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  • 1.
    Bhattacharyya, Shubhankar
    et al.
    Luleå tekniska universitet, Institutionen för samhällsbyggnad och naturresurser, Kemiteknik.
    Filippov, Andrei
    Luleå tekniska universitet, Institutionen för samhällsbyggnad och naturresurser, Kemiteknik. Institute of Physics, Kazan Federal University, Russia.
    Shah, Faiz Ullah
    Luleå tekniska universitet, Institutionen för samhällsbyggnad och naturresurser, Kemiteknik.
    High CO2 absorption capacity by chemisorption at cations and anions in choline-based ionic liquids2017Inngår i: Physical Chemistry, Chemical Physics - PCCP, ISSN 1463-9076, E-ISSN 1463-9084, Vol. 19, nr 46, s. 31216-31226Artikkel i tidsskrift (Fagfellevurdert)
    Abstract [en]

    The effect of CO2 absorption on the aromaticity and hydrogen bonding in ionic liquids is investigated. Five different ionic liquids with choline based cations and aprotic N-heterocyclic anions were synthesized. Purity and structures of the synthesized ionic liquids were characterized by 1H and 13C NMR spectroscopy. CO2 capture performance was studied at 20 °C and 40 °C under three different pressures (1, 3, 6 bar). The IL [N1,1,6,2OH][4-Triz] showed the highest CO2 capture capacity (28.6 wt%, 1.57 mol of CO2 per mol of the IL, 6.48 mol of CO2 per kg of the ionic liquid) at 20 °C and 1 bar. The high CO2 capture capacity of the [N1,1,6,2OH][4-Triz] IL is due to the formation of carbonic acid (–OCO2H) together with carbamate by participation of the –OH group of the [N1,1,6,2OH]+ cation in the CO2 capture process. The structure of the adduct formed by CO2 reaction with the IL [N1,1,6,2OH][4-Triz] was probed by using IR, 13C NMR and 1H–13C HMBC NMR experiments utilizing 13C labeled CO2 gas. 1H and 13C PFG NMR studies were performed before and after CO2 absorption to explore the effect of cation–anion structures on the microscopic ion dynamics in ILs. The ionic mobility was significantly increased after CO2 reaction due to lowering of aromaticity in the case of ILs with aromatic N-heterocyclic anions.

  • 2.
    Bhattacharyya, Shubhankar
    et al.
    Luleå tekniska universitet, Institutionen för samhällsbyggnad och naturresurser, Kemiteknik.
    Filippov, Andrei
    Luleå tekniska universitet, Institutionen för samhällsbyggnad och naturresurser, Kemiteknik.
    Shah, Faiz Ullah
    Luleå tekniska universitet, Institutionen för samhällsbyggnad och naturresurser, Kemiteknik.
    Insights into the Effect of CO2 Absorption on the Ionic Mobility of Ionic Liquids2016Inngår i: Physical Chemistry, Chemical Physics - PCCP, ISSN 1463-9076, E-ISSN 1463-9084, Vol. 18, nr 41, s. 28617-28625Artikkel i tidsskrift (Fagfellevurdert)
    Abstract [en]

    We investigate a comparative effect of CO2 absorption on the ionic mobility of two choline based ionic liquids comprising two different anions such as threonine and imidazole. The synthesized ionic liquids were characterized using 1H and 13C NMR and other spectroscopic techniques. By keeping a common cation and changing the anion from threonine to imidazole both the viscosity and density reduced drastically. We found that [N1,1,6,2OH][Imi] exhibits the highest CO2 capture capacity at 20 °C of 5.27 mol of CO2 per kg of ionic liquid (1.27 mol of CO2 per mol of ionic liquid, 23.26 wt% of CO2) whereas [N1,1,6,2OH][Threo] exhibits 3.6 mol of CO2 per kg of ionic liquid (1.05 mol of CO2 per mol of ionic liquid, 15.87 wt% of CO2). The activation energy for diffusion is calculated using the Vogel-Fulcher-Tamman (VFT) equation in the form of diffusivity. It was found that the activation energy for the diffusion of [N1,1,6,2OH][Threo] is ∼10 times higher than that of [N1,1,6,2OH][Imi]. 1H diffusion NMR data revealed that the diffusivity of [N1,1,6,2OH][Imi] is increased after CO2 absorption whereas a decrease in diffusivity was observed in the case of [N1,1,6,2OH][Threo]. This anomalous behavior of [N1,1,6,2OH][Imi] was further explained by using DFT calculations.

