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Ozonation of a lignin-carbohydrate complex model compound of the benzyl ether type
Luleå University of Technology, Department of Engineering Sciences and Mathematics, Wood Science and Engineering.ORCID iD: 0000-0002-7711-9267
Forestry and Forest Products Research Institute.
Forestry and Forest Products Research Institute.
Forestry and Forest Products Research Institute.
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2000 (English)In: Journal of Wood Science, ISSN 1435-0211, E-ISSN 1611-4663, Vol. 46, no 3, p. 263-265Article in journal (Refereed) Published
Abstract [en]

Evidence for the presence of lignin-carbohydrate bonds of the benzylic ether type in wood and pulps may be obtained by use of ozonation treatment to selectively degrade the lignin. It was found that the benzyl ether bond in 3-(4-hydroxy-3-methoxyphenyl)-2-(2-methoxy-phenoxy)-3-(methyl--d-glucopyranosid-6-O-yl)-1-propanol was rather stable during ozonation in acetic acid-water-methanol 1631 at 0°C. The corresponding acid, 3,4-dihydroxy-2-(methyl--d-glucopyranosid-6-O-yl)-butanoic acid, was found to be the major reaction product. The use of ozonation followed by acid hydrolysis in connection with studies of lignincarbohydrate linkages is briefly discussed.

Place, publisher, year, edition, pages
2000. Vol. 46, no 3, p. 263-265
National Category
Bio Materials
Research subject
Wood Physics
Identifiers
URN: urn:nbn:se:ltu:diva-6717DOI: 10.1007/BF00776460Local ID: 4ff36180-a71e-11dc-9534-000ea68e967bOAI: oai:DiVA.org:ltu-6717DiVA, id: diva2:979603
Note
Validerad; 2000; 20071210 (cira)Available from: 2016-09-29 Created: 2016-09-29 Last updated: 2017-11-24Bibliographically approved

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Karlsson, Olov

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