metallurgy and Metallic Materials
Research subject
Mineral Processing
Identifiers
URN: urn:nbn:se:ltu:diva-5986DOI: 10.1021/la001201jLocal ID: 42ece4a0-b121-11db-bf9d-000ea68e967bOAI: oai:DiVA.org:ltu-5986DiVA: diva2:978862
Note
Validerad; 2001; 20070131 (pafi)Available from: 2016-09-29 Created: 2016-09-29 Last updated: 2017-11-24Bibliographically approved

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