The "Ice Giants" Uranus and Neptune are a different class of planet compared to Jupiter and Saturn. Studying these objects is important for furthering our understanding of the formation and evolution of the planets, and unravelling the fundamental physical and chemical processes in the Solar System. The importance of filling these gaps in our knowledge of the Solar System is particularly acute when trying to apply our understanding to the numerous planetary systems that have been discovered around other stars. The Uranus Pathfinder (UP) mission thus represents the quintessential aspects of the objectives of the European planetary community as expressed in ESA's Cosmic Vision 2015-2025. UP was proposed to the European Space Agency's M3 call for medium-class missions in 2010 and proposed to be the first orbiter of an Ice Giant planet. As the most accessible Ice Giant within the M-class mission envelope Uranus was identified as the mission target. Although not selected for this call the UP mission concept provides a baseline framework for the exploration of Uranus with existing low-cost platforms and underlines the need to develop power sources suitable for the outer Solar System. The UP science case is based around exploring the origins, evolution, and processes at work in Ice Giant planetary systems. Three broad themes were identified: (1) Uranus as an Ice Giant, (2) An Ice Giant planetary system, and (3) An asymmetric magnetosphere. Due to the long interplanetary transfer from Earth to Uranus a significant cruise-phase science theme was also developed. The UP mission concept calls for the use of a Mars Express/Rosetta-type platform to launch on a Soyuz-Fregat in 2021 and entering into an eccentric polar orbit around Uranus in the 2036-2037 timeframe. The science payload has a strong heritage in Europe and beyond and requires no significant technology developments. © 2011 Springer Science+Business Media B.V.

Here we inspect whether microbial life may disperse using dust transported by wind in the Atacama Desert in northern Chile, a well-known Mars analog model. By setting a simple experiment across the hyperarid core of the Atacama we found that a number of viable bacteria and fungi are in fact able to traverse the driest and most UV irradiated desert on Earth unscathed using wind-transported dust, particularly in the later afternoon hours. This finding suggests that microbial life on Mars, extant or past, may have similarly benefited from aeolian transport to move across the planet and find suitable habitats to thrive and evolve.

Satellite remote sensing is an effective way to monitor vast extents of global glaciers and snowfields. However, satellite remote sensing is limited by spatial and temporal resolutions and the high costs involved in data acquisition. Unmanned aerial vehicle (UAV)-based glaciological studies are gaining pace in recent years due to their advantages over conventional remote sensing platforms. UAVs are easy to deploy, with the option of alternating the sensors working in visible, infrared, and microwave wavelengths. The high spatial resolution remote sensing data obtained from these UAV-borne sensors are a significant improvement over the data obtained by traditional remote sensing. The cost involved in data acquisition is minimal and researchers can acquire imagery according to their schedule and convenience. We discuss significant glaciological studies involving UAV as remote sensing platforms. This is the first review work, exclusively dedicated to highlight UAV as a remote sensing platform in glaciology. We examine polar and alpine applications of UAV and their future prospects in separate sections and present an extensive reference list for the readers, so that they can delve into their topic of interest. Because the technology is still widely unexplored for snow and glaciers, we put a special emphasis on discussing the future prospects of utilising UAVs for glaciological research.

The cryosphere consists of frozen water and includes lakes/rivers/sea ice, glaciers, ice caps/sheets, snow cover, and permafrost. Because highly reflective snow and ice are the main components of the cryosphere, it plays an important role in the global energy balance. Thus, any qualitative or quantitative change in the physical properties and extents of the cryosphere affects global air circulation, ocean and air temperatures, sea level, and ocean current patterns. Due to the hardships involved in collecting ground control points and field data for high alpine glaciers or vast polar ice sheets, several researchers are currently using remote sensing. Satellites provide an effective space-borne platform for remotely sensing frozen areas at the global and regional scales. However, satellite remote sensing has several constraints, such as limited spatial and temporal resolutions and expensive data acquisition. Therefore, aerial and terrestrial remote sensing platforms and sensors are needed to cover temporal and spatial gaps for comprehensive cryospheric research. Light Detection and Ranging (LiDAR) antennas form a group of active remote sensors that can easily be deployed on all three platforms, i.e., satellite, aerial, and terrestrial. The generation of elevation data for glacial and snow-covered terrain from photogrammetry requires high contrast amongst various reflective surfaces (ice, snow, firn, and slush). Conventional passive optical remote sensors do not provide the necessary accuracy, especially due to the unavailability of reliable ground control points. However, active LiDAR sensors can fill this research gap and provide high-resolution and accurate Digital Elevation Models (DEMs). Due to the obvious advantages of LiDAR over conventional passive remote sensors, the number of LiDAR-based cryospheric studies has increased in recent years. In this review, we highlight studies that have utilised LiDAR sensors for the cryospheric research of various features, such as snow cover, polar ice sheets and their atmospheres, alpine glaciers, and permafrost. Because this technology shows immense promise for applications in future cryospheric research, we also emphasise the prospects of utilising LiDAR sensors. In this paper, a large compilation of relevant references is presented to allow readers to explore particular topics of interest.

The catastrophic magnitude of life and monetary losses associated with earthquakes deserve serious attention and mitigation measures. However, in addition to the pre-earthquake and post-earthquake alleviation actions, the scientific community indeed needs to reconsider the possibilities of earthquake predictions using non-seismic precursors. A significant number of studies in the recent decades have reported several possible earthquake precursors such as anomalies in electric field, magnetic field, gas/aerosol emissions, ionospheric signals, ground water level, land surface temperature, surface deformations, animal behaviour, thermal infrared signals, atmospheric gravity waves, and lightning. Such substantial number of scientific articles and reported anomalous signals cannot be overlooked without a thoughtful appraisal. Here, we provide an opinion on the way forward for earthquake prediction in terms of challenges and possibilities while using non-seismic precursors. A general point of concern is the widely varying arrival times and the amplitudes of the anomalies, putting a question mark on their universal applicability as earthquake markers. However, a unifying concept which does not only define the physical basis of either all or most of these anomalies but which also streamlines their characterisation procedure must be the focus of future earthquake precursory research. Advancements in developing the adaptable instrumentation for in-situ observations of the claimed non-seismic precursors must be the next step and the satellite observations should not be taken as a replacement for field-based research. We support the need to standardise the precursor detection techniques and to employ a global-scale monitoring system for making any possible earthquake predictions reliable.

