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Structural organization of nickel(II), zinc(II), and copper(II) complexes with diisobutyldithiocarbamate: EPR, 13C and 15N CP/MAS NMR, and X-ray diffraction studies
Luleå University of Technology, Department of Civil, Environmental and Natural Resources Engineering, Sustainable Process Engineering.
Amur Institute of Integrated Research, Far East Division, Russian Academy of Sciences.
Institute of Chemistry, Far East Division, Russian Academy of Sciences.
Luleå University of Technology, Department of Civil, Environmental and Natural Resources Engineering, Sustainable Process Engineering.
2005 (English)In: Russian journal of coordination chemistry, ISSN 1070-3284, E-ISSN 1608-3318, Vol. 31, no 10, p. 695-707Article in journal (Refereed) Published
Abstract [en]

The structures and spectroscopic properties of nickel(II), zinc(II), and copper(II) complexes with dibutyl- and diisobutyldithiocarbamate were studied by EPR and 13C and 15N CP/MAS NMR spectroscopy and X-ray diffraction analysis. According to the EPR data, copper(II) forms mononuclear [63/65Cu{S2CNR2}2] and heterobinuclear complexes [63/65CuZn{S2CNR2}4] under magnetic dilution conditions. The isomeric forms of nickel(II) and zinc(II) diisobutyldithiocarbamates were detected by 13C and 15N NMR spectroscopy. The crystalline zinc(II) diisobutyldithiocarbamate was found to have a unique structural organization with alternating mononuclear [Zn{S2CN(i-C4H9)2}2] and binuclear molecular forms [Zn2{ S2CN(i-C4H9)2}4] in the 1 : 1 ratio.

Place, publisher, year, edition, pages
2005. Vol. 31, no 10, p. 695-707
National Category
Physical Chemistry
Research subject
Chemistry of Interfaces
Identifiers
URN: urn:nbn:se:ltu:diva-7392DOI: 10.1007/s11173-005-0157-4Local ID: 5c346750-e81f-11db-b9a9-000ea68e967bOAI: oai:DiVA.org:ltu-7392DiVA: diva2:980281
Note
Validerad; 2005; 20070411 (ysko)Available from: 2016-09-29 Created: 2016-09-29 Last updated: 2017-11-24Bibliographically approved

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