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Mantilla, I., Muthanna, T. M., Marsalek, J. & Viklander, M. (2025). Assessing spatial and temporal variability of grass swale infiltration in shallow groundwater conditions. Journal of Environmental Management, 380, Article ID 124977.
Öppna denna publikation i ny flik eller fönster >>Assessing spatial and temporal variability of grass swale infiltration in shallow groundwater conditions
2025 (Engelska)Ingår i: Journal of Environmental Management, ISSN 0301-4797, E-ISSN 1095-8630, Vol. 380, artikel-id 124977Artikel i tidskrift (Refereegranskat) Published
Abstract [en]

Implementing stormwater green infrastructure in shallow groundwater areas presents major challenges that could restrict widespread adoption of swales in such areas. These limitations are driven by concerns about reduced swale infiltration capacity, which negatively impacts the effectiveness of green measures in managing runoff volumes. This study evaluates the spatial and temporal distribution of infiltration rates in a 30-m grass swale section using a Modified Philip-Dune infiltrometer and full-scale infiltration testing. Groundwater levels were continuously monitored by three piezometers adjacent to the grass swale to assess the impact of unsaturated zone depth on the swale infiltration capacity. Results showed that infiltration rates varied widely from 13 mm/h at the swale bottom to 98 mm/h on the right slope and highlighted the potential overestimation of swale capacity when relying only on point measurements of infiltration. Results from a full-scale infiltration test revealed an overall swale infiltration rate of only 4 mm/h, which is below the values recommended in the literature for swale applicability. A 52 % decrease in infiltration rates was observed between 2022 and 2024. Experimental results indicated that the grass swale had the capacity to recover its storage and managed a subsequent rainfall event within 15 h of the full draw-down. While the findings did not show a strong correlation between swale infiltration rates and the depth of the unsaturated zone, the results underscore the need to balance the soil permeability and groundwater protection for effective stormwater management.

Ort, förlag, år, upplaga, sidor
Elsevier, 2025
Nyckelord
Grass swales, Stormwater management, Infiltration capacity, Spatial and temporal variability, Groundwater mounding, Unsaturated zone depth
Nationell ämneskategori
Vattenteknik
Forskningsämne
VA-teknik; Centrumbildning - Centrum för dagvattenhantering (DRIZZLE)
Identifikatorer
urn:nbn:se:ltu:diva-112206 (URN)10.1016/j.jenvman.2025.124977 (DOI)2-s2.0-105000538958 (Scopus ID)
Forskningsfinansiär
Vinnova, 2022-03092
Anmärkning

Validerad;2025;Nivå 2;2025-04-02 (u2);

Full text: CC BY license;

Tillgänglig från: 2025-04-02 Skapad: 2025-04-02 Senast uppdaterad: 2025-04-02Bibliografiskt granskad
Flanagan, K., Blecken, G.-T., Österlund, H. & Viklander, M. (2025). Comparing acute toxicity testing and extensive targeted chemical screening for risk assessment of urban stormwater pond sediments. Journal of Hazardous Materials, 494, Article ID 138451.
Öppna denna publikation i ny flik eller fönster >>Comparing acute toxicity testing and extensive targeted chemical screening for risk assessment of urban stormwater pond sediments
2025 (Engelska)Ingår i: Journal of Hazardous Materials, ISSN 0304-3894, E-ISSN 1873-3336, Vol. 494, artikel-id 138451Artikel i tidskrift (Refereegranskat) Published
Abstract [en]

32 urban stormwater pond sediment samples were analyzed for 259 organic substances, 13 trace elements, physico-chemical parameters and acute toxicity of eluates to the bioluminescent bacteria Aliivibrio fischeri according to the Microtox® method. Five of these samples showed some toxicity to Aliivibrio fischeri. Statistical analysis was conducted to identify substances with significantly different concentrations between toxic and non-toxic samples, as well as differences in contaminant patterns between these sets. Results showed no significant differences in trace element, organic contaminant concentrations or overall contaminant patterns between toxic and non-toxic samples. However, dissolved oxygen was significantly lower in toxic than in non-toxic samples, likely due to an influence on the lability of contaminants. This work highlights the difficulty of conducting a pertinent and robust environmental hazard assessment for complex matrices composed of a large number of substances present at low concentrations and discusses the advantages and limitations of both chemical and biological approaches to environmental hazard assessment for urban stormwater sediments. Because the evaluation of urban stormwater sediments is so complex, to comprehensively and accurately analyse its risks, it is very important to consider both biological and chemical factors. Considering both will provide an accurate identification of possible risks and enhanced control of environmental risks in urban areas.