Slope streaks have been frequently observed in the equatorial, low thermal inertia and dusty regions of Mars. The reason behind their formation remains unclear with proposed hypotheses for both dry and wet mechanisms. Here, we report an up-to-date distribution and morphometric investigation of Martian slope streaks. We find: (i) a remarkable coexistence of the slope streak distribution with the regions on Mars with high abundances of water-equivalent hydrogen, chlorine, and iron; (ii) favourable thermodynamic conditions for transient deliquescence and brine development in the slope streak regions; (iii) a significant concurrence of slope streak distribution with the regions of enhanced atmospheric water vapour concentration, thus suggestive of a present-day regolith-atmosphere water cycle; and (iv) terrain preferences and flow patterns supporting a wet mechanism for slope streaks. These results suggest a strong local regolith-atmosphere water coupling in the slope streak regions that leads to the formation of these fluidised features. Our conclusions can have profound astrobiological, habitability, environmental, and planetary protection implications

Slope streaks are prevalent and intriguing dark albedo surface features on contemporary Mars. Slope streaks are readily observed in the equatorial and subequatorial dusty regolith regions with low thermal inertia. They gradually fade over decadal timescales. The proposed mechanisms for their formation vary widely based on several physicochemical and geomorphological explanations. The scientific community is divided in proposing both dry and wet mechanisms for the formation of slope streaks. Here we perform a systematic evaluation of the literature for these wet and dry mechanisms. We discuss the probable constraints on the various proposed mechanisms and provide perspectives on the plausible process driving global‐scale slope streak formation on contemporary Mars. Although per our understanding, a thorough consideration of the global distribution of slope streaks, their morphology and topography, flow characteristics, physicochemical and atmospheric coincidences, and terrestrial analogies weighs more in favor of several wet mechanisms, we acknowledge that such wet mechanisms cannot explain all the reported morphological and terrain variations of slope streaks. Thus, we suggest that explanations considering both dry and wet processes can more holistically describe all the observed morphological variations among slope streaks. We further acknowledge the constraints on the resolutions of remote sensing data and on our understanding of the Martian mineralogy, climate, and atmosphere and recommend continuous investigations in this direction using future remote sensing acquisitions and simulations. In this regard, finding more wet and dry terrestrial analogs for Martian slope streaks and studying them at high spatiotemporal resolutions can greatly improve our understanding.

Several interpretations of recurring slope lineae (RSL) have related RSL to the potential presence of transient liquid water on Mars. Such probable signs of liquid water have implications for Mars exploration in terms of rover safety, planetary protection during rover operations, and the current habitability of the planet. Mawrth Vallis has always been a prime target to be considered for Mars rover missions due to its rich mineralogy. Most recently, Mawrth Vallis was one of the two final candidates selected by the European Space Agency as a landing site for the ExoMars 2020 mission. Therefore, all surface features and landforms in Mawrth Vallis that may be of special interest in terms of scientific goals, rover safety, and operations must be scrutinised to better assess it for future Mars missions. Here, we report on the initial detection of RSL candidates in two craters of Mawrth Vallis. The new sightings were made outside of established RSL regions and further prompt the inclusion of a new geographical region within the RSL candidate group. Our inferences on the RSL candidates are based on several morphological and geophysical evidences and analogies: (i) the dimensions of the RSL candidates are consistent with confirmed mid-latitude RSL; (ii) albedo and thermal inertia values are comparable to those of other mid-latitude RSL sites; and (iii) features are found in a summer season image and on the steep and warmest slopes. These results denote the plausible presence of transient liquid brines close to the previously proposed landing ellipse of the ExoMars rover, rendering this site particularly relevant to the search of life. Further investigations of Mawrth Vallis carried out at higher spatial and temporal resolutions are needed to identify more of such features at local scales to maximize the scientific return from the future Mars rovers, to prevent probable biological contamination during rover operations, to evade damage to rover components as brines can be highly corrosive, and to quantify the ability of the regolith at mid-latitudes to capture atmospheric water which is relevant for in-situ-resource utilization.

Aeolian processes are believed to play a major role in the landscape evolution of Mars. Investigations on Martian aeolian landforms such as ripples, transverse aeolian ridges (TARs), and dunes, and aeolian sediment flux measurements are important to enhance our understanding of past and present wind regimes, the ongoing dust cycle, landscape evolution, and geochemistry. These aeolian bedforms are often comprised of loose sand and sharply undulating topography and thus pose a threat to mobility and maneuvers of Mars rovers. Here we present a first-hand account of the distribution, morphologies, and morphometrics of TARs in Oxia Planum, the recently selected ExoMars 2020 Rover landing site. The gridded mapping was performed for contiguous stretches of TARs within all the landing ellipses using 57 sub-meter high resolution imaging science experiment (HiRISE) scenes. We also provide the morphological descriptions for all types of TARs present within the landing ellipses. We use HiRISE digital terrain models (DTMs) along with the images to derive morphometric information for TARs in Oxia Planum. In general, the average areal TAR coverage was found to be 5.4% (±4.9% standard deviation), increasing from west to east within the landing ellipses. We report the average TAR morphometrics in the form of crest–ridge width (131.1 ± 106.2 m), down-wind TAR length (17.6 ± 10.1 m), wavelength (37.3 ± 11.6 m), plan view aspect ratio (7.1 ± 2.3), inter-bedform spacing (2.1 ± 1.1), slope (10.6° ± 6.1°), predominant orientations (NE-SW and E-W), and height (1.2 ± 0.8 m). While simple TARs are predominant, we report other TAR morphologies such as forked TAR, wavy TAR with associated smaller secondary ripples, barchan-like TAR, networked TAR, and mini-TARs from the region. Our results can help in planning the rover traverses in terms of both safe passage and scientific returns favoring aeolian research, particularly improving our understanding of TARs.

Understanding extraterrestrial environments and landforms through remote sensing and terrestrial analogy has gained momentum in recent years due to advances in remote sensing platforms, sensors, and computing efficiency. The seasonal brines of the largest salt plateau on Earth in Salar de Uyuni (Bolivian Altiplano) have been inadequately studied for their localized hydrodynamics and the regolith volume transport across the freshwater-brine mixing zones. These brines have recently been projected as a new analogue site for the proposed Martian brines, such as recurring slope lineae (RSL) and slope streaks. The Martian brines have been postulated to be the result of ongoing deliquescence-based salt-hydrology processes on contemporary Mars, similar to the studied Salar de Uyuni brines. As part of a field-site campaign during the cold and dry season in the latter half of August 2017, we deployed an unmanned aerial vehicle (UAV) at two sites of the Salar de Uyuni to perform detailed terrain mapping and geomorphometry. We generated high-resolution (2 cm/pixel) photogrammetric digital elevation models (DEMs) for observing and quantifying short-term terrain changes within the brines and their surroundings. The achieved co-registration for the temporal DEMs was considerably high, from which precise inferences regarding the terrain dynamics were derived. The observed average rate of bottom surface elevation change for brines was ~1.02 mm/day, with localized signs of erosion and deposition. Additionally, we observed short-term changes in the adjacent geomorphology and salt cracks. We conclude that the transferred regolith volume via such brines can be extremely low, well within the resolution limits of the remote sensors that are currently orbiting Mars, thereby making it difficult to resolve the topographic relief and terrain perturbations that are produced by such flows on Mars. Thus, the absence of observable erosion and deposition features within or around most of the proposed Martian RSL and slope streaks cannot be used to dismiss the possibility of fluidized flow within these features

