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Resource-efficient manufacturing process of composite materials: Fibrillation of recycled textiles and compounding with thermoplastic polymer
Luleå tekniska universitet, Institutionen för teknikvetenskap och matematik, Materialvetenskap. Wallenberg Wood Science Center (WWSC), Luleå, Sweden.ORCID-id: 0000-0002-9239-7652
Luleå tekniska universitet, Institutionen för teknikvetenskap och matematik, Materialvetenskap.ORCID-id: 0000-0002-6247-5963
Luleå tekniska universitet, Institutionen för teknikvetenskap och matematik, Materialvetenskap. Wallenberg Wood Science Center (WWSC), Luleå, Sweden; Department of Mechanical & Industrial Engineering (MIE), University of Toronto, ON, M5S 3G8 Toronto, Canada.ORCID-id: 0000-0003-4762-2854
2023 (Engelska)Ingår i: Composites. Part A, Applied science and manufacturing, ISSN 1359-835X, E-ISSN 1878-5840, Vol. 175, artikel-id 107773Artikel i tidskrift (Refereegranskat) Published
Abstract [en]

This study aimed to develop a manufacturing process for recycled textile long fiber thermoplastics (RT-LFT) and thereby contribute to circular economy. Three different post-consumer textiles (cotton denim and plain weave, and silk plain weave) were cut into strips and fed directly into a co-rotating twin-screw extruder in which the textile was fibrillated and compounded with polypropylene (PP). The fibrillation of the textile, fiber dispersion, and interaction with the matrix polymer were studied, and the thermal and mechanical properties of the composites were evaluated. For example, cotton denim composites containing 30 wt% fiber content resulted in 26% increase in yield strength and a 72% increase in modulus when compared with that of PP. The RT-LFT process is a straightforward method for transforming used textiles into composites like cups and bottoms, offering advantages such as reduced manufacturing costs, add value for waste material, and lower carbon emissions.

Ort, förlag, år, upplaga, sidor
Elsevier, 2023. Vol. 175, artikel-id 107773
Nationell ämneskategori
Textil-, gummi- och polymermaterial Biomaterial
Forskningsämne
Trä och bionanokompositer
Identifikatorer
URN: urn:nbn:se:ltu:diva-101416DOI: 10.1016/j.compositesa.2023.107773ISI: 001083680100001Scopus ID: 2-s2.0-85171795421OAI: oai:DiVA.org:ltu-101416DiVA, id: diva2:1799512
Forskningsfinansiär
Knut och Alice Wallenbergs Stiftelse, KAW 2018.0451Stora Enso
Anmärkning

Validerad;2023;Nivå 2;2023-09-22 (joosat);

CC BY 4.0 License

Tillgänglig från: 2023-09-22 Skapad: 2023-09-22 Senast uppdaterad: 2024-10-10Bibliografiskt granskad
Ingår i avhandling
1. Use of co-rotating extrusion process for the development of resource-efficient biocomposites
Öppna denna publikation i ny flik eller fönster >>Use of co-rotating extrusion process for the development of resource-efficient biocomposites
2024 (Engelska)Doktorsavhandling, sammanläggning (Övrigt vetenskapligt)
Abstract [en]

Natural fibers have gained popularity for reinforcing polymers due to their renewability, biodegradability, and usually have lower costs than synthetic fibers. The demand to reduce environmental impact has heightened awareness of the importance of adopting resource-efficient alternatives in line with recycling, reusing, and responsible consumption practices. This study integrates resource-efficient use of materials using a co-rotating twin screw extruder (TSE) in the development of biocomposites as an alternative for recycling, reducing landfill disposal, and contributing to the circular economy. 

The influence of recycling wood-polymer composites (WPCs) was explored by subjecting the materials to nine extrusion cycles. The properties of the WPCs were evaluated after every other cycle and compared to those of virgin and recycled polypropylene (PP) and WPCs. The results revealed that, although shear forces during extrusion decreased the aspect ratio of the wood fibers and reduced tensile strength after nine recycling cycles, the WPC still maintained higher mechanical properties than virgin PP, highlighting the advantages of using recycled WPC over PP. Recycling WPCs reduces the overconsumption of fossil-based plastics, decreases landfill disposal, and lessens the need for virgin fibers. 

The valorization of end-of-life textiles was studied as a potential candidate for use in biocomposites. The primary challenge was to develop a low-energy consumption method for feeding, fibrillating, and compounding textiles with thermoplastic polymers without requiring chemical or mechanical pretreatments. A continuous extrusion process, recycled-textile long fiber thermoplastic (RT-LFT), was developed to incorporate end-of-life textiles into a PP matrix using a co-rotating TSE. The results demonstrated that RT-LFT is a direct, effective, and energy-efficient method for compounding end-of-life textiles with polymer, enabling the textiles to be separated into individual fibers that are well dispersed within the matrix. 

In addition, the performance of fibers from end-of-life textiles was also evaluated using PP, and Bio-flex a biodegradable blend of polybutylene adipate terephthalate (PBAT)/ polylactic acid (PLA). The addition of the fibers did not show improvements in the mechanical properties of the PP matrix but showed great enhancement for the Bio-flex matrix. Adding fibers also improved the flow properties and melt strength of the polymers. Moreover, the disintegration under compositing conditions showed that the addition of fibers delayed the process when compared to neat polymer, but after 75 days cotton and silk biocomposites began to disintegrate. 

WPCs are often modified with fossil-based virgin elastomers to enhance their impact and toughness properties. However, the use of these elastomers increases competition for limited resources and raises the costs of WPCs. To address this, the influence of recycled materials as impact modifiers in WPCs was investigated by replacing virgin elastomer with recycled fibers from end-of-life textiles and recycled elastomer. The results indicated that both recycled materials are viable alternatives to virgin elastomer, offering comparable impact and toughness properties while reducing the WPCs' carbon footprint and costs. 

In conclusion, using recycled or end-of-life materials presents an excellent alternative to virgin materials in biocomposites. It contributes to the circular economy, reduces landfill waste, decreases material costs, enhances resource efficiency, promotes recycling, and adds value to end-of-life materials. 

Ort, förlag, år, upplaga, sidor
Luleå: Luleå University of Technology, 2024
Serie
Doctoral thesis / Luleå University of Technology 1 jan 1997 → …, ISSN 1402-1544
Nyckelord
Co-rotating extrusion, Thermoplastic polymer, Biocomposites, Natural fibers, End-of-life textiles, Recycling, Resource efficiency
Nationell ämneskategori
Textil-, gummi- och polymermaterial
Forskningsämne
Trä och bionanokompositer
Identifikatorer
urn:nbn:se:ltu:diva-110325 (URN)978-91-8048-662-0 (ISBN)978-91-8048-663-7 (ISBN)
Disputation
2024-12-06, E632, Luleå University of Technology, Luleå, 10:00 (Engelska)
Opponent
Handledare
Projekt
Knut och Alice Wallenberg Stiftelse (KAW)Stora EnsoBio4Energy
Tillgänglig från: 2024-10-11 Skapad: 2024-10-10 Senast uppdaterad: 2025-06-16Bibliografiskt granskad

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