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Management of Excavated Sulfide soils: Enhancing Mechanical Stability and Maintaining Moisture Content
Luleå University of Technology, Department of Civil, Environmental and Natural Resources Engineering, Mining and Geotechnical Engineering.ORCID iD: 0000-0001-9688-9614
2025 (English)Doctoral thesis, comprehensive summary (Other academic)
Abstract [en]

Sulfide-rich soils pose significant geotechnical and environmental challenges due to high water content and organic content, fine particles, and acid-generating potential upon oxidation. Excavation and disposal are often necessary for infrastructure projects, but traditional disposal methods, including landfilling, are costly. This thesis investigates sustainable approaches to manage excavated sulfide soils by enhancing their mechanical properties for geotechnical applications and optimizing moisture retention in the soil to mitigate oxidation risks.

The research comprises three interrelated components. The first part focuses on field experiments evaluating the efficiency of mixing techniques in improving the uniformity and mechanical stability of soil-binder mixtures. The results revealed that multi-stage mixing substantially enhanced homogeneity and the strength of the stabilized soil, though laboratory-prepared samples consistently outperformed those mixed in the field. A predictive model was developed to explain the observed trends, highlighting the critical roles of binder dosage, porosity, and water content in achieving optimal stabilization results.

The second component examines the stabilization of acid sulfate soils using Portland cement and Multicem binders. Portland cement demonstrated superior effectiveness in enhancing mechanical properties due to its rapid alkalinity increase, particularly in highly acidic soils. Multicem, while effective under moderately acidic conditions, was less successful in environments with extreme acidity. The study emphasized the importance of understanding the interactions between binder type, soil composition, and environmental factors, as well as the role of porosity reduction in achieving enhanced mechanical stability.

The final part investigates the role of multi-layer mine soil cover systems in controlling oxygen ingress and moisture dynamics, alongside sulfide soil landfill designs. Mine covers, which are engineered to maintain optimal moisture levels and limit oxidation, were analyzed using numerical modeling validated through field instrumentation. The findings demonstrated that cover material properties, thickness, and the inclusion of features like capillary breaks are pivotal in maintaining moisture retention and minimizing environmental risks. These insights were also applied to sulfide soil landfills, where improved designs were shown to enhance landfill performance and contribute to a better understanding of sealing layer behavior in mine remediation projects.

This thesis provides a comprehensive framework for the sustainable management of sulfide-rich soils by integrating findings from field experiments, stabilization studies, and numerical modeling. This work aims at to contribute to the development of practical strategies to reduce the society’s dependency on landfill to handle excavated sulfide soils, improving geotechnical applications, and mitigating environmental impacts through optimized landfill and mine cover designs.

Place, publisher, year, edition, pages
Luleå: Luleå tekniska universitet, 2025.
Series
Doctoral thesis / Luleå University of Technology 1 jan 1997 → …, ISSN 1402-1544
National Category
Geotechnical Engineering
Research subject
Soil Mechanics
Identifiers
URN: urn:nbn:se:ltu:diva-111009ISBN: 978-91-8048-718-4 (print)ISBN: 978-91-8048-719-1 (electronic)OAI: oai:DiVA.org:ltu-111009DiVA, id: diva2:1919736
Public defence
2025-02-11, E632, Luleå University of Technology, Luleå, 09:00 (English)
Opponent
Supervisors
Available from: 2024-12-10 Created: 2024-12-09 Last updated: 2025-02-05Bibliographically approved
List of papers
1. Predictive Pattern of Undrained Shear Strength in Stabilized Sulfur Rich Silty Soil Based on Binder and Initial Mixing Water Content
Open this publication in new window or tab >>Predictive Pattern of Undrained Shear Strength in Stabilized Sulfur Rich Silty Soil Based on Binder and Initial Mixing Water Content
Show others...
2024 (English)In: Geotechnical and Geological Engineering, ISSN 0960-3182, E-ISSN 1573-1529, Vol. 42, p. 5033-5050Article in journal (Refereed) Published
Abstract [en]

