About 66% of all heat energy generated in Sweden originates from the incineration of municipal solid waste and biofuels such as wood, cardboard and peat. In addition to heat energy, incinerators generate about 1.7 Mt of ashes each year, of which 500 000 t are air pollution control (APC) residues. APC residues from municipal solid waste incineration are usually landfilled whereas those from biofuel incinerators are used in roads, as soil fertilizers, and as amendments for stabilizing APC residues classified as hazardous waste. The physico-chemical properties of compacted APC residues are such that they could be viable alternatives to clay in landfill cover liners, and could also replace cement in cases where a solidified structure is desired. However, APC residues are classified as waste and their use may rise concern due to the release of harmful substances into the environment. This thesis examines the environmental impact of APC residues when used together with other waste materials (e.g. sewage sludge, bottom ash, compost) in a landfill cover. In addition, the suitability of APC residues as amendments for stabilizing contaminated soil and their effect on the stability of treated soil under landfill conditions was investigated. The environmental impacts of alternative landfill cover were evaluated by field and laboratory tests that examined two water streams: the landfill cover’s drainage water and its leachate. The drainage water that seeps above the landfill cover liner and is drained away from a landfill cover was contaminated with Cl-, N, TOC and the trace elements As, Cu, Mo, Ni, Se, Pb and Zn. This water stream will need treatment for at least three to four decades. The amounts of landfill cover leachate that percolated through the liner in the field test ranged from 3 to 30 l (m2 y)-1, which was below the legal limit on the leachate flow in non-hazardous waste landfills (