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A Gas-Phase Study of the Preferential Solvation of Mn2+ in Mixed Water/Methanol Clusters
Department of Physical Chemistry, School of Chemistry, University of Nottingham.
Department of Chemistry, University of Sussex, Falmer, Brighton.
Department of Chemistry, University of Sussex, Falmer, Brighton.
Department of Chemistry, University of Sussex, Falmer, Brighton.
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2008 (English)In: Journal of the American Society for Mass Spectrometry, ISSN 1044-0305, E-ISSN 1879-1123, Vol. 19, no 4, p. 520-530Article in journal (Refereed) Published
Abstract [en]

The kinetic shift that exists between two competing unimolecular fragmentation processes has been used to establish whether or not gas-phase Mn2+ exhibits preferential solvation when forming mixed clusters with water and methanol. Supported by molecular orbital calculations, these first results for a metal dication demonstrate that Mn2+ prefers to be solvated by methanol in the primary solvation shell.

Place, publisher, year, edition, pages
2008. Vol. 19, no 4, p. 520-530
National Category
Bio Materials
Research subject
Wood and Bionanocomposites
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URN: urn:nbn:se:ltu:diva-8277DOI: 10.1016/j.jasms.2007.12.004Local ID: 6c34f75e-9dfd-434e-94cf-e53f3ee03e62OAI: oai:DiVA.org:ltu-8277DiVA, id: diva2:981168
Note
Upprättat; 2008; 20160829 (andbra)Available from: 2016-09-29 Created: 2016-09-29 Last updated: 2017-11-24Bibliographically approved

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Ryden, Jens

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