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Isomorphism of bis(diethyldithiocarbamato)zinc(II) adduct with pyridine, [Zn(Py)(EDtc)2]: hysteresis in the reaction of the adduct formation
Luleå University of Technology, Department of Civil, Environmental and Natural Resources Engineering, Sustainable Process Engineering.
Luleå University of Technology, Department of Civil, Environmental and Natural Resources Engineering, Sustainable Process Engineering.ORCID iD: 0000-0003-1067-7990
2002 (English)In: Polyhedron, ISSN 0277-5387, E-ISSN 1873-3719, Vol. 21, no 27-28, p. 2727-3731Article in journal (Refereed) Published
Abstract [en]

The structure of the polycrystalline adduct bis(diethyldithiocarbamato)-pyridine zinc(II) depends on the pathway of physico-chemical conditions during the preparation procedure, as was revealed by solid state 15N CP/MAS spectroscopy in good correlation with known single crystal X-ray diffraction structures of this adduct. Two isomorphs of the adduct, namely α-[Zn(Py)(S2CNEt2)2] and β-[Zn(Py)(S2CNEt2)2], are the two molecules in the asymmetric unit of a single crystal (or polycrystalline) sample that can be obtained by recrystallization from toluene of the equimolar solution of the initial diethyldithiocarbamate zinc(II) complex and pyridine. The third isomorph, γ-[Zn(Py)(S2CNEt2)2], can be obtained by recrystallization from pure pyridine of the diethyldithiocarbamate zinc(II) complex, or by its equimolar absorption of pyridine, or by desorption of pyridine from the clathrated adduct, [Zn(Py)(S2CNEt2)2]·Py. Finally, the γ-[Zn(Py)(S2CNEt2)2] isomorph recrystallizes from the melt into α/β-isomorphs of the adduct.

Place, publisher, year, edition, pages
2002. Vol. 21, no 27-28, p. 2727-3731
National Category
Physical Chemistry
Research subject
Chemistry of Interfaces
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URN: urn:nbn:se:ltu:diva-8342DOI: 10.1016/S0277-5387(02)01274-3ISI: 000179808400011Local ID: 6d897370-dde7-11db-9cae-000ea68e967bOAI: oai:DiVA.org:ltu-8342DiVA, id: diva2:981234
Note
Validerad; 2002; 20070329 (bajo)Available from: 2016-09-29 Created: 2016-09-29 Last updated: 2018-07-10Bibliographically approved

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Ivanov, Alexander V.Antzutkin, Oleg

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