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Structural organization of the tetranuclear zinc di-iso-propyl phosphorodithioate complex [Zn4O{S2P(O-iso-C3H7))(2)}(6)] as probed by single-crystal X-ray diffraction and C-13 and P-31 CP/MAS NMR
Amur State University, Blagoveshchensk, Russian Federation.
Luleå University of Technology, Department of Civil, Environmental and Natural Resources Engineering, Sustainable Process Engineering.
Amur State University, Blagoveshchensk, Russian Federation.
Russian Adademy of Sciences.
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2008 (English)In: Russian Journal of Inorganic Chemistry, ISSN 0036-0236, E-ISSN 1531-8613, Vol. 53, no 7, p. 1098-1109Article in journal (Refereed) Published
Abstract [en]

The zinc O,O'-di-iso-propyl phosphorodithioate complex [Zn4O⨑ub;S2P(O-iso-C3H7)2⫂ub;6] (I) has been synthesized and characterized by multinuclear MAS NMR (13C, 31P). The metal core of the tetranuclear structure of I, determined by single-crystal X-ray diffraction, is a tetrahedron centered by an oxygen atom. All Dtph ligands are structurally nonequivalent and act as μ2 bridges combining pairs of zinc atoms. Bonding of all metal atoms to the μ4 oxygen atom provides additional stabilization of the structure. For 31P NMR signals, the chemical shift anisotropy δaniso and the asymmetry parameter η were calculated, which allowed to assign them to the phosphorus positions in the structure of I.

Place, publisher, year, edition, pages
2008. Vol. 53, no 7, p. 1098-1109
National Category
Physical Chemistry
Research subject
Chemistry of Interfaces
Identifiers
URN: urn:nbn:se:ltu:diva-6934DOI: 10.1134/S003602360807019XISI: 000257777300019Scopus ID: 2-s2.0-47749095563Local ID: 54408e00-7452-11dd-a03a-000ea68e967bOAI: oai:DiVA.org:ltu-6934DiVA, id: diva2:979820
Note
Validerad; 2008; 20080827 (bajo)Available from: 2016-09-29 Created: 2016-09-29 Last updated: 2018-07-10Bibliographically approved

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Ivanov, Alexander V.Antzutkin, Oleg

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