A laboratory investigation was conducted to identify principal variables-initial mixing water content, porosity, and binder content- impacting undrained shear strength (qu) of stabilized sulfur-rich silty soil. An equation for predicting qu of stabilized soil was established based on the experimental data. Initially, samples were prepared with soils sample with different initial water and binder contents. Multicem, a binder consisting of a mix of cement and cement kiln dust, was added to the samples. Three different percentages of Multicem were mixed at five different soil water contents to measure qu of stabilized mixtures to understand how water content and porosity levels in the samples affect the performance of the binder and their combined impact on the strength of the samples. The soil-binder mixtures were compacted and subsequently cured in laboratory-controlled environment. The prepared samples were tested in uniaxial compression test apparatus. The results evidenced that binder content and corresponding porosity affect the strength of specimens at an equal water content. The results showed that at equal initial mixing water content, the qu of a sample increased by increasing binder content. Furthermore, it was observed that increase of binder content has a reverse effect on porosity. It was appeared lowering the soil water content, initially increased the strength until an optimum water content. Further lowering water content increased the porosity and consequently decreased qu of samples. Moreover, a ratio of porosity/volumetric binder content was chosen to evaluate the impact of these two variables on strength of samples. This study showed that qu is an exponential function of porosity/binder volumetric content ratio which depends on initial mixing water content of mixtures. It was shown at water content lower than the optimum, results of stabilization are more effective than in soil at higher water contents. Therefore, reducing the water content and thereby porosity has more significant effect on improving qu than increasing the binder content.

Place, publisher, year, edition, pages
Springer Nature, 2024
Keywords
Binder, Silty soil, Soil stabilization, Unconfined compressive strength, Volumetric binder content, Water content
National Category
Geotechnical Engineering
Research subject
Soil Mechanics
Identifiers
urn:nbn:se:ltu:diva-107504 (URN)10.1007/s10706-024-02828-y (DOI)001238565000001 ()2-s2.0-85195201800 (Scopus ID)
Funder
European Regional Development Fund (ERDF)Swedish Transport AdministrationSvenska Byggbranschens Utvecklingsfond (SBUF)
Note

Validerad;2024;Nivå 1;2024-08-13 (signyg);

Full text license: CC BY 4.0

Available from: 2024-06-18 Created: 2024-06-18 Last updated: 2025-02-05Bibliographically approved
2. Performance of Excavated Sulfur-Rich Soil Stabilized with Binder: A Field Study of Mixing Efficiency
Open this publication in new window or tab >>Performance of Excavated Sulfur-Rich Soil Stabilized with Binder: A Field Study of Mixing Efficiency
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2023 (English)In: Advances in Civil Engineering / Hindawi, ISSN 1687-8086, E-ISSN 1687-8094, article id 5446332Article in journal (Refereed) Published
Abstract [en]

In this study, a mixing procedure of sulfur-rich soil and cement-based binder to enhance the soil’s unconfined compressive strength (UCS) was tested in field conditions for geotechnical applications. The focus was to evaluate uniformity of industrial size soil-binder mixture, blended by existing method. This paper outlined sampling strategy and the number of samples needed for a valid uniformity evaluation. Moreover, this study emphasized the difference between field mixing and laboratory mixture preparation by comparing UCS of stabilized soil samples in the field and UCS of corresponding samples mixed and prepared in the laboratory environment. In the field, soil and cement were blended in two to four stages with 5% and 7% cement—the percentages being based on the soil’s dry weight under field conditions. Samples were taken from the field mixtures after each stage. Since the number of samples needed to be representative of mixture characteristics for large-scale mixing is not standardized, this field experiment included two phases. The first phase was dedicated to finding a sampling strategy for a large soil pile along with measuring UCS of collected samples. In the second phase, sample collection was conducted based on the results of sampling strategy from the first phase. In the laboratory, samples with percentages of binder similar to the amount of binder in the field were also prepared. Both field and laboratory samples were prepared using the tapping method in the laboratory for UCS test. Samples were cured under similar conditions for 28 days. The results showed that the uniformity of mixture improved after each additional mixing stage. In addition, while spots with low UCS were observed in the second mixing step, these spots were eliminated in the third mixing step, and results of the UCS tests were comparatively uniform. Moreover, comparison of the samples revealed that the UCS of the laboratory mixture is higher than that of the field mixture. This showed that even though the UCS is a good standard for comparing the strength of different soils stabilized with different percentages or types of binders in the field mixing, the actual strength of the stabilized mixtures under field circumstances is lower than that in laboratory prepared mixtures.

