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Performance of diffusive gradients in thin films for measurements of the isotopic composition of soluble Zn
Swedish Museum of Natural History.
Luleå University of Technology, Department of Civil, Environmental and Natural Resources Engineering, Geosciences and Environmental Engineering.ORCID iD: 0000-0003-2276-0564
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2005 (English)In: Analytica Chimica Acta, ISSN 0003-2670, E-ISSN 1873-4324, Vol. 537, no 1-2, p. 401-405Article in journal (Refereed) Published
Abstract [en]

The application of diffusive gradients in thin films (DGT) samplers for measurements of the isotopic composition of soluble Zn by multi-collector inductively coupled plasma mass spectrometry (MC-ICPMS) was tested under laboratory conditions. The effect of diffusion in hydrogels as a possible source of fractionation was investigated by measuring Zn isotope ratios for different fractions of Zn accumulated by DGT and comparing with the bulk isotope composition of the solution. An important finding of this study is that, provided quantitative elution is obtained, no fractionation of Zn isotopes due to the diffusion process is detectable within the reported precision of MC-ICPMS measurements. Consequently, DGT samplers are suitable for studies of the Zn isotopic composition in natural waters.

Place, publisher, year, edition, pages
2005. Vol. 537, no 1-2, p. 401-405
National Category
Geochemistry
Research subject
Applied Geology
Identifiers
URN: urn:nbn:se:ltu:diva-8937DOI: 10.1016/j.aca.2005.01.047ISI: 000228761300047Scopus ID: 2-s2.0-17044420421Local ID: 77d306a0-0585-11dc-8b31-000ea68e967bOAI: oai:DiVA.org:ltu-8937DiVA, id: diva2:981875
Note
Validerad; 2005; 20070518 (ysko)Available from: 2016-09-29 Created: 2016-09-29 Last updated: 2018-07-10Bibliographically approved

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Malinovskiy, DmitryBaxter, DouglasIngri, JohanRodushkin, Ilya

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CiteExportLink to record
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