Ort, förlag, år, upplaga, sidor
Elsevier B.V., 2025
Nyckelord
Organic contaminants, Metals, Environmental effects, Urban runoff, Bioassay
Nationell ämneskategori
Miljövetenskap Vattenteknik
Forskningsämne
VA-teknik
Identifikatorer
urn:nbn:se:ltu:diva-112732 (URN)10.1016/j.jhazmat.2025.138451 (DOI)2-s2.0-105004410247 (Scopus ID)
Forskningsfinansiär
Vinnova, Grant Nos. 2016-05176 and 2022-03092
Anmärkning

Validerad;2025;Nivå 2;2025-05-20 (u2);

Full text: CC BY license;

Tillgänglig från: 2025-05-20 Skapad: 2025-05-20 Senast uppdaterad: 2025-05-20Bibliografiskt granskad
Beryani, A., Flanagan, K., You, S., Forsberg, F., Viklander, M. & Blecken, G.-T. (2025). Critical field evaluations of biochar-amended stormwater biofilters for PFAS and other organic micropollutant removals. Water Research, 281, Article ID 123547.
Öppna denna publikation i ny flik eller fönster >>Critical field evaluations of biochar-amended stormwater biofilters for PFAS and other organic micropollutant removals
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2025 (Engelska)Ingår i: Water Research, ISSN 0043-1354, E-ISSN 1879-2448, Vol. 281, artikel-id 123547Artikel i tidskrift (Refereegranskat) Published
Abstract [en]

Biochar is often promoted as an ideal amendment for stormwater biofilters; however, its effectiveness has rarely been tested under field conditions. This study evaluates the impact of biochar addition on the removal of organic micropollutants (OMPs) in field-scale biofilters operating under real-world conditions for the first time. The research comprised four vegetated biofilter facilities (3 − 5 years old), two without and two with 2.1 wt. % (10 vol. %) biochar amendment. Stormwater and filter material samples from various locations after four years of operation were analyzed for a wide range of common and emerging OMPs found in urban runoff. Unlike hydrophobic OMPs (hydrocarbons, polychlorinated biphenyls, and di(2-ethylhexyl) phthalate), the investigated biofilters demonstrated low, or inconsistent, removal of hydrophilic and slow-adsorbing OMPs like bisphenol A, monobutyltin, and per-fluoroalkyl substances (PFASs). Although the physiochemical properties of biochar were well-adapted to pollutant removal, biochar amendment did not significantly improve OMP removal when compared with the status quo. This can be attributed to several field conditions and suboptimal design interfering with the biochar's sorption capacity, namely, the large particle size (D50 ∼4 mm) and low quantity of biochar, high levels of competing agents (i.e., dissolved oxygen carbon (DOC) and cations), co-contaminants in stormwater, limited contact time, biochar pore blockage (e.g., by DOC molecules and sediments/minerals), diminished biochar surface porosity, and sometimes increased removal uncertainty due to low influent concentrations. Our findings demonstrated the complexities associated with applying biochar for stormwater treatment. Further research on biochar-specific biofilter designs is needed to optimize the sorption potential of this material under field conditions.

Ort, förlag, år, upplaga, sidor
Elsevier, 2025
Nyckelord
Urban runoff, Bioretention, Biochar, Accumulation, Retention, PFAS
Nationell ämneskategori
Vattenteknik
Forskningsämne
VA-teknik; Experimentell fysik; Experimentell mekanik; Centrumbildning - Centrum för dagvattenhantering (DRIZZLE)
Identifikatorer
urn:nbn:se:ltu:diva-111366 (URN)10.1016/j.watres.2025.123547 (DOI)2-s2.0-105001507050 (Scopus ID)
Forskningsfinansiär
Vinnova, 2016-05176Vinnova, 2022-03092Naturvårdsverket, NV-03809-23
Anmärkning

Validerad;2025;Nivå 2;2025-04-04 (u4);

Fulltext license: CC BY;

This article has previously appeared as a manuscript in a thesis.

