In this work, an air-blast atomizing column was used to study the CO₂ capture performance with aqueous MEA (mono-ethanol-amine) and NaOH solutions. The effects of gas flow rate, the liquid to gas ratio (L/G), the CO₂ concentration on the CO₂ removal efficiency (η) and the volumetric overall mass transfer coefficient (KGav) were investigated. The air-blast atomizing column was also compared with the pressure spray tower on the studies of the CO₂ capture performance. For the aqueous MEA and NaOH solutions, the experimental results show that the ηdecreases with increasing gas flow rate and CO₂ concentration while it increases with increasing L/G. The effects on K_Ga_v are more complicated than those for η. When the CO₂ concentration is low (3 v/v%), K_Ga_v increases with increasing gas flow rate while decreases with increasing L/G. However, when the CO₂ concentration is high (9.5 v/v%), as the gas flow rate and L/G increases, K_Ga_v increases first and then decreases. The aqueous MEA solution achieves higher η and K_Ga_v than the aqueous NaOH solution. The air-blast atomizing column shows a good performance on CO₂ capture.