The high levels of uncertainty associated with earthquake prediction render earthquakes some of the worst natural calamities. Here, we present our observations of MODerate resolution Imaging Spectroradiometer (MODIS)-derived Land Surface Temperature (LST) anomaly for earthquakes in the largest tectonically active Himalayan and Andean mountain belts. We report the appearance of fairly detectable pre-earthquake Snow Surface Temperature (SST) anomalies. We use 16 years (2000–2015) of MODIS LST time-series data to robustly conclude our findings for three of the most destructive earthquakes that occurred in 2015 in the high mountains of Nepal, Chile, and Afghanistan. We propose the physical basis behind higher sensitivity of snow towards geothermal emissions. Although the preliminary appearance of SST anomalies and their amplitudes vary, we propose employing a global-scale monitoring system for detecting and studying such spatio-temporal geophysical signals. With the advent of improved remote sensors, we anticipate that such efforts can be another step towards improved earthquake predictions.

The low predictability of earthquakes and the high uncertainty associated with their forecasts make earthquakes one of the worst natural calamities, capable of causing instant loss of life and property. Here, we discuss the studies reporting the observed anomalies in the satellite-derived Land Surface Temperature (LST) before an earthquake. We compile the conclusions of these studies and evaluate the use of remotely sensed LST anomalies as precursors of earthquakes. The arrival times and the amplitudes of the anomalies vary widely, thus making it difficult to consider them as universal markers to issue earthquake warnings. Based on the randomness in the observations of these precursors, we support employing a global-scale monitoring system to detect statistically robust anomalous geophysical signals prior to earthquakes before considering them as definite precursors.

The Mars Science Laboratory rover Curiosity scooped samples of soil from the Rocknest aeolian bedform in Gale crater. Analysis of the soil with the Chemistry and Mineralogy (CheMin) x-ray diffraction (XRD) instrument revealed plagioclase (~An57), forsteritic olivine (~Fo62), augite, and pigeonite, with minor K-feldspar, magnetite, quartz, anhydrite, hematite, and ilmenite. The minor phases are present at, or near, detection limits. The soil also contains 27 ± 14 weight percent x-ray amorphous material, likely containing multiple Fe3+- and volatile-bearing phases, including possibly a substance resembling hisingerite. The crystalline component is similar to the normative mineralogy of certain basaltic rocks from Gusev crater on Mars and of martian basaltic meteorites. The amorphous component is similar to that found on Earth in places such as soils on the Mauna Kea volcano, Hawaii.

This article summarizes a practical case of introduction to research and planetary exploration through the analysis of data from the Rover Environmental Monitoring Station (REMS), one of the ten scientific instruments on board the Curiosity rover of the Mars Science Laboratory (MSL), currently operating at the impact crater Gale, on Mars. It is the main aim of this work to show how the data that are publicly available at the Planetary Data System (PDS) can be used to introduce undergraduate students and the general public into the subject of surface exploration and the environment of Mars. In particular, the goal of this practice was to investigate and quantify the heat flux between the rover spacecraft and the Martian surface, the role of the atmosphere in this interaction, and its dependence with seasons, as well as to estimate the thermal contamination of the Martian ground produced by the rover. The ground temperature sensor (GTS) of the REMS instrument has measured in-situ, for the first time ever, the diurnal and seasonal variation of the temperature of the surface on Mars along the rover traverse. This novel study shows that the rover radiative heat flux varies between 10 and 22 W/m2 during the Martian year, which is more than 10% of the solar daily averaged insolation at the top of the atmosphere. In addition, it is shown that the radiative heat flux from the rover to the ground varies with the atmospheric dust load, being the mean annual amplitude of the diurnal variation of the surface temperature of 76 K, as a result of solar heating during the day and infrared cooling during the night. As a remarkable and unexpected outcome, it has been established that the thermal contamination produced by the rover alone induces, on average, a systematic shift of 7.5 K, which is indeed about 10% of the one produced by solar heating. This result may have implications for the design and operation of future surface exploration probes such as InSight.

Suspicion that Mars could have transient liquid water on its surface through deliquescence of salts to form aqueous solutions or brines is an old proposal whose inquiry was boosted by Phoenix Lander observations. It provided some images of what were claimed to be brines, the presence of which at its landing site was compatible with the atmospheric parameters and the composition of the soil observed. On the other hand, the so called Recurrent Slope Lineae (RSL) often imaged by orbiters, were considered as another clue pointing to the occurrence of the phenomenon, since it was thought that they might be caused by it. Now, Curiosity rover has performed the first in-situ multi-instrumental study on Mars’ surface, having collected the most comprehensive environmental data set ever taken by means of their instruments Rover Environmental Monitoring Station (REMS), Dynamic Albedo of Neutrons (DAN), and Sample Analysis at Mars (SAM). REMS is providing continuous and accurate measurements of the relative humidity and surface and air temperatures among other parameters, and DAN and SAM provide the water content of the regolith and the atmosphere respectively. Analysis of these data has allowed to establish the existence of a present day active water cycle between the atmosphere and the regolith, that changes according to daily and seasonal cycles, and that is mediated by the presence of brines during certain periods of each and every day. Importantly, the study shows that the conditions for the occurrence of deliquescence are favourable even at equatorial latitudes where, at first, it was thought they were not due to the temperature and relative humidity conditions. This study provides new keys for the understanding of martian environment, and opens interesting lines of research and studies for future missions which may even have a bearing on extant microbial life.

