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Formation of the Hydroxyl Radical by Radiative Association
Department of Chemistry and Molecular Biology, University of Gothenburg.
Luleå University of Technology, Department of Engineering Sciences and Mathematics, Material Science.ORCID iD: 0000-0002-7629-0169
Department of Chemistry and Molecular Biology, University of Gothenburg.
2015 (English)In: Journal of Physical Chemistry A, ISSN 1089-5639, E-ISSN 1520-5215, Vol. 119, no 50, p. 12263-12269Article in journal (Refereed) Published
Abstract [en]

The reaction rate constant for the radiative association of O(3P) and H(2S) has been calculated by combining a few different methods and taking account of both direct and resonance-mediated pathways. The latter includes both shape resonances and Feshbach type inverse predissociation. The reaction rate constant is expressed as a function of temperature in the interval 10−30000 K. This reaction may be astrochemically relevant and is expected to be of use in astrochemical networks.

Place, publisher, year, edition, pages
2015. Vol. 119, no 50, p. 12263-12269
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Tillämpad fysik
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URN: urn:nbn:se:ltu:diva-6320DOI: 10.1021/acs.jpca.5b06300ISI: 000366881000035PubMedID: 26352189Scopus ID: 2-s2.0-84950327530Local ID: 48b6e0ab-8c37-4a23-b720-02def0350b5eOAI: oai:DiVA.org:ltu-6320DiVA, id: diva2:979197
Note
Validerad; 2016; Nivå 2; 20151128 (maggus)Available from: 2016-09-29 Created: 2016-09-29 Last updated: 2018-07-10Bibliographically approved

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