  • 3.
    Bhattacharyya, Shubhankar
    et al.
    Synthetic Chemistry Division, Defense R and D Establishment.
    Hatua, Kaushik
    Department of Chemistry, Bengal Engineering and Science University.
    Computational insight of the mechanism of Algar-Flynn-Oyamada (AFO) reaction2014Inngår i: RSC Advances, ISSN 2046-2069, E-ISSN 2046-2069, Vol. 4, nr 36, s. 18702-18709Artikkel i tidsskrift (Fagfellevurdert)
    Abstract [en]

    The present DFT investigation supports a previous conclusion of Dean et al. that hydroxylation occurs without epoxide intermediate at room temperature due to a strong electrostatic interaction of peroxide ions with π electrons of CC bonds of chalcone, and 3-hydroxyflavone has been found to be the major product. The calculated activation energy difference (ΔG#) of initial enolization followed by hydroxylation or simultaneous cyclization and hydroxylation has been found to be negligible (∼4 kcal mol-1). On the other hand, epoxide formation requires significant activation energy, which is supposed to occur at high temperatures. In addition, if epoxide is formed, the ring opens by an attack of phenolic oxygen, occurring preferentially at α position via a five-member transition state due to a low activation barrier height (19.82 kcal mol-1 in the gas phase and 19.55 kcal mol-1 in ethanol) compared to that of a six-member transition state (44.41 kcal mol-1 at B3LYP in the gas phase and 38.55 kcal mol -1 in ethanol). It is also observed that the solvation study does not affect the main conclusion of the paper. These findings also support the previous observation of Dean et al. Predicted ΔG# in different DFT functionals are consistent, although the total energy is significantly different

  • 4.
    Bhattacharyya, Shubhankar
    et al.
    Luleå tekniska universitet, Institutionen för samhällsbyggnad och naturresurser, Kemiteknik.
    Kaushik, Hatua
    Department of Chemistry, IIEST, Shibpur.
    Theoretical investigation of banert cascade reaction2018Inngår i: Royal Society Open Science, E-ISSN 2054-5703, Vol. 5, nr 4, artikkel-id 171075Artikkel i tidsskrift (Fagfellevurdert)
    Abstract [en]

    Computational inside of Banert cascade reaction for triazole formation is studied with B3LYP/6-31G(d,p) level of theory. The reaction proceeds mainly by SN2 initial chloride displacement rather than SN2 -type attack. Furthermore, according to the rate of reaction calculation, SN2 displacement is much faster than SN2 displacement in the order of 8. The [3,3]-sigmatropic rearrangement for the conversion of propargyl azide into triazafulvene has been proved as the rate-determining step having highest activation energy parameter. Solvent effect on total course of reaction has been found negligible. Furthermore, effects of different density functional theory functionals and functional groups on activation energies of [3,3]-sigmatropic rearrangement of propargyl azide were also studied. BHHLYP, ωB97XD, M062X and BMK calculated ∆G are consistent with B3LYP.

  • 5.
    Bhattacharyya, Shubhankar
    et al.
    Synthetic Chemistry Division, Defence R and D Establishment.
    Pathak, Uma
    Synthetic Chemistry Division, Defence R and D Establishment.
    A single-reagent-driven multistep one-pot preparation of thiazolines and 1,3-thiazines from aldoximes, nitriles, and carboxylic acids2015Inngår i: Synthesis (Stuttgart), ISSN 0039-7881, E-ISSN 1437-210X, Vol. 47, nr 22, s. 3553-3560, artikkel-id ss-2015-n0248-opArtikkel i tidsskrift (Fagfellevurdert)
    Abstract [en]

    N-(ω-Bromoalkyl)dichlorothiophosphoramidates have been designed as a new class of reagent for the single-reagent-driven multistep preparation of 2-substituted thiazolines and 1,3-thiazines from ald-oximes, nitriles, or carboxylic acids. A wide range of substrates both aromatic as well as aliphatic were investigated and found suitable for the developed protocol

  • 6.
    Bhattacharyya, Shubhankar
    et al.
    Synthetic Chemistry Division, Defence R and D Establishment.
    Pathak, Uma
    Synthetic Chemistry Division, Defence R and D Establishment.
    Mathur, Sweta
    Synthetic Chemistry Division, Defence R and D Establishment.
    Vishnoi, Subodh
    Synthetic Chemistry Division, Defence R and D Establishment.
    Jain, Rajeev
    School of Studies in Chemistry, Jiwaji University.
    Selective N-alkylation of primary amines with R-NH2·HBr and alkyl bromides using a competitive deprotonation/protonation strategy2014Inngår i: RSC Advances, ISSN 2046-2069, E-ISSN 2046-2069, Vol. 4, nr 35, s. 18229-18233Artikkel i tidsskrift (Fagfellevurdert)
    Abstract [en]

    Monoalkylation of primary amines using amine hydrobromides and alkyl bromides has been carried out. Under controlled reaction conditions the reactant primary amine was selectively deprotonated and made available for reaction, while the newly generated secondary amine remained protonated, and did not participate in alkylation further. Reaction was carried out under mild reaction conditions and was applicable to a wide range of primary amines and alkyl bromides.