The deep subsurface of other planetary bodies is of special interest for robotic and human exploration. The subsurface provides access to planetary interior processes, thus yielding insights into planetary formation and evolution. On Mars, the subsurface might harbour the most habitable conditions. In the context of human exploration, the subsurface can provide refugia for habitation from extreme surface conditions. We describe the fifth Mine Analogue Research (MINAR 5) programme at 1 km depth in the Boulby Mine, UK in collaboration with Spaceward Bound NASA and the Kalam Centre, India, to test instruments and methods for the robotic and human exploration of deep environments on the Moon and Mars. The geological context in Permian evaporites provides an analogue to evaporitic materials on other planetary bodies such as Mars. A wide range of sample acquisition instruments (NASA drills, Small Planetary Impulse Tool (SPLIT) robotic hammer, universal sampling bags), analytical instruments (Raman spectroscopy, Close-Up Imager, Minion DNA sequencing technology, methane stable isotope analysis, biomolecule and metabolic life detection instruments) and environmental monitoring equipment (passive air particle sampler, particle detectors and environmental monitoring equipment) was deployed in an integrated campaign. Investigations included studying the geochemical signatures of chloride and sulphate evaporitic minerals, testing methods for life detection and planetary protection around human-tended operations, and investigations on the radiation environment of the deep subsurface. The MINAR analogue activity occurs in an active mine, showing how the development of space exploration technology can be used to contribute to addressing immediate Earth-based challenges. During the campaign, in collaboration with European Space Agency (ESA), MINAR was used for astronaut familiarization with future exploration tools and techniques. The campaign was used to develop primary and secondary school and primary to secondary transition curriculum materials on-site during the campaign which was focused on a classroom extra vehicular activity simulation.

With no large-scale granitic continental crust, all environments on Mars are fundamentally derived from basaltic sources or, in the case of environments such as ices, evaporitic, and sedimentary deposits, influenced by the composition of the volcanic crust. Therefore, the selection of samples on Mars by robots and humans for investigating habitability or testing for the presence of life should be guided by our understanding of the microbial ecology of volcanic terrains on the Earth. In this paper, we discuss the microbial ecology of volcanic rocks and hydrothermal systems on the Earth. We draw on microbiological investigations of volcanic environments accomplished both by microbiology-focused studies and Mars analog studies such as the NASA BASALT project. A synthesis of these data emphasises a number of common patterns that include: (1) the heterogeneous distribution of biomass and diversity in all studied materials, (2) physical, chemical, and biological factors that can cause heterogeneous microbial biomass and diversity from sub-millimetre scales to kilometre scales, (3) the difficulty of a priori prediction of which organisms will colonise given materials, and (4) the potential for samples that are habitable, but contain no evidence of a biota. From these observations, we suggest an idealised strategy for sample collection. It includes: (1) collection of multiple samples in any given material type (∼9 or more samples), (2) collection of a coherent sample of sufficient size (∼10 cm3∼10 cm³) that takes into account observed heterogeneities in microbial distribution in these materials on Earth, and (3) collection of multiple sample suites in the same material across large spatial scales. We suggest that a microbial ecology-driven strategy for investigating the habitability and presence of life on Mars is likely to yield the most promising sample set of the greatest use to the largest number of astrobiologists and planetary scientists.

Habitability is a widely used word in the geoscience, planetary science, and astrobiology literature, but what does it mean? In this review on habitability, we define it as the ability of an environment to support the activity of at least one known organism. We adopt a binary definition of “habitability” and a “habitable environment.” An environment either can or cannot sustain a given organism. However, environments such as entire planets might be capable of supporting more or less species diversity or biomass compared with that of Earth. A clarity in understanding habitability can be obtained by defining instantaneous habitability as the conditions at any given time in a given environment required to sustain the activity of at least one known organism, and continuous planetary habitability as the capacity of a planetary body to sustain habitable conditions on some areas of its surface or within its interior over geological timescales. We also distinguish between surface liquid water worlds (such as Earth) that can sustain liquid water on their surfaces and interior liquid water worlds, such as icy moons and terrestrial-type rocky planets with liquid water only in their interiors. This distinction is important since, while the former can potentially sustain habitable conditions for oxygenic photosynthesis that leads to the rise of atmospheric oxygen and potentially complex multicellularity and intelligence over geological timescales, the latter are unlikely to. Habitable environments do not need to contain life. Although the decoupling of habitability and the presence of life may be rare on Earth, it may be important for understanding the habitability of other planetary bodies

The assessment of environmental habitability potential involves measurement of the chemical and physical attributes of the system as well as their dynamic interplay. The environmental dynamics describe the availability of both energy sources and raw materials for meeting the requirements of organisms and for altering the environment. Energetic exchange can also determine the preservation potential for organic materials in the rock record. During its first year at Gale Crater, the Mars Science Laboratory payload has directly measured the chemistry and physical attributes, e.g., temperature, humidity, radiation, pressure, etc. of the martian atmosphere. Curiosity has also acquired chemical and mineralogical data, both from a wind drift deposit of fines and from two examples of a sedimentary rock formation in a region of Gale Crater called Yellowknife Bay, some 445 meters to the east of Bradbury Landing, where Curiosity initially touched down. These data enabled inferences to be made regarding depositional environment and past habitability potential at Gale Crater. The rock chemistry data reveal signs of aqueous interaction i.e., H2O, OH and H2 and sufficient elemental basis (C, H, O, S and possibly N) for plausible nutrient supply, should Mars have ever had autotrophic prokaryotes to exploit it, and a range of redox conditions tolerable to Earth microbes is indicated by the presence of clay minerals. Curiosity’s observations of the chemical, physical and geologic features of Yellowknife Bay point to a formerly habitable environment.

The ChemCam instrument onboard the Curiosity rover provides for the first time an opportunity to study martian soils at a sub-millimeter resolution. In this work, we analyzed 24 soil targets probed by ChemCam during the first 250 sols on Mars. Using the depth profile capability of the ChemCam LIBS (Laser-Induced Breakdown Spectroscopy) technique, we found that 45% of the soils contained coarse grains (>500 μm). Three distinct clusters have been detected: Cluster 1 shows a low SiO2 content; Cluster 2 corresponds to coarse grains with a felsic composition, whereas Cluster 3 presents a typical basaltic composition. Coarse grains from Cluster 2 have been mostly observed exposed in the vicinity of the landing site, whereas coarse grains from Clusters 1 and 3 have been detected mostly buried, and were found all along the rover traverse. The possible origin of these coarse grains was investigated. Felsic (Cluster 2) coarse grains have the same origin as the felsic rocks encountered near the landing site, whereas the origin of the coarse grains from Clusters 1 and 3 seems to be more global. Fine-grained soils (particle size < laser beam diameter which is between 300 and 500 μm) show a homogeneous composition all along the traverse, different from the composition of the rocks encountered at Gale. Although they contain a certain amount of hydrated amorphous component depleted in SiO2, possibly present as a surface coating, their overall chemical homogeneity and their close-to-basaltic composition suggest limited, or isochemical alteration, and a limited interaction with liquid water. Fine particles and coarse grains from Cluster 1 have a similar composition, and the former could derive from weathering of the latter. Overall martian soils have a bulk composition between that of fine particles and coarse grains. This work shows that the ChemCam instrument provides a means to study the variability of soil composition at a scale not achievable by bulk chemical analyses.