Tillgänglig från: 2025-01-22 Skapad: 2025-01-22 Senast uppdaterad: 2025-04-14Bibliografiskt granskad
Lönnqvist, J., Broekhuizen, I., Blecken, G.-T. & Viklander, M. (2025). Green roof runoff reduction of 84 rain events: Comparing Sedum, life strategy-based vegetation, unvegetated and conventional roofs. Journal of Hydrology, 646, Article ID 132325.
Öppna denna publikation i ny flik eller fönster >>Green roof runoff reduction of 84 rain events: Comparing Sedum, life strategy-based vegetation, unvegetated and conventional roofs
2025 (Engelska)Ingår i: Journal of Hydrology, ISSN 0022-1694, E-ISSN 1879-2707, Vol. 646, artikel-id 132325Artikel i tidskrift (Refereegranskat) Published
Abstract [en]

Green roofs have emerged as effective stormwater management systems, but understanding the contribution of their various components to hydrological performance is crucial for optimizing their design and implementation. More empirically measured data on the hydrological function of green roof vegetation is needed, especially under realistic low-maintenance, non-irrigated scenarios. Further, targeted, evidence-based plant selection based on ecological theories may improve green roof hydrological performance. Previous research has suggested that, in contrast to monocultures, mixtures of species with complementary traits could optimize provisioning of various ecosystem services. Thus, species mixtures based on their adaptive life strategy using the CSR theory (Competitor, Stress tolerator, and Ruderal) were hypothesized to have better hydrological performance than a Sedum monoculture or bare substrate under natural conditions over multiple seasons. To test this hypothesis, the runoff from thirty 2 m2 green roof modules was measured. The retention and detention performance of different green roof treatments were evaluated for 84 precipitation events of varying rain depth and intensity during snow-free periods. Differences in retention as well as detention between the vegetation treatments varied, but generally increased with increasing rain event volume and the Stress-tolerant treatment generally performed better than bare substrate. On a mean event basis, the mixture of stress-tolerator species demonstrated a 74 % retention rate, while the Bare substrate retained 72 % of the rainfalls. Overall, the green roofs, including bare substrate and vegetated treatments, effectively retained >50 % of the cumulative precipitation depth. In line with previous studies, the Sedum monoculture generally showed worse hydrological performance than other non-succulent vegetation mixtures, despite its relatively high cover and survival. The vegetated treatment with the highest species richness and diversity in life strategies (Mix) did not provide the best vegetation cover, or hydrological performance. Instead, the Stress-tolerant treatment, characterized by the high survival rate of a single graminoid species, consistently demonstrated superior event-based stormwater retention and peak attenuation capabilities.

Ort, förlag, år, upplaga, sidor
Elsevier, 2025
Nyckelord
Green roof, Stormwater retention, Peak attenuation, Peak flow reduction, Plant mix, CSR strategy
Nationell ämneskategori
Vattenteknik
Forskningsämne
VA-teknik; Centrumbildning - Centrum för dagvattenhantering (DRIZZLE)
Identifikatorer
urn:nbn:se:ltu:diva-96974 (URN)10.1016/j.jhydrol.2024.132325 (DOI)001362726200001 ()2-s2.0-85209348147 (Scopus ID)
Forskningsfinansiär
Forskningsrådet Formas, 2014-00854Vinnova, 2016-05176, 2022-03092
Anmärkning

Validerad;2024;Nivå 2;2024-12-05 (hanlid);

Full text license: CC BY;

This article has previously appeared as a manuscript in a thesis.

Tillgänglig från: 2023-05-02 Skapad: 2023-05-02 Senast uppdaterad: 2024-12-17Bibliografiskt granskad
Kaykhaii, S., Herrmann, I., Gelfgren, M., Hedström, A., Heidfors, I. & Viklander, M. (2025). Mass flow distribution of stormwater pollutants in ultrafiltration treatment system and permeate reuse. Desalination and Water Treatment, 322, Article ID 101101.
Öppna denna publikation i ny flik eller fönster >>Mass flow distribution of stormwater pollutants in ultrafiltration treatment system and permeate reuse
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2025 (Engelska)Ingår i: Desalination and Water Treatment, ISSN 1944-3994, E-ISSN 1944-3986, Vol. 322, artikel-id 101101Artikel i tidskrift (Refereegranskat) Published
Abstract [en]

