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Laser-induced phase transformations in microalloyed steels
Luleå University of Technology, Department of Engineering Sciences and Mathematics, Product and Production Development.ORCID iD: 0000-0002-3060-5831
2022 (English)Doctoral thesis, comprehensive summary (Other academic)
Abstract [en]

The application of thermal cycles below melting temperature can induce solid-to-solid phase transformation in steels, which is the transition between different crystalline structures of the same compound. There are many types of crystalline structures in steels produced, depending on the characteristics of the applied thermal cycle. For instance, rapid cooling can generate martensite structure that tends to increase the hardness of the steels, while slow cooling will more likely produce ferrite structure, which is less hard than the martensite structure. Laser heat treatment is one example where the laser becomes a thermal energy source, inducing thermal cycles below melting point and an extremely rapid cooling rate, which results in unexpected microstructures upon cooling. The mechanism of such phase transformations is still widely unknown, although the knowledge can be beneficial for many laser processes. Accordingly, studies on laser induced phase transformation are necessary.

The purpose of my work is explaining underlying mechanisms of solid-to-solid phase transformation in microalloyed steels due to short thermal cycles of the laser heat treatment. My work aims to (1) find the correlation between energy input distributions from the laser beam and temperature history during the laser heat treatment process and (2) describe how changes in the thermal cycle induced by laser illumination influence the phase transformation dynamics. This work focuses on martensitic transformation and infrared laser (1070 nm).

To explain martensitic transformation during laser heat treatment, this work involved ex-situ observations of the laser heat treated specimens. The study consists of varying the laser parameters, measuring the surface temperature of the specimens and simulating the in-depth temperature. Consecutively, characteristics (i.e., holding time, peak temperature, and cooling rate) of the measured and/or calculated thermal cycles were extracted, and the microstructures of the specimens were observed using microscopes. Finally, the thermal cycle characteristics and the microstructure of the specimens were related.

The results show that the energy input distributions from the laser beam (e.g., laser beam profile) determine the geometry of the treated area, while processing speed and laser power influence the cooling rate and peak temperature of the thermal cycle respectively. The short thermal cycles induced by the laser beam are able to induce martensitic structure in the specimen. However, ferrite structure unexpectedly remains in the treated area. The holding time, which is the duration of temperature staying above austenisation temperature, has an inverse correlation to the appearance of ferrite structure in the treated area. This relates to the carbon diffusion occurring during the process, in which the carbon atoms have to diffuse from rich-carbon-austenite into low-carbon-austenite before cooling. Accordingly, the amount of martensite structure in the treated area depends on the holding time value of the process. There are indications that the rapid cooling induced by the laser beam can abruptly stop the diffusion process. It is clear that the laser provides an opportunity to control martensite structure.

Place, publisher, year, edition, pages
Luleå University of Technology, 2022.
Series
Doctoral thesis / Luleå University of Technology, ISSN 1402-1544
National Category
Manufacturing, Surface and Joining Technology Metallurgy and Metallic Materials
Research subject
Manufacturing Systems Engineering
Identifiers
URN: urn:nbn:se:ltu:diva-89434ISBN: 978-91-8048-037-6 (print)ISBN: 978-91-8048-038-3 (electronic)OAI: oai:DiVA.org:ltu-89434DiVA, id: diva2:1641707
Public defence
2022-05-25, E231, Luleå tekniska universitet, Luleå, 09:00 (English)
Opponent
Supervisors
Funder
VinnovaAvailable from: 2022-03-03 Created: 2022-03-03 Last updated: 2025-10-21Bibliographically approved
List of papers
1. Influence of secondary-pass laser treatment on retained ferrite and martensite in 44MnSiVS6 microalloyed steel
Open this publication in new window or tab >>Influence of secondary-pass laser treatment on retained ferrite and martensite in 44MnSiVS6 microalloyed steel
2022 (English)In: Materials Today Communications, ISSN 2352-4928, Vol. 31, article id 103282Article in journal (Refereed) Published
Abstract [en]

Overlapping regions of laser surface treatment are necessary features when processing large surface areas or cylindrical specimens. However, complex microstructural changes that appear in the regions with multiple heat treatment can affect their mechanical properties. Therefore, this study focuses on examining thermal cycle characteristics and resulting microstructures, particularly martensite and retained ferrite structures, to better understand the correlation between experienced thermal cycles and resulting microstructures. Laser surface hardening experiments on 44MnSiVS6 microalloyed steels together with thermal diffusion simulations were conducted to relate microstructures after the secondary pass of the laser treatment to the local thermal cycles experienced during the process. The amount of retained ferrite was calculated and compared to the respective thermal cycle characteristics. Regions which experienced thermal cycles below Ac3 temperature showed microstructures similar to those after tempering. The sizes of retained ferrite structures were found to decrease as the total holding time increases regardless of how the holding time is distributed in multiple laser treatments. However, the size of retained ferrite structures were constant in the region where tempering effect occurred. This shows that the amount of retained ferrite can be tailored by modifying the experienced total holding time and a reduction of retained ferrite structure happens only if the secondary thermal cycle is above Ac3 temperature.