Place, publisher, year, edition, pages
Hindawi Publishing Corporation, 2023
National Category
Geotechnical Engineering
Research subject
Soil Mechanics
Identifiers
urn:nbn:se:ltu:diva-93990 (URN)10.1155/2023/5446332 (DOI)000965277600002 ()2-s2.0-85152794483 (Scopus ID)
Projects
Sustainable treatment of coastal deposited sulfde soils (STASIS)
Note

Validerad;2023;Nivå 2;2023-04-14 (hanlid);

Funder: Interreg Botnia-Atlantica program

Available from: 2022-11-10 Created: 2022-11-10 Last updated: 2025-02-05Bibliographically approved
3. Validation of a Sulfide Soil Landfill Numerical Model using Seep/W Software
Open this publication in new window or tab >>Validation of a Sulfide Soil Landfill Numerical Model using Seep/W Software
2024 (English)Conference paper, Published paper (Other academic)
Abstract [en]

Due to their silty texture and high organic content, sulfide soils are typically unsuitable for use as a foundation for construction projects. In most cases, excavation and replacement with other construction materials are needed to ensure the structural integrity of building or infrastructure. Landfills are commonly used for the disposal of excavated sulfide soil. Because of the chemical properties of these soils and the risk of acidification, these landfills need to be kept saturated to limit oxygen diffusion. However, the long-term behaviour of these landfills is not yet fully understood, highlighting the need for further research to investigate the fluctuation of the degree of saturation in the soil, under different conditions. This study examined the effect of seasons on the degree of saturation in sulfide soil landfills and its effect on oxygen transport. The objective of the current study was to validate a numerical model of a sulfide soil embankment, done using SEEP/W software, with data from the monitoring of a sulfide soil landfill, in Northern Sweden. A one-dimensional numerical model of the landfill was created using laboratory measurements of hydraulic conductivity and water retention capacity. This model was then validated by comparing it with data from installed sensors. The numerical model accurately predicted the degree of saturation changes over time in the landfilled soil. These findings allow engineers to optimize design and predict long-term performance under different environmental conditions. The study highlights the importance of numerical modelling in predicting long-term hydrological behaviour and offers valuable insights into sulfide soil landfill behaviour.

Keywords
Sulfide soil landfill, Numerical modelling, SEEP/W, Saturation degree, Oxygen transport.
National Category
Geotechnical Engineering
Research subject
Soil Mechanics
Identifiers
urn:nbn:se:ltu:diva-111008 (URN)
Conference
The XVIII European Conference on Soil Mechanics and Geotechnical Engineering (ECSMGE 2024), Lisbon, Portugal, August 26 to August 30, 2024.
Available from: 2024-12-09 Created: 2024-12-09 Last updated: 2025-02-05
4. Optimized landfill cover to prevent oxidation in disposed sulfide soil
Open this publication in new window or tab >>Optimized landfill cover to prevent oxidation in disposed sulfide soil
(English)In: Waste Management, ISSN 0956-053X, E-ISSN 1879-2456Article in journal (Refereed) Submitted
Abstract [en]