Stormwater can have environmental impacts because it causes various pollutants to be released into the environment during precipitation events. This study quantifies the flow of different metals through an ultrafiltration membrane unit during stormwater treatment and investigates the possibility of reusing treated stormwater both as non-potable and potable purposes and of metal recovery from the backwash water obtained from membrane cleaning. The stormwater used for the ultrafiltration experiments was sampled in three catchments during different rain events. The results indicate that the permeate quality complied with most of the parameters for potable water as stipulated by the Swedish Food Agency, except in respect of manganese, nitrate and ammonia concentrations from permeate from stormwater samples originating from road runoff. The backwash water from the membrane cleaning contained metals in high concentrations, e.g. average copper concentrations were 5.2 times higher in the backwash than in the feed. Recovering metals like Cu, Ni, and Zn from backwash water could be a sustainable process, as stormwater transports 0.03 %, 0.01 %, and 0.04 % of their annual production in high-extraction countries, provided operational costs and logistics are feasible.

Ort, förlag, år, upplaga, sidor
Elsevier B.V., 2025
Nyckelord
Backwash water, Potable water, Ultrafiltration membrane, Metal recovery
Nationell ämneskategori
Vattenteknik
Forskningsämne
VA-teknik
Identifikatorer
urn:nbn:se:ltu:diva-112090 (URN)10.1016/j.dwt.2025.101101 (DOI)001446311200001 ()2-s2.0-86000491719 (Scopus ID)
Forskningsfinansiär
Forskningsrådet Formas, 2016–20075
Anmärkning

Validerad;2025;Nivå 2;2025-03-24 (u5);

Full text license: CC BY 4.0;

Funder: Drizzle Centre of Stormwater Management (2022–03092);

Tillgänglig från: 2025-03-24 Skapad: 2025-03-24 Senast uppdaterad: 2025-04-11Bibliografiskt granskad
Lindfors, S., Österlund, H., Lorenz, C., Vianello, A., Nordqvist, K., Gopinath, K., . . . Viklander, M. (2025). Microplastics and tyre wear particles in urban runoff from different urban surfaces. Science of the Total Environment, 980, Article ID 179527.
Öppna denna publikation i ny flik eller fönster >>Microplastics and tyre wear particles in urban runoff from different urban surfaces
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2025 (Engelska)Ingår i: Science of the Total Environment, ISSN 0048-9697, E-ISSN 1879-1026, Vol. 980, artikel-id 179527Artikel i tidskrift (Refereegranskat) Published
Abstract [en]

Urban runoff is an important conveyor of microplastics (MPs) and tyre wear particles (TWP) to receiving waters. However, knowledge of contributions by surfaces within land use type/activities is currently limited. To address this knowledge gap, runoff samples were collected simultaneously during three rainfall events in October and November 2020 at three locations in Luleå, Sweden, with different urban surfaces (parking lot, road and roof). The occurrence of MPs (by number and estimated mass) and TWP (mass) were determined using μ-FTIR and Pyr-GC/MS, respectively. MPs and TWP were found at all sites in all events, with large variations between events and sites. The highest concentrations of MPs (number) and TWP were found in road runoff followed by parking lot runoff and roof runoff. The mass concentrations of MPs did not follow the same pattern and were generally highest at the parking lot, highlighting the importance of reporting data as both mass and particle numbers to derive a complete overview of MPs and TWP behaviour. Polypropylene, polyethylene, and polyester accounted, on average, for 99 % of MP polymers (by mass and number) at all sites with common sources, including traffic (vehicle wear and tear) and littering. MPs in the <75 μm fraction contributed >50 % of the total number of MPs in parking lot runoff, >58 % in roof runoff and > 90 % in road runoff.

Ort, förlag, år, upplaga, sidor
Elsevier B.V., 2025
Nyckelord
Stormwater, MP, TWP, Land use, μ-FTIR, Pyr-GC/MS
Nationell ämneskategori
Vattenteknik
Forskningsämne
VA-teknik
Identifikatorer
urn:nbn:se:ltu:diva-112631 (URN)10.1016/j.scitotenv.2025.179527 (DOI)2-s2.0-105003647295 (Scopus ID)
Forskningsfinansiär
Naturvårdsverket, 208-0182-18Vinnova, 2016-05176, 2022-03092
Anmärkning

Validerad;2025;Nivå 2;2025-05-12 (u5);

Full text license: CC BY 4.0;