Place, publisher, year, edition, pages
Elsevier BV, 2022
Keywords
Overlapping multiple tracks, Crankshaft, Laser surface hardening, Tempering
National Category
Manufacturing, Surface and Joining Technology Metallurgy and Metallic Materials
Research subject
Manufacturing Systems Engineering
Identifiers
urn:nbn:se:ltu:diva-89431 (URN)10.1016/j.mtcomm.2022.103282 (DOI)000761190900002 ()2-s2.0-85124703406 (Scopus ID)
Funder
Vinnova, 2019-03618
Note

Validerad;2022;Nivå 2;2022-03-04 (hanlid);

Funder: Research Fund for Coal and Steel, RFCS (754155 and 800726)

Available from: 2022-03-03 Created: 2022-03-03 Last updated: 2025-10-21Bibliographically approved
2. Short thermal cycle treatment with laser of vanadium microalloyed steels
Open this publication in new window or tab >>Short thermal cycle treatment with laser of vanadium microalloyed steels
2020 (English)In: Journal of Manufacturing Processes, ISSN 1526-6125, Vol. 57, p. 543-551Article in journal (Refereed) Published
Abstract [en]

Improvement of crankshaft fatigue properties can be approached by altering its mechanical properties in the surface, such as laser surface treatment. Laser beam treatment offers efficient and precise surface hardening processing with possibility of reducing the production cost compared to the conventional hardening techniques. However, its characteristic of having short thermal cycle can be a challenge for the development of laser surface hardening techniques, such as inadequacy of literatures in phase transformation and resulting mechanical properties under rapid heating and cooling rate. Therefore, this work investigated the impact of short thermal cycles induced by the laser beam on the resulting microstructure and hardness properties in the surface of 38MnSiVS5 and 44MnSiVS6 microalloyed steels. Temperature cycles during the process were recorded and examined with the resulting microstructure along with microhardness values. 44MnSiVS6 microalloyed steel, which contains ca. double the amount of vanadium compared to 38MnSiVS5 steel, produces finer ferrite grains in the treated area for all investigated short thermal cycles. This fine-grained microstructure leads to steady hardness distributions in the treated area. The short thermal cycle was assumed to be unable to dissolve the vanadium precipitates that reside in the ferrite grains, which then initiate precipitation hardening.

Place, publisher, year, edition, pages
Elsevier, 2020
Keywords
Precipitation hardening, Short thermal cycle, Laser surface treatmen
National Category
Manufacturing, Surface and Joining Technology
Research subject
Manufacturing Systems Engineering
Identifiers
urn:nbn:se:ltu:diva-80567 (URN)10.1016/j.jmapro.2020.06.036 (DOI)000570221800002 ()2-s2.0-85084155349 (Scopus ID)
Note

Validerad;2020;Nivå 2;2020-10-07 (johcin)

Available from: 2020-08-26 Created: 2020-08-26 Last updated: 2025-10-22Bibliographically approved
3. Impact of laser beam oscillation strategies on surface treatment of microalloyed steel
Open this publication in new window or tab >>Impact of laser beam oscillation strategies on surface treatment of microalloyed steel
2020 (English)In: Journal of laser applications, ISSN 1042-346X, E-ISSN 1938-1387, Vol. 32, no 4, article id 042006Article in journal (Refereed) Published
Abstract [en]