It is commonly accepted that the evolution of the human eye has been driven by the maximum intensity of the radiation emitted by the Sun. However, the interpretation of the surrounding environment is constrained not only by the amount of energy received but also by the information content of the radiation. Information is related to entropy rather than energy. The human brain follows Bayesian statistical inference for the interpretation of visual space. The maximization of information occurs in the process of maximizing the entropy. Here, we show that the photopic and scotopic vision absorption peaks in humans are determined not only by the intensity but also by the entropy of radiation. We suggest that through the course of evolution, the human eye has not adapted only to the maximum intensity or to the maximum information but to the optimal wavelength for obtaining information. On Earth, the optimal wavelengths for photopic and scotopic vision are 555 nm and 508 nm, respectively, as inferred experimentally. These optimal wavelengths are determined by the temperature of the star (in this case, the Sun) and by the atmospheric composition.

Thermodynamic disequilibrium is a necessary situation in a system in which complex emergent structures are created and maintained. It is known that most of the chemical disequilibrium, a particular type of thermodynamic disequilibrium, in Earth's atmosphere is a consequence of life. We have developed a thermochemical model for the Martian atmosphere to analyze the disequilibrium by chemical reactions calculating the entropy production. It follows from the comparison with the Earth atmosphere that the magnitude of the entropy produced by the recombination reaction forming O 3 (O + O 2 + CO 2 O 3 + CO 2) in the atmosphere of the Earth is larger than the entropy produced by the dominant set of chemical reactions considered for Mars, as a consequence of the low density and the poor variety of species of the Martian atmosphere. If disequilibrium is needed to create and maintain self-organizing structures in a system, we conclude that the current Martian atmosphere is unable to support large physico-chemical structures, such as those created on Earth.

The operating temperature of a solar cell determines its efficiency and performance. This temperature depends on the materials used to build the cell but also on the environmental variables surrounding it (i.e., radiation, ambient temperature, wind speed and humidity). Several equations have been proposed to calculate this temperature, depending on these variables. Also, for Earth conditions, simplifiedequations have been developed, but are not valid for other planets, as Mars, where the environmental conditions are extremely different.In this paper, we develop a simplified equation to calculate the temperature of a solar cell under Mars environmental conditions and discuss the effect that altitude and wind on Mars might have on the solar cell temperature. The correct determination of the operating temperature of the cell will help to optimize the design of the next solar cell powered rovers for the exploration of Mars.

The energy requirements of the planetary exploration spacecrafts constrain the lifetime of the missions, their mobility and capabilities, and the number of instruments onboard. They are limiting factors in planetary exploration. Several missions to the surface of Mars have proven the feasibility and success of solar panels as energy source. The analysis of the exergy efficiency of the solar radiation has been carried out successfully on Earth, however, to date, there is not an extensive research regarding the thermodynamic exergy efficiency of in-situ renewable energy sources on Mars. In this paper, we analyse the obtainable energy (exergy) from solar radiation under Martian conditions. For this analysis we have used the surface environmental variables on Mars measured in-situ by the Rover Environmental Monitoring Station onboard the Curiosity rover and from satellite by the Thermal Emission Spectrometer instrument onboard the Mars Global Surveyor satellite mission. We evaluate the exergy efficiency from solar radiation on a global spatial scale using orbital data for a Martian year; and in a one single location in Mars (the Gale crater) but with an appreciable temporal resolution (1 h). Also, we analyse the wind energy as an alternative source of energy for Mars exploration and compare the results with those obtained on Earth. We study the viability of solar and wind energy station for the future exploration of Mars, showing that a small square solar cell of 0.30 m length could maintain a meteorological station on Mars. We conclude that the low density of the atmosphere of Mars is responsible of the low thermal exergy efficiency of solar panels. It also makes the use of wind energy uneffective. Finally, we provide insights for the development of new solar cells on Mars.

Ultraviolet radiation from 10 to 420 nm reaching Mars Top of the Atmosphere (TOA) and surface is important in a wide variety of fields such as space exploration, climate modeling, and spacecraft design, as it has impact in the physics and chemistry of the atmosphere and soil. Despite the existence of databases for UV radiation reaching Earth TOA, based in space-borne instrumentation orbiting our planet, there is no similar information for Mars. Here we present a Mars TOA UV spectral irradiance database for solar cycle 24 (years 2008–2019), containing daily values from 10 to 420 nm. The values in this database have been computed using a model that is fed by the Earth-orbiting Solar Radiation and Climate Experiment (SORCE) data. As the radiation coming from the Sun is not completely isotropic, in order to eliminate the geometrically related features but being able to capture the general characteristics of the solar cycle stage, we provide 3-, 7- and 15-days averaged values at each wavelength. Our database is of interest for atmospheric modeling and spectrally dependent experiments on Mars, the analysis of current and upcoming surface missions (rovers and landers) and orbiters in Mars. Daily values for the TOA UV conditions at the rover Curiosity location, as well as for the NASA Insight mission in 2016, and ESA/Russia ExoMars mission in 2018 are provided.

VISTA (Volatile In Situ Thermogravimetry Analyser) is a µ-Thermogravimeter sensor developed by Consortium of Italian Institutes. ThermoGravimetric Analysis (TGA) is a widely used technique to monitor thermal processes involving volatile compounds, e.g. deposition/sublimation and absorption/ desorption. The instrument core is composed by a Piezoelectric Crystal Microbalance (PCM), equipped with built-in heater and built-in temperature sensor, and provided of its own Proximity Electronics (PE). The PCM oscillation frequency linearly depends on the mass deposited on its sensible area (according to Sauerbrey equation) while the PCM temperature can be increased by means of integrated heaters. Thus, mass and volatile composition can be inferred by the frequency change and by desorption temperature, respectively. The instrument is divided in two sensor heads: VISTA1, able to monitor outgassing processes in space, and VISTA2, able to reach higher temperatures, studying the dehydration and organics decomposition in minerals in different environmental conditions. An Engineering Model of VISTA1 and a laboratory breadboard of VISTA2 have been developed. Pure organic compounds and contaminant have been characterized by using deposition processes and TGA cycles obtaining some physical-chemical parameters, i.e. enthalpy of sublimation/evaporation, ΔHHsub,evap , deposition rates, kk and vapor pressures, Pvap . The instrument concept, the scientific objectives and the laboratory measurements are explained in this work.