Funder: FanpLESStic Sea EU Baltic Interreg (R092);

Tillgänglig från: 2025-05-12 Skapad: 2025-05-12 Senast uppdaterad: 2025-05-12Bibliografiskt granskad
Furén, R., Winston, R. J., Tirpak, R. A., Dorsey, J. D., Viklander, M. & Blecken, G.-T. (2025). Occurrence and Concentration of 6 Metals and 28 Organic Micropollutants in the Forebays of Bioretention Facilities. Journal of Sustainable Water in the Built Environment, 11(1), Article ID 04024013.
Öppna denna publikation i ny flik eller fönster >>Occurrence and Concentration of 6 Metals and 28 Organic Micropollutants in the Forebays of Bioretention Facilities
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2025 (Engelska)Ingår i: Journal of Sustainable Water in the Built Environment, E-ISSN 2379-6111, Vol. 11, nr 1, artikel-id 04024013Artikel i tidskrift (Refereegranskat) Published
Abstract [en]

Pollutant loads in urban runoff from anthropogenic sources contribute to degradation of downstream waters. Cities are turning toward green infrastructure to manage urban stormwater. Bioretention is popular as green infrastructure and is commonly installed to remove runoff pollutants. A significant proportion of pollutants in urban runoff are particulates or particulate-bound and are effectively removed in bioretention cells. Pollutants accumulate in concentrated areas of the bioretention (e.g., forebays, inlets, surficial filter layers), which require maintenance to restore effective treatment and to increase the operational lifespan. Particles trapped in forebays risk diminished effectiveness of the pretreatment, which may eventually lead to filter clogging and leaching of toxic pollutants. Studies have examined pollutant accumulation and distribution in bioretention filter media, but less is known about processes in bioretention forebays. In this study, 28 bioretention forebays were examined in urban areas of Ohio and Michigan (United States) as well as Stockholm and Malmö (Sweden) to investigate the occurrence and accumulation of metals (i.e., Cd, Cr, Cu, Ni, Pb, and Zn) and 38 analytes of organic micropollutants [OMPs, i.e., alkylphenols, polycyclic aromatic hydrocarbons (PAHs), polychlorinated biphenyls (PCBs), and phthalates]. Investigated metals were present in all 28 samples, except Cd detected in 27 samples. Of 38 OMP analytes, 31 were detected in at least one sample. PAHs and PCBs were the most frequently detected pollutants found at all examined sites. In general, high concentrations of pollutants were detected in all forebay sediments. Cu, Ni, Zn, PAHs with high molecular weight, and PCBs were detected at concentrations above US and Swedish soil quality guidelines. It was concluded that forebays regularly need to be excavated to maintain their function, and excavated sediments must be handled safely during maintenance work and disposal.

Ort, förlag, år, upplaga, sidor
American Society of Civil Engineers (ASCE), 2025
Nationell ämneskategori
Vattenteknik
Forskningsämne
VA-teknik; Centrumbildning - Centrum för dagvattenhantering (DRIZZLE)
Identifikatorer
urn:nbn:se:ltu:diva-110963 (URN)10.1061/jswbay.sweng-583 (DOI)001379560600006 ()2-s2.0-85210600111 (Scopus ID)
Projekt
Dag & Nät
Forskningsfinansiär
Vinnova, 2016–05176Svenska Byggbranschens Utvecklingsfond (SBUF), 14197
Anmärkning

Validerad;2025;Nivå 1;2025-03-17 (u4);

Full text license: CC BY 4.0

Tillgänglig från: 2024-12-04 Skapad: 2024-12-04 Senast uppdaterad: 2025-04-25Bibliografiskt granskad
Kali, S. E., Österlund, H., Viklander, M. & Blecken, G.-T. (2025). Occurrence, concentration and distribution of 50 organic contaminants in water and bottom sediment from urban streams affected by stormwater discharges. Water Research, 283, Article ID 123847.
Öppna denna publikation i ny flik eller fönster >>Occurrence, concentration and distribution of 50 organic contaminants in water and bottom sediment from urban streams affected by stormwater discharges
2025 (Engelska)Ingår i: Water Research, ISSN 0043-1354, E-ISSN 1879-2448, Vol. 283, artikel-id 123847Artikel i tidskrift (Refereegranskat) Published
Abstract [en]

