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  • 1.
    Bortoluzzi, Marco
    et al.
    Dipartimento di Scienze Molecolari e Nanosistemi, Università Ca’ Foscari Venezia.
    Castro, Jesús
    Departamento de Química Inorgánica, Universidade de Vigo, Facultade de Química, Edificio de Ciencias Experimentais.
    Enrichi, Francesco
    Luleå University of Technology, Department of Engineering Sciences and Mathematics, Material Science. Consorzio Interuniversitario Reattività Chimica e Catalisi (CIRCC) .
    Vomiero, Alberto
    Luleå University of Technology, Department of Engineering Sciences and Mathematics, Material Science.
    Busato, Marta
    Dipartimento di Scienze Molecolari e Nanosistemi, Università Ca’ Foscari Venezia.
    Huang, Weizhe
    Dipartimento di Scienze Molecolari e Nanosistemi, Università Ca’ Foscari Venezia.
    Green-emitting manganese (II) complexes with phosphoramide and phenylphosphonic diamide ligands2018In: Inorganic Chemistry Communications, ISSN 1387-7003, E-ISSN 1879-0259, Vol. 92, p. 145-150Article in journal (Refereed)
    Abstract [en]

    Tetrahedral manganese(II) complexes having formulae [MnX2{O = PR(NMe2)2}2] (X = Br, I; R = NMe2, Ph) were isolated and characterized, and in the case of [MnBr2{O = PPh(NMe2)2}2] the structure was ascertained by means of single crystal X-ray diffraction. All the complexes showed intense green emission assigned to the Mn(II) 4T1(4G) → 6A1(6S) transition upon excitation with UV light, with photoluminescence lifetimes in the range 100–1000 μs. Bromo-complexes maintain their luminescence features once dispersed in polycaprolactone matrix.

  • 2.
    Bortoluzzi, Marco
    et al.
    Dipartimento di Scienze Molecolari e Nanosistemi, Università Ca' Foscari Venezia, Mestre, VE, Italy;Consorzio Interuniversitario Reattività Chimica e Catalisi (CIRCC), Bari, Italy.
    Castro, Jesús
    Departamento de Química Inorgánica, Universidade de Vigo, Facultade de Química, Edificio de Ciencias Experimentais, Galicia, Spain.
    Girotto, Matteo
    Dipartimento di Scienze Molecolari e Nanosistemi, Università Ca' Foscari Venezia, Mestre, VE, Italy.
    Enrichi, Francesco
    Luleå University of Technology, Department of Engineering Sciences and Mathematics, Material Science. Dipartimento di Scienze Molecolari e Nanosistemi, Università Ca' Foscari Venezia, Mestre, VE, Italy.
    Vomiero, Alberto
    Luleå University of Technology, Department of Engineering Sciences and Mathematics, Material Science. Dipartimento di Scienze Molecolari e Nanosistemi, Università Ca' Foscari Venezia, Mestre, VE, Italy.
    Luminescent copper(I) coordination polymer with 1-methyl-1H-benzotriazole, iodide and acetonitrile as ligands2019In: Inorganic Chemistry Communications, ISSN 1387-7003, E-ISSN 1879-0259, Vol. 102, p. 141-146Article in journal (Refereed)
    Abstract [en]

    The Cu(I) coordination polymer [Cu33-I)3(μ-btzMe)(NCCH3)]n (btzMe = 1-methyl-1H-benzotriazole) was prepared and characterized by X-Ray diffraction. The compound showed strong green emission upon excitation with wavelengths below 475 nm, with lifetime of 47 μs. The emission was attributed to 3(X,M)LCT transition on the basis of experimental data and DFT calculations.

  • 3.
    Ferraro, Valentina
    et al.
    Dipartimento di Scienze Molecolari e Nanosistemi, Università Ca’ Foscari Venezia, Via Torino 155, I-30170 Mestre, VE, Italy. Consorzio Interuniversitario Reattività Chimica e Catalisi (CIRCC), via Celso Ulpiani 27, 70126 Bari, Italy.
    Bortoluzzi, Marco
    Dipartimento di Scienze Molecolari e Nanosistemi, Università Ca’ Foscari Venezia, Via Torino 155, I-30170 Mestre, VE, Italy. Consorzio Interuniversitario Reattività Chimica e Catalisi (CIRCC), via Celso Ulpiani 27, 70126 Bari, Italy.
    Castro, Jesús
    Departamento de Química Inorgánica, Universidade de Vigo, Facultade de Química, Edificio de Ciencias Experimentais, 36310 Vigo, Galicia, Spain.
    Vomiero, Alberto
    Luleå University of Technology, Department of Engineering Sciences and Mathematics, Material Science. Dipartimento di Scienze Molecolari e Nanosistemi, Università Ca’ Foscari Venezia, Via Torino 155, I-30170 Mestre, VE, Italy.
    You, Shujie
    Luleå University of Technology, Department of Engineering Sciences and Mathematics, Material Science.
    Luminescent Cu(I) complex with bis(indazol-1-yl)phenylmethane as chelating ligand2020In: Inorganic Chemistry Communications, ISSN 1387-7003, E-ISSN 1879-0259, Vol. 116, article id 107894Article in journal (Refereed)
    Abstract [en]

    The cationic Cu(I) complex [Cu(N^N)2]+, where N^N is bis(indazol-1-yl)phenylmethane, was synthesized as chloride or tetrafluoroborate salt by reacting CuCl or [Cu(NCCH3)4][BF4] with bis(indazol-1-yl)phenylmethane under mild conditions. The structure of [Cu(N^N)2]Cl was ascertained by single-crystal X-ray diffraction. The complex exhibited bright yellow emission upon excitation with near UV and violet light, attributed to triplet LLCT/MLCT transitions on the basis of experimental data and computational outcomes.

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