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Use of co-rotating extrusion process for the development of resource-efficient biocomposites
Luleå University of Technology, Department of Engineering Sciences and Mathematics, Material Science.ORCID iD: 0000-0002-9239-7652
2024 (English)Doctoral thesis, comprehensive summary (Other academic)
Abstract [en]

Natural fibers have gained popularity for reinforcing polymers due to their renewability, biodegradability, and usually have lower costs than synthetic fibers. The demand to reduce environmental impact has heightened awareness of the importance of adopting resource-efficient alternatives in line with recycling, reusing, and responsible consumption practices. This study integrates resource-efficient use of materials using a co-rotating twin screw extruder (TSE) in the development of biocomposites as an alternative for recycling, reducing landfill disposal, and contributing to the circular economy. 

The influence of recycling wood-polymer composites (WPCs) was explored by subjecting the materials to nine extrusion cycles. The properties of the WPCs were evaluated after every other cycle and compared to those of virgin and recycled polypropylene (PP) and WPCs. The results revealed that, although shear forces during extrusion decreased the aspect ratio of the wood fibers and reduced tensile strength after nine recycling cycles, the WPC still maintained higher mechanical properties than virgin PP, highlighting the advantages of using recycled WPC over PP. Recycling WPCs reduces the overconsumption of fossil-based plastics, decreases landfill disposal, and lessens the need for virgin fibers. 

The valorization of end-of-life textiles was studied as a potential candidate for use in biocomposites. The primary challenge was to develop a low-energy consumption method for feeding, fibrillating, and compounding textiles with thermoplastic polymers without requiring chemical or mechanical pretreatments. A continuous extrusion process, recycled-textile long fiber thermoplastic (RT-LFT), was developed to incorporate end-of-life textiles into a PP matrix using a co-rotating TSE. The results demonstrated that RT-LFT is a direct, effective, and energy-efficient method for compounding end-of-life textiles with polymer, enabling the textiles to be separated into individual fibers that are well dispersed within the matrix. 

In addition, the performance of fibers from end-of-life textiles was also evaluated using PP, and Bio-flex a biodegradable blend of polybutylene adipate terephthalate (PBAT)/ polylactic acid (PLA). The addition of the fibers did not show improvements in the mechanical properties of the PP matrix but showed great enhancement for the Bio-flex matrix. Adding fibers also improved the flow properties and melt strength of the polymers. Moreover, the disintegration under compositing conditions showed that the addition of fibers delayed the process when compared to neat polymer, but after 75 days cotton and silk biocomposites began to disintegrate. 

WPCs are often modified with fossil-based virgin elastomers to enhance their impact and toughness properties. However, the use of these elastomers increases competition for limited resources and raises the costs of WPCs. To address this, the influence of recycled materials as impact modifiers in WPCs was investigated by replacing virgin elastomer with recycled fibers from end-of-life textiles and recycled elastomer. The results indicated that both recycled materials are viable alternatives to virgin elastomer, offering comparable impact and toughness properties while reducing the WPCs' carbon footprint and costs. 

In conclusion, using recycled or end-of-life materials presents an excellent alternative to virgin materials in biocomposites. It contributes to the circular economy, reduces landfill waste, decreases material costs, enhances resource efficiency, promotes recycling, and adds value to end-of-life materials. 

Place, publisher, year, edition, pages
Luleå: Luleå University of Technology, 2024.
Series
Doctoral thesis / Luleå University of Technology 1 jan 1997 → …, ISSN 1402-1544
Keywords [en]
Co-rotating extrusion, Thermoplastic polymer, Biocomposites, Natural fibers, End-of-life textiles, Recycling, Resource efficiency
National Category
Textile, Rubber and Polymeric Materials
Research subject
Wood and Bionanocomposites
Identifiers
URN: urn:nbn:se:ltu:diva-110325ISBN: 978-91-8048-662-0 (print)ISBN: 978-91-8048-663-7 (electronic)OAI: oai:DiVA.org:ltu-110325DiVA, id: diva2:1904959
Public defence
2024-12-06, E632, Luleå University of Technology, Luleå, 10:00 (English)
Opponent
Supervisors
Projects
Knut och Alice Wallenberg Stiftelse (KAW)Stora EnsoBio4EnergyAvailable from: 2024-10-11 Created: 2024-10-10 Last updated: 2024-11-15Bibliographically approved
List of papers
1. The Effect of Recycling on Wood-Fiber Thermoplastic Composites
Open this publication in new window or tab >>The Effect of Recycling on Wood-Fiber Thermoplastic Composites
2020 (English)In: Polymers, E-ISSN 2073-4360, Vol. 12, no 8, article id 1750Article in journal (Refereed) Published
Abstract [en]

The aim of this study was to investigate the effect of recycling on polypropylene (PP) and wood-fiber thermoplastic composites (WPCs) using a co-rotating twin-screw extruder. After nine extrusion passes microscopy studies confirmed that the fiber length decreased with the increased number of recycling passes but the increased processing time also resulted in excellent dispersion and interfacial adhesion of the wood fibers in the PP matrix. Thermal, rheological, and mechanical properties were studied. The repeated extrusion passes had minimal effect on thermal behavior and the viscosity decreased with an increased number of passes, indicating slight degradation. The recycling processes had an effect on the tensile strength of WPCs while the effect was minor on the PP. However, even after the nine recycling passes the strength of WPC was considerably better (37 MPa) compared to PP (28 MPa). The good degree of property retention after recycling makes this recycling strategy a viable alternative to discarding the materials. Thus, it has been demonstrated that, by following the most commonly used extrusion process, WPCs can be recycled several times and this methodology can be industrially adapted for the manufacturing of recycled products.