The rover Curiosity is conducting X-ray diffraction experiments on the surface of Mars using the CheMin instrument. The analyses enable identification of the major and minor minerals, providing insight into the conditions under which the samples were formed or altered and, in turn, into past habitable environments on Mars. The CheMin instrument was developed over a twenty-year period, mainly through the efforts of scientists and engineers from NASA and DOE. Results from the first four experiments, at the Rocknest, John Klein, Cumberland, and Windjana sites, have been received and interpreted. The observed mineral assemblages are consistent with an environment hospitable to Earth-like life, if it existed on Mars.

A methodology to couple Numerical Weather Prediction (NWP) models with steady-state Computational Fluid Dynamic (CFD) models for wind resource assessment applications is proposed. NWP simulations are averaged according to their atmospheric stability and wind direction. The averaged NWP simulations are used to generate the initial and boundary conditions of the CFD model. The method is applied using one year of Weather Research and Forecasting (WRF) simulations at the Honkajoki wind farm in Finland and validated by Sonic Detection and Ranging (SODAR) measurements at the site. It is shown that coupled simulations reproduce a more realistic shear for heights above 150 m. In terms of estimated energy production, there is not a big difference between coupled and standalone models. Nevertheless, a considerable difference in the horizontal wind speed patterns can be seen between the coupled and non-coupled approaches. The WRF model resolution has only a small influence on the coupled CFD results.

For data analysis of the Michelson Interferometer for Passive Atmospheric Sounding (MIPAS) atmospheric limb emission spectroscopic experiment on Environmental Satellite microwindows, i.e., small spectral regions for data analysis, have been defined and optimized. A novel optimization scheme has been developed for this purpose that adjusts microwindow boundaries such that the total retrieval error with respect to measurement noise, parameter uncertainties, and systematic errors is minimized. Dedicated databases that contain optimized microwindows for retrieval of vertical profiles of pressure and temperature, H2O, O3, HNO3, CH4, N2O, and NO2 have been generated. Furthermore, a tool for optimal selection of subsets of predefined microwindows for specific retrieval situations has been provided. This tool can be used further for estimating total retrieval errors for a selected microwindow subset. It has been shown by use of this tool that an altitude-dependent definition of microwindows is superior to an altitude-independent definition. For computational efficiency a dedicated microwindow-related list of spectral lines has been defined that contains only those spectral lines that are of relevance for MIPAS limb sounding observations.

The Graduate School of Space Technology

Methane has been detected on all planets of our Solar System, and most of the larger moons, as well as in dwarf-planets like Pluto and Eric. The presence of this molecule in rocky planets is very interesting because its presence in the Earth's atmosphere is mainly related to biotic processes. Space instrumentation in orbiters around Mars has detected olivine on the Martian soil and dust. On the other hand the measurements of methane from the Curiosity rover report detection of background levels of atmospheric methane with abundance that is lower than model estimates of ultraviolet degradation of accreted interplanetary dust particles or carbonaceous chondrite material. Additionally, elevated levels of methane about this background have been observed implying that Mars is episodically producing methane from an additional unknown source, making the reasons of these temporal fluctuations of methane a hot topic in planetary research. The goal of this study is to investigate at atomic level the interactions during the adsorption processes of methane and other Mars atmospheric species (CO₂, H₂O) on forsterite surfaces, through electronic structure calculations based on the Density Functional Theory (DFT). We propose two models to simulate the interaction of adsorbates with the surface of dust mineral, such as binary mixtures (5CH₄+5H₂O/5CH₄+5CO₂) and as a semi-clathrate adsorption. We have obtained interesting results of the adsorption process in the mixture 5CH₄+5CO₂. Associative and dissociative adsorptions were observed for water and CO₂ molecules. The methane molecules were only trapped and held by water or CO₂ molecules. In the dipolar surface, the adsorption of CO₂ molecules produced new species: one CO from a CO₂ dissociation, and, two CO₂ molecules chemisorbed to mineral surface forming a carbonate group. Our results suggest that CO₂ has a strong interaction with the mineral surface when methane is present. These results could be confirmed after the analysis of the data from the upcoming remote and in-situ observations on Mars, as those to be performed by instruments on the ESA's ExoMars Trace Gas Orbiter and ExoMars rover.

Titanium dioxide TiO₂ is one of the most studied oxides in photocatalysis, due to its electronic structure and its wide variety of applications, such as gas sensors and biomaterials, and especially in methane-reforming catalysis. Titanium dioxide and olivine have been detected both on Mars and our Moon. It has been postulated that on Mars photocatalytic processes may be relevant for atmospheric methane fluctuation, radicals and perchlorate productions etc. However, to date no investigation has been devoted to modelling the properties of TiO₂ adsorbed on olivine surface.

The goal of this study is to investigate at atomic level with electronic structure calculations based on the Density Functional Theory (DFT), the atomic interactions that take place during the adsorption processes for formation of a TiO regolith. This model is formed with different TiO films adsorbed on olivine (forsterite) surfaces, one of the most common minerals in Universe, Earth, Mars, cometary and interstellar dust. We propose three regolith models to simulate the principal phase of titanium oxide (TiO, Ti₂O₃ and TiO₂). The models show different adsorption processes i.e. physisorption and chemisorption. Our results suggest that the TiO is the most reactive phase and produces a strong exothermic effect. Besides, we have detailed, from a theoretical point of view, the effect that has the adsorption process in the electronic properties such as electronic density of state (DOS) and oxide reduction process (redox). This theoretical study can be important to understand the formation of new materials (supports) that can be used as support in the catalytic processes that occur in the Earth, Mars and Moon. Also, it may be important to interpret the present day photochemistry and interaction of regolith and airborne aerosols in the atmosphere on Mars or to define possible catalytic reactions of the volatiles captured on the Moon regolith.

Perchlorates have been found widespread on the surface of Mars, their origin and degradation pathways are not understood to date yet. We investigate here, from a theoretical point of view, the potential redox processes that take place in the interaction of Martian minerals such as olivine, with anhydrous and hydrated perchlorates. For this theoretical study, we take as mineral substrate the (1 0 0) surface of forsterite and calcium perchlorate salt as adsorbate. Our DFT calculations suggests a reduction pathway to chlorate and chlorite. When the perchlorate has more than 4 water molecules, this mechanism, which does not require high-temperature or high energy sources, results in parallel with the oxidation of the mineral surface, forming magnesium peroxide, MgO2, and in the formation of ClO3, which through photolysis is known to form ClO-O2. Because of the high UV irradiance that reaches the surface of Mars, this may be a source of O2 on Mars. Our results suggest that this process may be a natural removal pathway for perchlorates from the Martian regolith, which in the presence of atmospheric water for salt hydration, can furthermore lead to the production of oxygen. This mechanism may thus have implications on the present and future habitability of the Martian surface.

