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High pressure study of the 2D polymeric phase of C60 by means of Raman spectroscopy
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2001 (English)In: High Pressure Research, ISSN 0895-7959, E-ISSN 1477-2299, Vol. 18, no 1-6, p. 145-151Article in journal (Refereed) Published
Abstract [en]

The effect of high hydrostatic pressure, up to 12GPa, on the intramolecular phonon frequencies and the material stability of the two-dimensional tetragonal Cm polymer has been studied by means of Raman spectroscopy in the spectral range of the radial intramolecular modes (200-800cm-1). A number of new Raman modes appear in the spectrum for pressures ≈ 1.4 and ≈ 5.0 GPa. The pressure coefficients for the majority of the phonon modes exhibit changes to lower values at P=4.0 GPa, which may be related to a structural modification of the 2D polymer to a more isotropic phase. The peculiarities observed in the Raman spectra are reversible and the material is stable in the pressure region investigated.

Place, publisher, year, edition, pages
2001. Vol. 18, no 1-6, p. 145-151
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Fysik
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URN: urn:nbn:se:ltu:diva-6012DOI: 10.1080/08957950008200961Local ID: 434bd130-ef61-11db-bb5c-000ea68e967bOAI: oai:DiVA.org:ltu-6012DiVA, id: diva2:978888
Note
Upprättat; 2001; 20070420 (ysko)Available from: 2016-09-29 Created: 2016-09-29 Last updated: 2018-04-25Bibliographically approved

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Soldatov, Alexander

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