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A comparative study of the structural organization of zinc complexes with dialkyl-substituted and cyclic dithiocarbamate ligands: synthesis, single-crystal X-ray diffraction, and CP/MAS C-13 and N-15 NMR
Luleå University of Technology, Department of Civil, Environmental and Natural Resources Engineering, Sustainable Process Engineering.
Russian Adademy of Sciences.
Russian Adademy of Sciences.
Luleå University of Technology, Department of Civil, Environmental and Natural Resources Engineering, Sustainable Process Engineering.
2003 (English)In: Russian Journal of Inorganic Chemistry, ISSN 0036-0236, E-ISSN 1531-8613, Vol. 48, no 1, p. 45-54Article in journal (Refereed) Published
Abstract [en]

The structures and spectral properties of eight zinc(II) dithiocarbamate complexes [Zn-2(S2CNR2)(4)] (R = CH3, C2H5, C3H7, C3H7, C4H9; or R-2 = (CH2)(5), (CH2)(6), (CH2)(4)O) have been studied by single-crystal X-ray diffraction and CP/MAS C-13 and N-15 NMR. The experimental C-13 and N-15 NMR signals have been assigned to the positions of the corresponding atoms in the ligands with different structural functions (terminal or bridging). Differences in the N-15 NMR isotropic chemical shifts of dialkyldithiocarbamate ligands have been interpreted based on the concept of joint manifestation of the mesometic effect of dithiocarbamate groups and the inductive effect of alkyl substituents. The zinc dibutyl-, pentamethylene-, and morpholinedithiocarbamate complexes have been prepared and comprehensively characterized. The binuclear complex [Zn-2{S2CN(C4H9)(2)}(4)] appears to be the second example of a noncentrosymmetiic molecule of zinc dithiocarbamate. Another structural feature of the dimer is the fact that the eight-membered [Zn2S4C2] metallacycle is stabilized in the boat rather than in the chair conformation.

Place, publisher, year, edition, pages
2003. Vol. 48, no 1, p. 45-54
National Category
Physical Chemistry
Research subject
Chemistry of Interfaces
Identifiers
URN: urn:nbn:se:ltu:diva-9735Local ID: 866ef3e0-dc59-11db-b67f-000ea68e967bOAI: oai:DiVA.org:ltu-9735DiVA, id: diva2:982673
Note
Validerad; 2003; 20070327 (bajo)Available from: 2016-09-29 Created: 2016-09-29 Last updated: 2017-11-24Bibliographically approved

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Ivanov, Alexander V.Forsling, Willis

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