This paper addresses the design of low-density parity-check (LDPC) codes for half-duplex co-operative relay networks. Structured rate-compatible codes with unequal error protection (UEP) are designed through joint optimization of the codes for the channels between source and relay and source and destination. The proposed codes clearly outperform simpler LDPC codes which are not optimized for relay channels and puncturing-based rate-compatible LDPC codes, and they show a significant performance improvement over the direct link communication depending on the position of relay. The optimization algorithm for the proposed codes is based on density evolution using the Gaussian approximation and optimal variable node degree distributions are found through iterative linear programming. Interestingly, they anyhow show performance which is almost comparable to the performance of codes optimized through a more complex non-linear optimization algorithm. We analyze the performance of our proposed codes with short, medium and long block lengths, and with low and high rates under realistic assumptions, i.e., imperfect decoding of the codeword at relay and variant signal-to-noise ratio within a single codeword.