Stormwater runoff transports organic contaminants from urban areas to receiving water bodies, yet its contribution to these pollutants in the aquatic environment is still poorly understood. Additionally, contaminants behave differently in receiving waters, with some binding to particles and accumulating in sediments while others stay dissolved in the water. This study was carried out three Swedish urban streams receiving stormwater discharges through separate sewer systems, under dry and wet weather conditions. Stream water and bottom sediment samples were collected along an urbanization gradient, from rural upstream to urban downstream sections, and analyzed for 50 stormwater-related organic contaminants to assess the impact of stormwater on contaminant levels. Polycyclic aromatic hydrocarbons (PAHs) and phthalates were more prevalent in sediment samples, with concentrations increasing along the urbanization gradient, indicating contributions from urban areas and stormwater runoff. In contrast, organotin compounds and phenols showed no clear pattern indicating transport through stormwater runoff in the water phase. Per and polyfluoroalkyl substances (PFAS) behaved differently from other contaminant groups by exhibiting a clear contribution from stormwater runoff in both phases. Though carried out in streams passing through relatively small urban settings, the findings clearly demonstrate that stormwater discharges can impact receiving waters. Of the 50 analyzed contaminants, three exceeded toxicity-based limits in dry weather (DW), seven in wet weather (WW), and twenty in bottom sediments. In the water phase, under DW and WW conditions, the three contaminants with the highest exceedance of toxicity-based limits were Perfluorooctanesulfonic acid (PFOS), Tributyltin (TBT), and 4-nonylphenol (4-NP). In the sediment phase, 4‑tert-octylphenol (4-t-OP), Tributyltin (TBT), and di-2-ethylhexyl phthalate (DEHP) were the three compounds with the highest exceedance of toxicity-based limits. Compared to relatively hydrophilic contaminants (e.g., PFAS), hydrophobic organic contaminants, particularly those accumulating in sediments (e.g. phenols, phthalates), posed a greater risk to the aquatic environment with exceedance levels reaching up to 105 times the thresholds. These findings raise concerns about the long-term impact on aquatic environments and highlight the need for mitigation strategies, including regulatory or operational restrictions on the contaminant sources and implementation of stormwater treatment facilities.

Ort, förlag, år, upplaga, sidor
Elsevier Ltd, 2025
Nyckelord
Urban runoff, Micropollutants, Urban river, Wet weather, Emerging contaminants
Nationell ämneskategori
Vattenteknik Miljövetenskap
Forskningsämne
VA-teknik
Identifikatorer
urn:nbn:se:ltu:diva-112782 (URN)10.1016/j.watres.2025.123847 (DOI)2-s2.0-105005513291 (Scopus ID)
Forskningsfinansiär
Naturvårdsverket, Grant numbers 06920-21 and 03808-23Forskningsrådet Formas, Grant number 2023-02529Vinnova, Grant number 2022-03092
Anmärkning

Validerad;2025;Nivå 2;2025-05-26 (u2);

Full text: CC BY license;

Tillgänglig från: 2025-05-26 Skapad: 2025-05-26 Senast uppdaterad: 2025-05-26Bibliografiskt granskad
Kali, S. E., Österlund, H., Viklander, M. & Blecken, G.-T. (2025). Stormwater discharges affect PFAS occurrence, concentrations, and spatial distribution in water and bottom sediment of urban streams. Water Research, 271, Article ID 122973.
Öppna denna publikation i ny flik eller fönster >>Stormwater discharges affect PFAS occurrence, concentrations, and spatial distribution in water and bottom sediment of urban streams
2025 (Engelska)Ingår i: Water Research, ISSN 0043-1354, E-ISSN 1879-2448, Vol. 271, artikel-id 122973Artikel i tidskrift (Refereegranskat) Published
Abstract [en]