Place, publisher, year, edition, pages
MDPI, 2020
Keywords
wood fiber, thermoplastic composite, extrusion, mechanical properties, recycling
National Category
Bio Materials
Research subject
Wood and Bionanocomposites
Identifiers
urn:nbn:se:ltu:diva-80342 (URN)10.3390/polym12081750 (DOI)000568035500001 ()32764421 (PubMedID)2-s2.0-85089830225 (Scopus ID)
Funder
Knut and Alice Wallenberg Foundation, 225442
Note

Validerad;2020;Nivå 2;2020-08-18 (alebob)

Available from: 2020-08-10 Created: 2020-08-10 Last updated: 2024-10-10Bibliographically approved
2. Resource-efficient manufacturing process of composite materials: Fibrillation of recycled textiles and compounding with thermoplastic polymer
Open this publication in new window or tab >>Resource-efficient manufacturing process of composite materials: Fibrillation of recycled textiles and compounding with thermoplastic polymer
2023 (English)In: Composites. Part A, Applied science and manufacturing, ISSN 1359-835X, E-ISSN 1878-5840, Vol. 175, article id 107773Article in journal (Refereed) Published
Abstract [en]

This study aimed to develop a manufacturing process for recycled textile long fiber thermoplastics (RT-LFT) and thereby contribute to circular economy. Three different post-consumer textiles (cotton denim and plain weave, and silk plain weave) were cut into strips and fed directly into a co-rotating twin-screw extruder in which the textile was fibrillated and compounded with polypropylene (PP). The fibrillation of the textile, fiber dispersion, and interaction with the matrix polymer were studied, and the thermal and mechanical properties of the composites were evaluated. For example, cotton denim composites containing 30 wt% fiber content resulted in 26% increase in yield strength and a 72% increase in modulus when compared with that of PP. The RT-LFT process is a straightforward method for transforming used textiles into composites like cups and bottoms, offering advantages such as reduced manufacturing costs, add value for waste material, and lower carbon emissions.

Place, publisher, year, edition, pages
Elsevier, 2023
National Category
Textile, Rubber and Polymeric Materials Bio Materials
Research subject
Wood and Bionanocomposites
Identifiers
urn:nbn:se:ltu:diva-101416 (URN)10.1016/j.compositesa.2023.107773 (DOI)001083680100001 ()2-s2.0-85171795421 (Scopus ID)
Funder
Knut and Alice Wallenberg Foundation, KAW 2018.0451Stora Enso
Note

Validerad;2023;Nivå 2;2023-09-22 (joosat);

CC BY 4.0 License

Available from: 2023-09-22 Created: 2023-09-22 Last updated: 2024-10-10Bibliographically approved
3. Use of Recycled Additive Materials to Promote Efficient Use of Resources While Acting as an Effective Toughness Modifier of Wood–Polymer Composites
Open this publication in new window or tab >>Use of Recycled Additive Materials to Promote Efficient Use of Resources While Acting as an Effective Toughness Modifier of Wood–Polymer Composites
2024 (English)In: Polymers, E-ISSN 2073-4360, Vol. 16, no 18, article id 2549Article in journal (Refereed) Published
Abstract [en]

Wood–polymer composites (WPCs) with polypropylene (PP) matrix suffer from low toughness, and fossil-based impact modifiers are used to improve their performance. Material substitution of virgin fossil-based materials and material recycling are key aspects of sustainable development and therefore recycled denim fabric, and elastomer were evaluated to replace the virgin elastomer modifier commonly used in commercial WPCs. Microtomography images showed that the extrusion process fibrillated the denim fabric into long, thin fibers that were well dispersed within the WPC, while the recycled elastomer was found close to the wood fibers, acting as a soft interphase between the wood fibers and PP. The fracture toughness (KIC) of the WPC with recycled denim fabric matched the commercial WPC which was 1.4 MPa m1/2 and improved the composite tensile strength by 18% and E-modulus by 54%. Recycled elastomer resulted in slightly lower KIC, 1.1 MPa m1/2, as well as strength and modulus while increasing elongation and contributing to toughness. The results of this study showed that recycled materials can potentially be used to replace virgin fossil-based elastomeric modifiers in commercial WPCs, thereby reducing the CO2 footprint by 23% and contributing to more efficient use of resources.

Place, publisher, year, edition, pages
MDPI, 2024
Keywords
wood–polymer composites, recycled modifiers, impact properties, fracture toughness, microtomography
National Category
Composite Science and Engineering
Research subject
Wood and Bionanocomposites
Identifiers
urn:nbn:se:ltu:diva-110043 (URN)10.3390/polym16182549 (DOI)001323651600001 ()39339013 (PubMedID)2-s2.0-85205130062 (Scopus ID)
Funder
Knut and Alice Wallenberg FoundationBio4Energy
Note

Validerad;2024;Nivå 2;2024-09-19 (joosat);

Full text license: CC BY;

Funder: Stora Enso (KAW 2018.0451);

Available from: 2024-09-19 Created: 2024-09-19 Last updated: 2024-11-20Bibliographically approved
4. Bio-flex® copolymer properties improved with end-of-life polyester, viscose, cotton, and silk fibers
Open this publication in new window or tab >>Bio-flex® copolymer properties improved with end-of-life polyester, viscose, cotton, and silk fibers
(English)Manuscript (preprint) (Other academic)
National Category
Textile, Rubber and Polymeric Materials
Identifiers
urn:nbn:se:ltu:diva-110323 (URN)
Projects
Bio4Energy
Available from: 2024-10-10 Created: 2024-10-10 Last updated: 2024-10-10

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