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Raman scattering in locally inhomogeneous oxide crystals
Mineralogisch-Petrographisches Institut, Universität Hamburg.
Central Laboratory of Mineralogy and Crystallography, Bulgarian Academy of Sciences.
Physikalisch-Technische Bundesanstalt, Braunschweig.
Luleå tekniska universitet.
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2003 (English)In: Phase Transitions, ISSN 0141-1594, E-ISSN 1029-0338, Vol. 76, no 1-2, p. 17-32Article in journal (Refereed) Published
Abstract [en]

Local-scale atomic arrangements in three types of oxide crystalline materials with structural defects, self-bonded molecular sieves, ferroelastics and relaxor ferroelectricity, are investigated by Raman spectroscopy. The experimentally observed spectral data are analysed through normal mode calculations for structural species representative of the intermediate range order in the solid. In the case of molecular sieves, the important role of incipient structural species for producing crystalline silicalite-1 and zeolite beta spheres of mm size is shown. In the case of ferroelastics, further insights on structural perturbation across the domain walls in monoclinic Pb 3(PO4)2 are provided. In the case of relaxors, the local structure and related dynamical effects in PbSc0.5Nb 0.5O3 and PbSc0.5Nb0.5O3 is revealed.

Place, publisher, year, edition, pages
2003. Vol. 76, no 1-2, p. 17-32
Keywords [en]
Technology - Chemical engineering
Keywords [sv]
Teknikvetenskap - Kemiteknik
National Category
Chemical Process Engineering
Research subject
Chemical Technology
Identifiers
URN: urn:nbn:se:ltu:diva-6244DOI: 10.1080/0141159031000076011Scopus ID: 2-s2.0-0842295830Local ID: 47163820-a9ca-11de-8293-000ea68e967bOAI: oai:DiVA.org:ltu-6244DiVA, id: diva2:979121
Note
Validerad; 2003; 20090925 (ysko)Available from: 2016-09-29 Created: 2016-09-29 Last updated: 2018-07-10Bibliographically approved

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Sterte, Johan

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