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Modification of the conductance of single fullerene molecules by endohedral doping
Institut für Bio- und Nanosysteme, Forschungszentrum Jülich.
Tyndall National Institute, University College Cork.
Department of Physics, Queen Mary University of London.
Department of Physics, Queen Mary University of London.
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2009 (English)In: Applied Physics Letters, ISSN 0003-6951, E-ISSN 1077-3118, Vol. 95, no 13Article in journal (Refereed) Published
Abstract [en]

We use scanning tunneling microscopy to establish controlled contacts to single molecules of endohedrally doped Ce 2@C 80 fullerenes with C 60 as a reference. The stability of the experimental setup allows for the determination of the conductance of Ce 2@C 80 relative to the conductance of C 60. The endohedral doping reduces the conductance of Ce 2@C 80 by a factor of about five with respect to C 60. Ab initio calculations show that the reason for this reduced conductance is the absence of electron orbitals delocalized over the cage of Ce 2@C 80 in the energy window of the conductance measurement

Place, publisher, year, edition, pages
2009. Vol. 95, no 13
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URN: urn:nbn:se:ltu:diva-8839DOI: 10.1063/1.3236529Local ID: 76349a31-33dc-4142-b8a4-17255c66a95aOAI: oai:DiVA.org:ltu-8839DiVA, id: diva2:981777
Note
Upprättat; 2009; Bibliografisk uppgift: Article number 133118; 20130227 (andbra)Available from: 2016-09-29 Created: 2016-09-29 Last updated: 2017-11-24Bibliographically approved

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Larsson, Andreas

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