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Clathrate Formation of Bis(diethyldithiocarbamato)pyridinezinc(II) and Bis(diethyldithiocarbamato)pyridinecopper(II) with Benzene by EPR, High-Resolution Solid-State 13C and 15N NMR, and X-ray Crystallography
Luleå University of Technology, Department of Civil, Environmental and Natural Resources Engineering, Sustainable Process Engineering.
Arrhenius Laboratory, University of Stockholm.
University of Linköping.
Luleå University of Technology, Department of Civil, Environmental and Natural Resources Engineering, Sustainable Process Engineering.ORCID iD: 0000-0003-1067-7990
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1998 (English)In: Russian Journal of Inorganic Chemistry, ISSN 0036-0236, E-ISSN 1531-8613, Vol. 43, no 9, p. 1368-1376Article in journal (Refereed) Published
Abstract [en]

The structures of the clathrates of bis(diethyldithiocarbamato)pyridinezinc(H) and-copper(II) with benzene were studied by EPR, high-resolution solid-state 13C and 15N NMR, and X-ray crystallography. The geometry of the coordination polyhedra in the clathrates M(EDtc)2· Py · C6H6is close to trigonal-bipyramidal. Two short M-S bonds and the M-N bond form the equatorial plane, and two long M-S bonds point toward the axial positions. For the magnetically diluted copper(II) clathrate, the hyperfine structure can be observed at low temperatures due to the nitrogen atom of pyridine, which is associated with the contribution of the dz2orbital to the ground-state wave function of the unpaired electron. The 13C and 15N NMR signals were assigned.

Place, publisher, year, edition, pages
1998. Vol. 43, no 9, p. 1368-1376
National Category
Physical Chemistry
Research subject
Chemistry of Interfaces
Identifiers
URN: urn:nbn:se:ltu:diva-8029Local ID: 6784d690-13b9-11de-ae64-000ea68e967bOAI: oai:DiVA.org:ltu-8029DiVA, id: diva2:980919
Note
Godkänd; 1998; 20090318 (andbra)Available from: 2016-09-29 Created: 2016-09-29 Last updated: 2017-11-24Bibliographically approved

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Ivanov, Alexander V.Antzutkin, Oleg

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