Per- and polyfluoroalkyl substances (PFAS) are extensively used in urban environments and are, thus, found in urban stormwater. However, the relevance of stormwater as a pathway for PFAS to urban streams is largely unknown. This study evaluated the impact of urban stormwater runoff on PFAS concentrations and spatial distribution in three urban streams affected by stormwater discharges from separate sewer systems. River water was sampled during dry (DW) and wet weather (WW) upstream, immediately downstream, and further downstream of three urbanized areas with separate sewer systems and with and without point sources (i.e. waste water treatment plant, airports). Water samples were analyzed for 34 targeted PFAS compounds and sediment samples for 35 targeted PFAS and 30 PFAS compounds using a total oxidizable precursor assay. The sum of the quantified PFAS concentrations ranged from the reporting limit (RL) to 84.7 ng/L during DW and increased as the streams were affected by WW discharges (0.87 to 102.3 ng/L). The highest PFAS concentrations were found downstream of urban areas and/or point sources (i.e. airports) during WW, indicating a clear contribution from stormwater discharges. A consistent PFAS contribution from the WWTP was observed under both DW and WW conditions. During WW events, concentrations of perfluorooctanesulfonic acid (PFOS) and total PFAS (PFOA equivalents) exceeded the annual average environmental quality standards, which are an established limit of 0.65 ng/L for PFOS and a proposed limit of 4.4 ng/L for total PFAS. Notably, except for the legacy PFAS, PFOS and perfluorooctanoic acid (PFOA), the most frequently quantified PFAS during DW were short-chain. For WW, long-chain perfluorocarboxylic acids (PFCAs) and a precursor, 6:2 Fluorotelomer sulfonic acid (6:2 FTS), were more frequently quantified, suggesting stormwater is a source of these longer-chain and particle-associated PFAS. The detection of unregulated fluorotelomer sulfonates (FTSs) such as 6:2 and 8:2 FTS during WW suggests a need for regulatory action, as these compounds can degrade into more stable PFAS. In sediment, higher concentrations, and a greater variety of PFAS were found at sites with known point sources i.e. airports. Long-chain PFCAs (C7–C13), perfluoroalkyl sulfonates (PFSAs) (C6), and precursors (i.e. N-Ethyl perfluorooctane sulfonamidoacetic acid), were more prevalent in sediments than in the water. Notably, PFOS concentrations in sediment exceeded the lowest Predicted No-Effect Concentration (PNEC) across sites, posing a potential long-term environmental risk, though current PNECs for other PFAS may underestimate such risks. The findings of the study highlight urban stormwater as a source of PFAS to urban streams indicating the need to minimize PFAS sources in the urban environment and to effectively treat stormwater to protect receiving water bodies.

Ort, förlag, år, upplaga, sidor
Elsevier Ltd, 2025
Nyckelord
Urban runoff, Receiving water, Urban river, Wet weather, Contaminant of emerging concern, Perfluoroalkyl and polyfluoroalkyl substances
Nationell ämneskategori
Miljövetenskap Vattenteknik
Forskningsämne
VA-teknik
Identifikatorer
urn:nbn:se:ltu:diva-111238 (URN)10.1016/j.watres.2024.122973 (DOI)39700609 (PubMedID)2-s2.0-85212533156 (Scopus ID)
Forskningsfinansiär
Naturvårdsverket, Grant numbers 06920-21 and 03808-23Vinnova, Grant numbers 2016–05176 and 2022-03092
Anmärkning

Validerad;2025;Nivå 2;2025-01-08 (joosat);

Full text: CC BY license;

Tillgänglig från: 2025-01-08 Skapad: 2025-01-08 Senast uppdaterad: 2025-02-11Bibliografiskt granskad
Lundy, L., Österlund, H., Fors, H., Müller, A., Gavric, S., Randrup, T. B. & Viklander, M. (2025). Urban stormwater research – An evidence synthesis: Development of a holistic understanding of current technical, environmental and social/institutional knowledge with regard to urban stormwater research. Naturvårdsverket
Öppna denna publikation i ny flik eller fönster >>Urban stormwater research – An evidence synthesis: Development of a holistic understanding of current technical, environmental and social/institutional knowledge with regard to urban stormwater research
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2025 (Engelska)Rapport (Övrigt vetenskapligt)
Ort, förlag, år, upplaga, sidor
Naturvårdsverket, 2025. s. 190
Serie
Rapport, ISSN 0282-7298 ; 7182
Nationell ämneskategori
Vattenteknik
Forskningsämne
VA-teknik
Identifikatorer
urn:nbn:se:ltu:diva-113404 (URN)978-91-620-7182-0 (ISBN)
Tillgänglig från: 2025-06-16 Skapad: 2025-06-16 Senast uppdaterad: 2025-06-16Bibliografiskt granskad
Organisationer
Identifikatorer
ORCID-id: ORCID iD iconorcid.org/0000-0003-1725-6478

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