We determined radiogenic and cosmogenic noble gases in a mudstone on the floor of Gale Crater. A K-Ar age of 4.21 ± 0.35 billion years represents a mixture of detrital and authigenic components and confirms the expected antiquity of rocks comprising the crater rim. Cosmic-ray-produced 3He, 21Ne, and 36Ar yield concordant surface exposure ages of 78 ± 30 million years. Surface exposure occurred mainly in the present geomorphic setting rather than during primary erosion and transport. Our observations are consistent with mudstone deposition shortly after the Gale impact or possibly in a later event of rapid erosion and deposition. The mudstone remained buried until recent exposure by wind-driven scarp retreat. Sedimentary rocks exposed by this mechanism may thus offer the best potential for organic biomarker preservation against destruction by cosmic radiation.

High-altitude balloons and rockets are regularly launched at the Esrange Space Center (ESC) in Kiruna, Sweden, with the aim of retrieving atmospheric data for meteorological and space studies in the Arctic region. Meteorological conditions, particularly wind direction and speed, play a critical role in the decision of whether to go ahead with or postpone a planned launch. Given the lack of high-resolution wind forecasts for this remote region, the Weather Research and Forecasting (WRF) Model is used to downscale short-term forecasts given by the Global Forecast System (GFS) for the ESC for six 5-day periods in the warm, cold, and transition seasons. Three planetary boundary layer (PBL) schemes are considered: the local Mellor-Yamada-Janjic' (MYJ), the nonlocal Yonsei University (YSU), and the hybrid local-nonlocal Asymmetric Convective Model 2 (ACM2). The ACM2 scheme is found to provide the most skillful forecasts. An analysis of the WRF Model output against the launch criteria for two of the most commonly launched vehicles, the sounding rockets Veículo de Sondagem Booster-30 (VSB-30) and Improved Orion, reveals probability of detection (POD) values that always exceeds 60% with the false alarm rate (FAR) generally below 50%. It is concluded that the WRF Model, in its present configuration, can be used to generate useful 5-day wind forecasts for the launches of these two rockets. The conclusions reached here are applicable to similar sites in the Arctic and Antarctic regions.

We have used the Weather Research and Forecasting (WRF) model to simulate the climate of the Kerguelen Islands (49° S, 69° E) and investigate its inter-annual variability. Here, we have dynamically downscaled 30 years of the Climate Forecast System Reanalysis (CFSR) over these islands at 3-km horizontal resolution. The model output is found to agree well with the station and radiosonde data at the Port-aux-Français station, the only location in the islands for which observational data is available. An analysis of the seasonal mean WRF data showed a general increase in precipitation and decrease in temperature with elevation. The largest seasonal rainfall amounts occur at the highest elevations of the Cook Ice Cap in winter where the summer mean temperature is around 0 °C. Five modes of variability are considered: conventional and Modoki El Niño-Southern Oscillation (ENSO), Indian Ocean Dipole (IOD), Subtropical IOD (SIOD) and Southern Annular Mode (SAM). It is concluded that a key mechanism by which these modes impact the local climate is through interaction with the diurnal cycle in particular in the summer season when it has a larger magnitude. One of the most affected regions is the area just to the east of the Cook Ice Cap extending into the lower elevations between the Gallieni and Courbet Peninsulas. The WRF simulation shows that despite the small annual variability, the atmospheric flow in the Kerguelen Islands is rather complex which may also be the case for the other islands located in the Southern Hemisphere at similar latitudes.

In this paper we use the Mars implementation of the Planet Weather Research and Forecasting model, MarsWRF, to simulate the Entry, Descent and Landing (EDL) vertical profiles from six past missions: Pathfinder, Mars Exploration Rovers Opportunity and Spirit, Phoenix, Mars Science Laboratory Curiosity rover and ExoMars 2016 (Schiaparelli), and compare the results with observed data. In order to investigate the sensitivity of the model predictions to the atmospheric dust distribution, MarsWRF is run with two prescribed dust scenarios. It is concluded that the MarsWRF EDL predictions can be used for guidance into the design and planning stage of future missions to the planet, as it generally captures the observed EDL profiles, although it has a tendency to underestimate the temperature and overestimate the density for heights above 15 km. This could be attributed to an incorrect representation of the observed dust loading. We have used the model to predict the EDL conditions that may be encountered by two future missions: ExoMars 2020 and Mars 2020. When run for Oxia Planum and Jezero Crater for the expected landing time, MarsWRF predicts a large sensitivity to the dust loading in particular for the horizontal wind speed above 10‐15 km with maximum differences of up to ±30 m s‐1 for the former and ±15 m s‐1 for the latter site. For both sites, the best time for EDL, i.e. when the wind speed is generally the weakest with smaller shifts in direction, is predicted to be in the late morning and early afternoon.

Good knowledge of the environmental conditions of deserts on Earth is relevant forclimate studies. The Atacama Desert is of particular interest as it is considered tobe the driest region on Earth. We have performed simulations using the WeatherResearch and Forecasting (WRF) model over the Atacama Desert for two week-longperiods in the austral winter season coincident with surface temperature and relativehumidity in-situ observations at three sites. We found that the WRF model generallyoverestimates the daytime surface temperature, with biases of up to 11◦C, despitegiving a good simulation of the relative humidity. In order to improve the agree-ment with observed measurements, we conducted sensitivity experiments in whichthe surface albedo, soil moisture content and five tuneable parameters in the NoahLand Surface Model (namely soil porosity, soil suction, saturated soil hydraulic con-ductivity, thebparameter used in hydraulic functions and the quartz fraction) areperturbed. We concluded that an accurate simulation is not possible, most likelybecause the Noah Land Surface Model does not have a groundwater table that maybe shallow in desert regions. The WRF-predicted land surface temperature is alsoevaluated against that estimated from the Moderate Resolution Imaging Spectrora-diometer (MODIS) instrument. While at night the satellite-derived and ground-basedmeasurements are generally in agreement, during the day MODIS estimates aretypically lower by as much as 17◦C. This is attributed to the large uncertainty inthe MODIS-estimated land surface temperatures in arid and semi-arid regions. Thefindings of this work highlight the need for ground-based observational networksin remote regions such as the Atacama Desert where satellite-derived and modelproducts may not be very accurate.

