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Optimized landfill cover to prevent oxidation in disposed sulfide soil
Luleå University of Technology, Department of Civil, Environmental and Natural Resources Engineering, Mining and Geotechnical Engineering. (Geoteknik)ORCID iD: 0000-0001-9688-9614
(English)In: Waste Management, ISSN 0956-053X, E-ISSN 1879-2456Article in journal (Refereed) Submitted
Abstract [en]

Sulfide-rich soils contain iron monosulfides and disulfides, which can oxidize under aerobic conditions when the soil is drained, facilitating oxygen diffusion and leading to the acidification of surrounding watercourses. This type of soil is often excavated due to its unsuitable geotechnical properties. As a result, soils with acidification potential need to be safely transported and deposited in landfills. Moisture content plays a crucial role in controlling the oxidation process, as maintaining optimal moisture levels limits oxygen diffusion, thereby preventing oxidation and acid generation. This study uses numerical modeling using SEEP/W to predict moisture fluctuations in sulfide soil landfills under various conditions. It further investigates the effects of soil properties, weather conditions, and landfill cover thickness on landfill performance, focusing on their role in maintaining moisture levels that inhibit sulfide oxidation. Results indicate that soil hydrological properties have a significant impact on saturation levels in the landfill, independent of other parameters. Adding a capillary break positively affects the moisture levels period studied, and a thicker cover enhances moisture retention. Keeping the water table close to the surface helps the system recover water lost due to evaporation and weather changes. These findings showed the current cover design practices, mandating uniform 1-meter cover thickness for all sulfide soil landfills is over-design in some cases and provide helpful insights for developing effective management plans to mitigate environmental risks and optimize landfill construction.

Keywords [en]
Sulfide soil, Landfills, Seep/w, Volumetric water content, waste soil
National Category
Geotechnical Engineering and Engineering Geology
Research subject
Soil Mechanics
Identifiers
URN: urn:nbn:se:ltu:diva-111007OAI: oai:DiVA.org:ltu-111007DiVA, id: diva2:1919731
Available from: 2024-12-09 Created: 2024-12-09 Last updated: 2025-10-21
In thesis
1. Management of Excavated Sulfide soils: Enhancing Mechanical Stability and Maintaining Moisture Content
Open this publication in new window or tab >>Management of Excavated Sulfide soils: Enhancing Mechanical Stability and Maintaining Moisture Content
2025 (English)Doctoral thesis, comprehensive summary (Other academic)
Abstract [en]

Most scientific literature on sulfide-rich soils address the environmental hazard caused by the oxidation of Potential Acid Sulfate Soil (PASS) in its unoxidized form to Acid Sulfate Soil (ASS) when exposed to oxygen. Sulfide-rich soils pose also significant geotechnical challenges due to high water content and organic content, fine particles, lack of consolidation and acid-generating potential. Excavation and disposal are often necessary for infrastructure projects in e.g. Sweden and Finland. This thesis investigates approaches managing excavated sulfide soils by enhancing their mechanical properties for geotechnical applications and optimizing water content in the soil to mitigate oxidation risks.  

The research comprises three interrelated components. The first focuses on field experiments evaluating the efficiency of in-situ mixing techniques in improving the uniformity and mechanical stability of sulfide soil-binder mixtures. Results indicate that multi-stage mixing substantially enhanced soil-binder homogeneity and strength of the stabilized soil. Mechanical stability of laboratory prepared samples consistently outperformed those mixed in the field. A predictive model was developed to explain the observed trends, highlighting the critical roles of binder dosage, porosity, and water content in achieving stabilization.  

The second component examines the stabilization of acid sulfate soils using Portland cement and Multicem binders. Portland cement was more effective in enhancing mechanical properties due to its rapid increase in alkalinity, particularly in highly acidic soils. Multicem, while effective under moderately acidic conditions, was less successful in environments with high acidity. The study emphasized the importance of understanding the interactions between binder type, soil composition, and environmental factors.   

The final part investigates the role of multi-layer soil cover systems in mine and sulfide soil landfill designs in controlling moisture dynamics. Sulfide soil landfills were analyzed using numerical modeling validated through field instrumentation. The findings demonstrated that cover material properties, thickness, and the inclusion of features like capillary breaks are significant in maintaining moisture and minimizing environmental risks by oxidation. These insights were also applies to mine covers.  

This thesis provides a framework for a more sustainable management of sulfiderich soils by integrating findings from field experiments, laboratory, and numerical modeling. This study aims to contribute to the development of practical strategies to reduce society’s reliance on landfills for managing excavated sulfide soils, promoting geotechnical applications while mitigating environmental impacts.

Place, publisher, year, edition, pages
Luleå: Luleå tekniska universitet, 2025
Series
Doctoral thesis / Luleå University of Technology 1 jan 1997 → …, ISSN 1402-1544
National Category
Geotechnical Engineering and Engineering Geology
Research subject
Soil Mechanics
Identifiers
urn:nbn:se:ltu:diva-111009 (URN)978-91-8048-718-4 (ISBN)978-91-8048-719-1 (ISBN)
Public defence
2025-03-11, E632, Luleå University of Technology, Luleå, 09:00 (English)
Opponent
Supervisors
Available from: 2024-12-10 Created: 2024-12-09 Last updated: 2025-10-21Bibliographically approved

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Ziagharib, Alaleh

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