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Processing, microstructure and high temperature dry sliding wear of a Cr-Fe-Hf-Mn-Ti-Ta-V high-entropy alloy based composite
Luleå University of Technology, Department of Engineering Sciences and Mathematics, Material Science.ORCID iD: 0000-0002-8173-8554
Luleå University of Technology, Department of Engineering Sciences and Mathematics, Material Science.ORCID iD: 0000-0001-9920-1643
Luleå University of Technology, Department of Engineering Sciences and Mathematics, Material Science.ORCID iD: 0000-0003-4888-6237
2021 (English)In: Materials Today Communications, ISSN 2352-4928, Vol. 28, article id 102657Article in journal (Refereed) Published
Abstract [en]

High-entropy materials are promising for high-temperature applications. In order to achieve high-temperature wear resistance, a novel high-entropy alloy based composite, (CrMnFeHf)7.14(TiTaV)23.81, was designed and consolidated by spark plasma sintering at 1320 ℃ following thermodynamic simulations using the CALPHAD method. The microstructure of the sintered composite revealed a Ti30V36Ta19Cr5Mn5Fe4Hf1 body-centered cubic (bcc) high-entropy alloy matrix with C14 Laves phase and carbide particles. The Laves phase and carbide particles of higher hardness were formed in situ during the sintering in a bcc matrix. The dry sliding wear behavior of the composite against Si3N4 ceramic counter ball (10 N, 30 min) from room temperature to 600 ℃ was investigated. The high-entropy alloy composite showed a superior resistance to wear against Si3N4 ceramic due to the presence of reinforcing C14 laves phase and carbide particles in the high-entropy alloy matrix. Furthermore, the wear rate reduced with increasing temperature. The dominating wear mechanisms of the high-entropy alloy composite were adhesive wear and abrasive wear at room temperature and 200 ℃, oxidation wear and abrasive wear at 400 ℃ and oxidation wear and delamination wear at 600 ℃. The formation of multiple oxides, presence of Laves and carbide phase contributed to the low volume loss of high-entropy alloy composite during wear tests at high temperatures.

Place, publisher, year, edition, pages
Elsevier, 2021. Vol. 28, article id 102657
Keywords [en]
high-entropy alloys, wear resistance, spark plasma sintering, Laves phase
National Category
Other Materials Engineering
Research subject
Engineering Materials
Identifiers
URN: urn:nbn:se:ltu:diva-86376DOI: 10.1016/j.mtcomm.2021.102657ISI: 000696951200001Scopus ID: 2-s2.0-85111261914OAI: oai:DiVA.org:ltu-86376DiVA, id: diva2:1580665
Funder
Swedish Foundation for Strategic Research, RIF14-0083The Kempe Foundations, JCK-1803
Note

Validerad;2021;Nivå 2;2021-07-26 (beamah)

Available from: 2021-07-15 Created: 2021-07-15 Last updated: 2025-10-21Bibliographically approved

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Xing, QiuweiFeltrin, Ana CarolinaAkhtar, Farid

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