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CP/MAS NMR (13C, 15N, and 113Cd), thermal behavior, and sorption properties of cadmium Di-Iso-Butyldithiocarbamate: The Gold(III)-Binding species sorbed from solutions
Institute of Geology and Nature Management, Far East Branch, Russian Academy of Sciences, Blagoveshchensk.
Institute of Geology and Nature Management, Far East Branch, Russian Academy of Sciences, Blagoveshchensk.
Institute of Geology and Nature Management, Far East Branch, Russian Academy of Sciences, Blagoveshchensk.
Institute of Geology and Nature Management, Far East Branch, Russian Academy of Sciences, Blagoveshchensk.
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2012 (English)In: Russian Journal of Inorganic Chemistry, ISSN 0036-0236, E-ISSN 1531-8613, Vol. 57, no 11, p. 1490-1495Article in journal (Refereed) Published
Abstract [en]

The structure and thermal behavior of cadmium di-iso-butyldithiocarbamate (I) have been stud- ied by solid-state 13C and 15N CP/MAS NMR and simultaneous thermal analysis (STA). The cadmium com- plex forms two crystalline polymorphs, a and β. The structure of each of the polymorphs contains two struc- turally nonequivalent binuclear [Cd 2{S 2CN(iso-C 4H 9) 2} 4] molecules. The STA data have shown the possibil- ity of the α-I β-I phase transition. Studying the thermal behavior of the complex has demonstrated that the end product of thermodestruction is a fine yellow-orange powder of CdS. The sorption properties of I have been studied with respect to gold(III) chloride solutions in 2 M HCl. It has been found that gold(III) is efficiently sorbed from strong acid solutions in the Au3+ concentration range 0.032-3.220 mg/mL. On the basis of multinuclear (13C, 15N, and 113Cd) MAS NMR data, it has been demonstrated that the individual gold(III)-binding species in the sorption system is the ionic gold(III) cadmium-complex of composition [Au{S2CN(iso-C 4H 9) 2} 2] 2[CdCl 4

Place, publisher, year, edition, pages
2012. Vol. 57, no 11, p. 1490-1495
National Category
Physical Chemistry
Research subject
Chemistry of Interfaces
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URN: urn:nbn:se:ltu:diva-8677DOI: 10.1134/S0036023612110113ISI: 000310876500012Scopus ID: 2-s2.0-84869020687Local ID: 7384a5fc-78b7-46a5-9599-e77ea9791264OAI: oai:DiVA.org:ltu-8677DiVA, id: diva2:981615
Note
Validerad; 2012; 20121203 (andbra)Available from: 2016-09-29 Created: 2016-09-29 Last updated: 2018-07-10Bibliographically approved

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