Change search
CiteExportLink to record
Permanent link

Direct link
Cite
Citation style
  • apa
  • harvard1
  • ieee
  • modern-language-association-8th-edition
  • vancouver
  • Other style
More styles
Language
  • de-DE
  • en-GB
  • en-US
  • fi-FI
  • nn-NO
  • nn-NB
  • sv-SE
  • Other locale
More languages
Output format
  • html
  • text
  • asciidoc
  • rtf
Solvation isomers of solvated adducts of copper and zinc diethyldithiocarbamate complexes in the M(II)-EDtc-Py-Mf systems: synthesis, EPR, and solid-state C-13 and N-15 CP/MAS NMR
Russian Adademy of Sciences.
Russian Adademy of Sciences.
Luleå University of Technology, Department of Civil, Environmental and Natural Resources Engineering, Sustainable Process Engineering.ORCID iD: 0000-0003-1067-7990
2001 (English)In: Russian Journal of Inorganic Chemistry, ISSN 0036-0236, E-ISSN 1531-8613, Vol. 46, no 12, p. 1832-1838Article in journal (Refereed) Published
Abstract [en]

The crystalline adducts [M(B)(EDtc)(2)] (M = Zn, Cu; B = Py, Mf) quantitatively absorb bases to produce their solvated forms incorporating outer-sphere molecules of N-donor bases: [M(Mf)(EDtc)(2)] . Mf, [M(Mf)(EDtc)(2)] . Py, and [M(Py)(EDtc)(2)] . Mf. The adducts of the last two types ire solvate isomers, which differ in the distribution of different bases between the outer and inner coordination spheres, Computer simulation points to the individual character of the EPR spectra of the isomers [Cu(Mf)(EDtc)(2)] . Py and [Cu(Py)(EDtc)(2)] . Mf and the lack of redistribution of base molecules between two coordination spheres. The copper coordination polyhedra in these compounds are close to a trigonal bipyramid (the TBP contribution is about 80%); the ground state of the unpaired electron is dominated by the 3d(z2) copper(II) AO. Combined analysis of C-13 and N-15 NMR data permitted the identification of the signals that arise from the coordinated and outer-sphere pyridine molecules in the solvate isomers [Zn(Mf)(EDtc)(2)] . Py and [Zn(Py)(EDtc)(2)] . Mf.

Place, publisher, year, edition, pages
2001. Vol. 46, no 12, p. 1832-1838
National Category
Physical Chemistry
Research subject
Chemistry of Interfaces
Identifiers
URN: urn:nbn:se:ltu:diva-7351Local ID: 5ba80430-debb-11db-9cae-000ea68e967bOAI: oai:DiVA.org:ltu-7351DiVA: diva2:980240
Note
Validerad; 2001; 20070330 (bajo)Available from: 2016-09-29 Created: 2016-09-29 Last updated: 2017-11-24Bibliographically approved

Open Access in DiVA

No full text in DiVA

Search in DiVA

By author/editor
Antzutkin, OlegForsling, Willis
By organisation
Sustainable Process Engineering
In the same journal
Russian Journal of Inorganic Chemistry
Physical Chemistry

Search outside of DiVA

GoogleGoogle Scholar

urn-nbn

Altmetric score

urn-nbn
Total: 33 hits
CiteExportLink to record
Permanent link

Direct link
Cite
Citation style
  • apa
  • harvard1
  • ieee
  • modern-language-association-8th-edition
  • vancouver
  • Other style
More styles
Language
  • de-DE
  • en-GB
  • en-US
  • fi-FI
  • nn-NO
  • nn-NB
  • sv-SE
  • Other locale
More languages
Output format
  • html
  • text
  • asciidoc
  • rtf