The Mars implementation of the Planet Weather Research and Forecasting (PlanetWRF) model, MarsWRF, is used here to simulate the atmospheric conditions at Gale Crater for different seasons during a period coincident with the Curiosity rover operations. The model is first evaluated with the existing single-point observations from the Rover Environmental Monitoring Station (REMS), and is then used to provide a larger scale interpretation of these unique measurements as well as to give complementary information where there are gaps in the measurements.

The variability of the planetary boundary layer depth may be a driver of the changes in the local dust and trace gas content within the crater. Our results show that the average time when the PBL height is deeper than the crater rim increases and decreases with the same rate and pattern as Curiosity's observations of the line-of-sight of dust within the crater and that the season when maximal (minimal) mixing is produced is L_s 225°-315° (L_s 90°-110°). Thus the diurnal and seasonal variability of the PBL depth seems to be the driver of the changes in the local dust content within the crater. A comparison with the available methane measurements suggests that changes in the PBL depth may also be one of the factors that accounts for the observed variability, with the model results pointing towards a local source to the north of the MSL site.

The interaction between regional and local flows at Gale crater is also investigated assuming that the meridional wind, the dynamically important component of the horizontal wind at Gale, anomalies with respect to the daily mean can be approximated by a sinusoidal function as they typically oscillate between positive (south to north) and negative (north to south) values that correspond to upslope/downslope or downslope/upslope regimes along the crater rim and Mount Sharp slopes and the dichotomy boundary. The smallest magnitudes are found in the northern crater floor in a region that comprises Bradbury Landing, in particular at L_s 90° when they are less than 1 m s⁻¹, indicating very little lateral mixing with outside air. The largest amplitudes occur in the south-western portions of the crater where they can exceed 20 m s⁻¹. Should the slope flows along the crater rims interact with the dichotomy boundary flow, which is more likely at L_s 270° and very unlikely at L_s 90°, they are likely to interact constructively for a few hours from late evening to nighttime (∼17-23 LMST) and from pre-dawn early morning (∼5-11 LMST) hours at the norther crater rim and destructively at night (∼22-23 LMST) and in the morning (∼10-11 LMST) at the southern crater rim.

We conclude that a better understanding of the PBL and circulation dynamics has important implications for the variability of the concentration of dust, non-condensable and trace gases at the bottom of other craters on Mars as mixing with outside air can be achieved vertically, through changes in the PBL depth, and laterally, by the transport of air into and out of the crater.

The Sample Analysis at Mars (SAM) instrument [Mahaffy et al., 2012] onboard the Mars Science Laboratory (MSL) Curiosity rover is designed to conduct inorganic and organic chemical analyses of the atmosphere and the surface regolith and rocks to help evaluate the past and present habitability potential of Mars at Gale Crater [Grotzinger et al., 2012]. Central to this task is the development of an inventory of any organic molecules present to elucidate processes associated with their origin, diagenesis, concentration and long-term preservation. This will guide the future search for biosignatures [Summons et al., 2011]. Here we report the definitive identification of chlorobenzene (150–300 parts per billion by weight (ppbw)) and C2 to C4 dichloroalkanes (up to 70 ppbw) with the SAM gas chromatograph mass spectrometer (GCMS), and detection of chlorobenzene in the direct evolved gas analysis (EGA) mode, in multiple portions of the fines from the Cumberland drill hole in the Sheepbed mudstone at Yellowknife Bay. When combined with GCMS and EGA data from multiple scooped and drilled samples, blank runs and supporting laboratory analog studies, the elevated levels of chlorobenzene and the dichloroalkanes cannot be solely explained by instrument background sources known to be present in SAM. We conclude that these chlorinated hydrocarbons are the reaction products of martian chlorine and organic carbon derived from martian sources (e.g. igneous, hydrothermal, atmospheric, or biological) or exogenous sources such as meteorites, comets or interplanetary dust particles.

Atmospheric emissions at 5.3 μm will be measured by the Michelson Interferometer for Passive Atmospheric Sounding (MIPAS), a high-resolution limb sounder on board the European polar platform ENVISAT, scheduled to be launched in 2001. Measured spectra at 5.3 μm contain information on important atmospheric quantities such as NO volume mixing ratio, thermospheric temperature, and chemical NO production rates. However, the scientific analysis of this spectral region has to deal with complex non-local thermodynamic equilibrium (non-LTE) effects. A conventional non-LTE retrieval approach using ab initio vibrational temperatures cannot be applied due to rotational and spin-orbit non-LTE of NO in the thermosphere, and the dependence of NO state populations on the NO abundance itself caused by chemical excitations. An innovative non-LTE retrieval method enabling the treatment of vibrational, rotational, and spin non-LTE as well as a dependence of the non-LTE state distribution on the retrieval target quantities has thus been developed for the MIPAS data analysis. The ability of the developed non-LTE inversion tool to retrieve NO abundance profiles, thermospheric temperature profiles, and NO mean production rates by NO2 photolysis in the stratosphere and N+O2 combination in the thermosphere is demonstrated by means of a feasibility study.

The Sample Analysis at Mars (SAM) instrument onboard the Mars Science Laboratory Curiosity rover measures the chemical composition of major atmospheric species (CO₂, N₂, ⁴⁰Ar, O₂, and CO) through a dedicated atmospheric inlet. We report here measurements of volume mixing ratios in Gale Crater using the SAM quadrupole mass spectrometer, obtained over a period of nearly 5 years (3 Mars years) from landing. The observation period spans the northern summer of MY 31 and solar longitude (L_S) of 175° through spring of MY 34, L_S = 12°. This work expands upon prior reports of the mixing ratios measured by SAM QMS in the first 105 sols of the mission. The SAM QMS atmospheric measurements were taken periodically, with a cumulative coverage of four or five experiments per season on Mars. Major observations include the seasonal cycle of CO₂, N₂, and Ar, which lags approximately 20–40° of L_S behind the pressure cycle driven by CO₂ condensation and sublimation from the winter poles. This seasonal cycle indicates that transport occurs on faster timescales than mixing. The mixing ratio of O₂ shows significant seasonal and interannual variability, suggesting an unknown atmospheric or surface process at work. The O₂ measurements are compared to several parameters, including dust optical depth and trace CH₄ measurements by Curiosity. We derive annual mean volume mixing ratios for the atmosphere in Gale Crater: CO₂ = 0.951 (±0.003), N₂ = 0.0259 (±0.0006), ⁴⁰Ar = 0.0194 (±0.0004), O₂ = 1.61 (±0.09) x 10^‐3, and CO = 5.8 (±0.8) x 10^‐4.