  • 7.
    Bhattacharyya, Shubhankar
    et al.
    Luleå tekniska universitet, Institutionen för samhällsbyggnad och naturresurser, Kemiteknik.
    Shah, Faiz Ullah
    Luleå tekniska universitet, Institutionen för samhällsbyggnad och naturresurser, Kemiteknik.
    Ether Functionalized Choline Tethered Amino Acid Ionic Liquids for Enhanced CO2 Capture2016Inngår i: A C S Sustainable Chemistry & Engineering, ISSN 2168-0485, Vol. 4, nr 10, s. 5441-5449Artikkel i tidsskrift (Fagfellevurdert)
    Abstract [en]

    Amino acid ionic liquids (ILs) are the most interesting and effective for CO2 capture due to their low toxicity, biodegradability and fast reactivity towards CO2. Ionic nature of amino acid ILs can raise an environmental issue if the cation counterpart becomes toxic to the aquatic ecosystems and can become potential atmospheric pollutant. In this regard, choline based ILs are known to be promising scaffolds for the development of less toxic amino acid ILs. However, the existing choline amino acid ILs are highly viscous limiting their applicability as solvents. Ether functionalized choline based amino acid ILs with novel series of less toxic green ILs were explored with reduced viscosity and high CO2 capture capacity. A simple, economic, clean and environmentally benign method was utilized for the synthesis of novel choline based amino acid ILs using a commercially available and economical starting material 2-(dimethylamino)ethanol (deanol, a human dietary food supplement). Reported ILs have low viscosity with high CO2 capture capacity (1.62 mol of CO2 /mol of IL, 4.31 mol of CO2/kg of IL, 19.02 wt.% of CO2). Mechanism of [N1,1,6,2O4][Lys]+CO2 reaction and adduct structure was proposed by means of DFT and NMR.

  • 8.
    Bhattacharyya, Shubhankar
    et al.
    Luleå tekniska universitet, Institutionen för samhällsbyggnad och naturresurser, Kemiteknik.
    Shah, Faiz Ullah
    Luleå tekniska universitet, Institutionen för samhällsbyggnad och naturresurser, Kemiteknik.
    Functionalized Choline Based Amino Acid Ionic Liquids: Scope Of Bio-ILs2016Konferansepaper (Fagfellevurdert)
  • 9.
    Bhattacharyya, Shubhankar
    et al.
    Luleå tekniska universitet, Institutionen för samhällsbyggnad och naturresurser, Kemiteknik.
    Shah, Faiz Ullah
    Luleå tekniska universitet, Institutionen för samhällsbyggnad och naturresurser, Kemiteknik.
    Thermal stability of choline based amino acid ionic liquids2018Inngår i: Journal of Molecular Liquids, ISSN 0167-7322, E-ISSN 1873-3166, Vol. 266, s. 597-602Artikkel i tidsskrift (Fagfellevurdert)
    Abstract [en]

    Thermal stability of different choline based amino acid ionic liquids were studied. Both short term as well as long term thermal studies were carried out. Long term thermal studies of all ILs were carried out by isothermal TGA and short term thermal studies were measured by temperature ramped TGA. Isothermal TGA were studied at two different temperatures 100 °C and 150 °C for 500 min. Whereas, short term thermal stability represents as T2%, T5% and T10% which are the temperature at which 2%, 5% and 10% mass loss of ILs were observed. The effect of alkyl side chain on the cation, etherification of the cation as well structural variation of anion on the thermal stability of choline based ILs were investigated. It was observed that thermal characteristics of ILs towards temperature ramped TGA were different compared to isothermal TGA.