The depth homogeneity of laser-treated zones is one possible factor to define the quality and efficacy of altered mechanical properties in materials. For instance, half-rounded cross-sectional shapes of laser hardened zones using Gaussian beams provide dissimilar hardened depth in the edges and center of the treated area. This means that the in-depth distribution of compressive residual stress varies between the edges and the center of the hardened area. Nonhomogeneity of compressive residual stress distributions can inhibit fatigue properties and can lead to product failure. The utilization of oscillated laser beams has been proven to improve the welding efficiency and energy input distribution to the material, which promises achieving a homogeneous depth of laser-treated zones in hardening applications. Therefore, this work examines the influence of triangular, square, and circular beam oscillation strategies on the energy input distribution during the process and the geometry of the laser-treated zones on microalloyed steel. Laser beam pathways were assembled using a vector graphic editor to visualize the energy distribution from each oscillation strategy. Cross section images of the hardened tracks were taken and related to the thermal energy input profiles. It was revealed that each oscillation strategy demonstrates characteristic temporal and spatial thermal energy input distribution, influencing the geometry of the hardened zone. The circular oscillation strategy produced a widely constant depth in contrary to the triangular and square beam oscillation due to its characteristic energy distribution that allows homogeneous heat dissemination in the material. This confirms that the laser beam oscillation strategy can tailor the energy input distribution to optimize the processing outcome.

Place, publisher, year, edition, pages
American Institute of Physics (AIP), 2020
Keywords
laser beam oscillation, laser beam shaping, laser surface treatment
National Category
Manufacturing, Surface and Joining Technology
Research subject
Manufacturing Systems Engineering
Identifiers
urn:nbn:se:ltu:diva-81182 (URN)10.2351/7.0000196 (DOI)000575069100001 ()2-s2.0-85092347774 (Scopus ID)
Note

Validerad;2020;Nivå 2;2020-10-19 (johcin)

Available from: 2020-10-19 Created: 2020-10-19 Last updated: 2025-10-22Bibliographically approved
4. Carbon diffusion and martensitic transformation during laser surface treatment
Open this publication in new window or tab >>Carbon diffusion and martensitic transformation during laser surface treatment
Show others...
(English)In: Article in journal (Other academic) Submitted
National Category
Metallurgy and Metallic Materials Manufacturing, Surface and Joining Technology
Research subject
Manufacturing Systems Engineering
Identifiers
urn:nbn:se:ltu:diva-89432 (URN)
Projects
StiffcrankIn-situ High Energy Synchrotron X-ray Diffraction of Laser Materials Processing
Funder
Vinnova, 2019-03618_VINNOVA
Note

Funder: EC Research Fund for Coal and Steel, RFCS, (no. 754155)

Available from: 2022-03-03 Created: 2022-03-03 Last updated: 2025-10-21
5. Temperature distribution inside metal droplets influenced by tailored laser beam pulse
Open this publication in new window or tab >>Temperature distribution inside metal droplets influenced by tailored laser beam pulse
(English)Manuscript (preprint) (Other academic)
National Category
Manufacturing, Surface and Joining Technology Metallurgy and Metallic Materials
Identifiers
urn:nbn:se:ltu:diva-89433 (URN)
Available from: 2022-03-03 Created: 2022-03-03 Last updated: 2025-10-21
6. Microstructure and mechanical properties of laser surface treated 44MnSiVS6 microalloyed steel
Open this publication in new window or tab >>Microstructure and mechanical properties of laser surface treated 44MnSiVS6 microalloyed steel
Show others...
2020 (English)In: Optics and Laser Technology, ISSN 0030-3992, E-ISSN 1879-2545, Vol. 127, article id 106139Article in journal (Refereed) Published
Abstract [en]

Fatigue property improvement for automotive components such as crankshafts can be achieved through material selection and tailored surface design. Microalloyed steels are of high interest for automotive applications due to their balanced properties, excellent hardenability and good machinability. Lasers facilitate efficient and precise surface processing and understanding the laser-material-property interrelationships is the key to process optimisation. This work examines microstructural development during laser surface treatment of 44MnSiVS6 microalloyed steel and the resulting mechanical properties. Laser beam shaping techniques are employed to evaluate the impact of beam shaping on the process. It revealed that ferrite structures remain in the treated area surrounded by martensite due to insufficient heating and dwell time of carbon diffusion.

Place, publisher, year, edition, pages
Elsevier, 2020
Keywords
Laser surface treatment, 44MnSiVS6, Laser beam shaping, Microalloyed steel, Phase transformation
National Category
Manufacturing, Surface and Joining Technology
Research subject
Manufacturing Systems Engineering
Identifiers
urn:nbn:se:ltu:diva-77853 (URN)10.1016/j.optlastec.2020.106139 (DOI)000523646800033 ()2-s2.0-85079522725 (Scopus ID)
Note

Validerad;2020;Nivå 2;2020-04-21 (alebob)

Available from: 2020-02-25 Created: 2020-02-25 Last updated: 2025-10-22Bibliographically approved

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Dewi, Handika Sandra

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