  • 10.
    Filippov, Andrei
    et al.
    Luleå tekniska universitet, Institutionen för samhällsbyggnad och naturresurser, Kemiteknik.
    Azancheev, Nail
    Institute of Physics, Kazan Federal University, Kazan, Russia.
    Gibaydullin, Amal
    Institute of Physics, Kazan Federal University, Kazan, Russia.
    Bhattacharyya, Shubhankar
    Luleå tekniska universitet, Institutionen för samhällsbyggnad och naturresurser, Kemiteknik.
    Antzutkin, Oleg N.
    Luleå tekniska universitet, Institutionen för samhällsbyggnad och naturresurser, Kemiteknik.
    Shah, Faiz Ullah
    Luleå tekniska universitet, Institutionen för samhällsbyggnad och naturresurser, Kemiteknik.
    Dynamic Properties of Imidazolium Orthoborate Ionic Liquids Mixed with Polyethylene Glycol Studied by NMR Diffusometry and Impedance Spectroscopy2018Inngår i: Magnetic Resonance in Chemistry, ISSN 0749-1581, E-ISSN 1097-458X, Vol. 56, nr 2, s. 113-119Artikkel i tidsskrift (Fagfellevurdert)
    Abstract [en]

    We used 1H pulsed field gradient (PFG) NMR to study the self-diffusion of polyethylene glycol (PEG) with average molecular mass of 200 and ions in mixtures of PEG with imidazolium bis(mandelato)borate (BMB) and imidazolium bis(oxalato)borate (BOB) ionic liquids (ILs). The ionic liquid was mixed with PEG in the concentration range of 0–100 wt%. Within the temperature range of 295 to 353 K, the diffusion coefficient of BMB is slower than that of the imidazolium cation. The diffusion coefficients of PEG, as well as the imidazolium cation and BMB anions, differ under all experimental conditions tested. This demonstrates that the IL in the mixture is present in at least a partially dissociated state. Generally, increasing the concentration of PEG leads to an increase in the diffusion coefficients of PEG and both the ions, and decreases their activation energy for diffusion. NMR chemical shift alteration analysis showed that the presence of PEG changes the chemical shifts of both ions but in different directions. Impedance spectroscopy was used to measure the ionic conductivity of the ionic liquids mixed with PEG.

  • 11.
    Filippov, Andrei
    et al.
    Luleå tekniska universitet, Institutionen för samhällsbyggnad och naturresurser, Kemiteknik. Institute of Physics, Kazan Federal University, Russia.
    Bhattacharyya, Shubhankar
    Luleå tekniska universitet, Institutionen för samhällsbyggnad och naturresurser, Kemiteknik.
    Shah, Faiz Ullah
    Luleå tekniska universitet, Institutionen för samhällsbyggnad och naturresurser, Kemiteknik.
    CO2 absorption and ion mobility in aqueous choline-based ionic liquids2019Inngår i: Journal of Molecular Liquids, ISSN 0167-7322, E-ISSN 1873-3166, Vol. 276, s. 748-752Artikkel i tidsskrift (Fagfellevurdert)
    Abstract [en]

    CO2 absorption and ion mobility are investigated in a series of 50/50 wt% aqueous solutions of choline-based ionic liquids with different cations and anions: [N1,1,4,2OH][Threo], [N1,1,5,2OH][Threo], [N1,1,6,2OH][Threo], [N1,1,5,2OH][β-ala] and [N1,1,5,2OH][Tau]. The process of CO2 absorption was completed in an hour reaching maximum of absorption capacity 0.07–0.10 wt% to ionic liquid (by 0.4–0.6 molar ratios). A rapid CO2 absorption is observed by the formation of solid product as a result of reaction between CO2 molecule and the ionic liquid. Diffusion coefficients of the cation and anion in the mixture are comparable while the diffusivity of water molecules is found to be quite different from the ions. In the process of CO2 absorption, an increase in the diffusivity of ions is observed due to the precipitation of solid products and depletion of ions contents in the liquid phase of the system. 13C NMR measurements of diffusivity of CO2 enriched with 13C isotope showed that a part of the absorbed CO2 remained in the liquid phase being physically and chemically bound to ions. The ionic liquid is re-cycled by evaporating water and releasing CO2 molecules using vacuum and temperature.

  • 12.
    Pathak, Uma
    et al.
    Synthetic Chemistry Division, Defence R and D Establishment.
    Bhattacharyya, Shubhankar
    Dhruwansh, Vishwanath
    ynthetic Chemistry Division, Defence R and D Establishment.
    Pandey, Lokesh Kumar
    Synthetic Chemistry Division, Defence R and D Establishment.
    Tank, Rekha
    Synthetic Chemistry Division, Defence R and D Establishment.
    Suryanarayana, Malladi Venkata Satya
    Synthetic Chemistry Division, Defence R and D Establishment.
    An easy access to thiazolines and thiazines via tandem S-alkylation- cyclodeamination of thioamides/haloamines2011Inngår i: Green Chemistry, ISSN 1463-9262, E-ISSN 1463-9270, Vol. 13, nr 7, s. 1648-1651Artikkel i tidsskrift (Fagfellevurdert)
    Abstract [en]

    This is the first report of a facile synthesis of thiazolines and thiazines from a self-catalyzed, water assisted tandem S-alkylation-cyclodeamination reaction of thioamides/haloamines. The reaction is clean and efficient with simple product work-up, and is applicable to a variety of substrates

  • 13.
    Pathak, Uma
    et al.
    Synthetic Chemistry Division, Defence R and D Establishment.
    Bhattacharyya, Shubhankar
    Synthetic Chemistry Division, Defence R and D Establishment.
    Mathur, Sweta
    Synthetic Chemistry Division, Defence R and D Establishment.
    Selective thioacylation of amines in water: A convenient preparation of secondary thioamides and thiazolines2015Inngår i: RSC Advances, ISSN 2046-2069, E-ISSN 2046-2069, Vol. 5, nr 6, s. 4484-4488Artikkel i tidsskrift (Fagfellevurdert)
    Abstract [en]

    Primary thioamides have been utilised directly in water, without any derivatisation, to selectively thioacylate primary amines. By employing 2-hydroxyethylamines, the reaction can be extended to the preparation of 2-thiazolines via formation of β-hydroxythioamides

  • 14.
    Pathak, Uma
    et al.
    Synthetic Chemistry Division, Defence R and D Establishment.
    Bhattacharyya, Shubhankar
    Synthetic Chemistry Division, Defence R and D Establishment.
    Pandey, Lokesh Kumar
    Synthetic Chemistry Division, Defence R and D Establishment.
    Mathur, Sweta
    Synthetic Chemistry Division, Defence R and D Establishment.
    Jain, Rajeev
    School of Studies in Chemistry, Jiwaji University.
    An easy access to tertiary amides from aldehydes and N,N- dialkylchlorothiophosphoramidates2014Inngår i: RSC Advances, ISSN 2046-2069, E-ISSN 2046-2069, Vol. 4, nr 8, s. 3900-3903Artikkel i tidsskrift (Fagfellevurdert)
    Abstract [en]

    A mechanistically unprecedented approach for the formation of tertiary amides from N,N-dialkylchlorothiophosphoramidates and aldehydes has been developed. The reaction occurred via the activation of aldehydes with N,N-dialkylchlorothiophosphoramidates followed by amidation with dialkylamine pendent of the same phosphoramidate

  • 15.
    Shah, Faiz Ullah
    et al.
    Luleå tekniska universitet, Institutionen för samhällsbyggnad och naturresurser, Kemiteknik.
    Bhattacharyya, Shubhankar
    Luleå tekniska universitet, Institutionen för samhällsbyggnad och naturresurser, Kemiteknik.
    Filippov, Andrei
    Luleå tekniska universitet, Institutionen för samhällsbyggnad och naturresurser, Kemiteknik.
    Akhtar, Farid
    Luleå tekniska universitet, Institutionen för teknikvetenskap och matematik, Materialvetenskap.
    Ionic Liquids As Liquid And Solid Sorbents For Post-Combustion CO2 Capture2016Konferansepaper (Fagfellevurdert)
  • 16.
    Tank, Rekha
    et al.
    Synthetic Chemistry Division, Defence R and D Establishment.
    Pathak, Uma
    Synthetic Chemistry Division, Defence R and D Establishment.
    Vimal, Manorama
    Synthetic Chemistry Division, Defence R and D Establishment.
    Bhattacharyya, Shubhankar
    Synthetic Chemistry Division, Defence R and D Establishment.
    Pandey, Lokesh Kumar
    Synthetic Chemistry Division, Defence R and D Establishment.
    Hydrogen peroxide mediated efficient amidation and esterification of aldehydes: Scope and selectivity2011Inngår i: Green Chemistry, ISSN 1463-9262, E-ISSN 1463-9270, Vol. 13, nr 12, s. 3350-3354Artikkel i tidsskrift (Fagfellevurdert)
    Abstract [en]

    An efficient method for the amidation and esterification of aldehydes utilizing hydrogen peroxide as an oxidant has been developed. Cyclic amines and primary alcohols selectively reacted with aromatic aldehydes under mild conditions to yield the corresponding amides and esters

1 - 16 of 16
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