Sulfide-rich soils contain iron monosulfides and disulfides, which can oxidize under aerobic conditions when the soil is drained, facilitating oxygen diffusion and leading to the acidification of surrounding watercourses. This type of soil is often excavated due to its unsuitable geotechnical properties. As a result, soils with acidification potential need to be safely transported and deposited in landfills. Moisture content plays a crucial role in controlling the oxidation process, as maintaining optimal moisture levels limits oxygen diffusion, thereby preventing oxidation and acid generation. This study uses numerical modeling using SEEP/W to predict moisture fluctuations in sulfide soil landfills under various conditions. It further investigates the effects of soil properties, weather conditions, and landfill cover thickness on landfill performance, focusing on their role in maintaining moisture levels that inhibit sulfide oxidation. Results indicate that soil hydrological properties have a significant impact on saturation levels in the landfill, independent of other parameters. Adding a capillary break positively affects the moisture levels period studied, and a thicker cover enhances moisture retention. Keeping the water table close to the surface helps the system recover water lost due to evaporation and weather changes. These findings showed the current cover design practices, mandating uniform 1-meter cover thickness for all sulfide soil landfills is over-design in some cases and provide helpful insights for developing effective management plans to mitigate environmental risks and optimize landfill construction.

Keywords
Sulfide soil, Landfills, Seep/w, Volumetric water content, waste soil
National Category
Geotechnical Engineering
Research subject
Soil Mechanics
Identifiers
urn:nbn:se:ltu:diva-111007 (URN)
Available from: 2024-12-09 Created: 2024-12-09 Last updated: 2025-02-05
5. Mechanical properties of excavated sulfur rich soil stabilized with cement - A laboratory and field experiment
Open this publication in new window or tab >>Mechanical properties of excavated sulfur rich soil stabilized with cement - A laboratory and field experiment
2023 (English)Licentiate thesis, comprehensive summary (Other academic)
Abstract [en]

Sulfide soils are silty soils, often found in saturated conditions, under the groundwater level. Characteristics of these soils, including particle size distribution and consistency limits along with chemical composition and environmental properties, cause excavation to be necessary for construction purposes. The excavated sulfide soil usually is transported and deposited in landfills. These soils are either deposited in saturated conditions or chemical buffers are added to the soil to prevent acidification. Special conditions of these landfills complicate the disposal procedure and the landfill maintenance which makes those financially expensive. Reusing sulfide soil in construction is a solution to reduce the expenses related to the management of sulfide soils. Since the mechanical properties of these soils are not suitable for construction purposes, the first step is to improve soil characteristics to the level that fulfills the needs of construction applications. One solution to improve the mechanical properties of the soil is adding a binder to the soil.

The main focus of the research was to improve the mechanical properties of soil. The research activities were divided into two parts. The first part was conducted in a laboratory environment to develop mixtures, while the second focused on transferring the results to field conditions. The laboratory tests included mixing soil and binder i.e., cement was added to the soil at different percentages to evaluate the soil improvement. An unconfined compressive strength (UCS) test was conducted on the stabilized sample to evaluate the efficiency of the stabilization. The resultsof UCS for the stabilized samples were compared. Since the soil contains a high amount of water, the traditional sample preparation was not suitable. Therefore, an alternative method was developed and evaluated. Moreover, the effect of curing time on the strength and consistency limit of stabilized samples was evaluated. At last, the effect of different variables, including porosity, binder content and initial water content, on the UCS of soil was investigated to identify potential correlation between UCS and different soil variables.

The results of the tests showed that adding a binder, regardless of the type of sulfide soil, positively affects the UCS of prepared samples and increasing the curing time increased the UCS of the samples. At higher cement content, the effect of curing time was more significant. Also, it was shown that at higher water content, the effect of binder is lower in comparison with the same soil at lower water content. By lowering the water content, the strength of stabilized soil reaches a maximum and drying further the soil, below the optimum water content, led to strength reduction. A correlation between UCS of sample and porosity/binder ratio was employed to predict the strength behavior of stabilized soil based on variables such as porosity, initial water content and binder dosage.

In order to evaluate if laboratory results can be applied to geotechnical applications, the second part of this research included a field mixing experiment for a large-scale mixture of soil and cement. The effect of the mixing procedure with common equipment on the homogeneity of industrial-size mixture was investigated. A sampling strategy for collecting representative samples of mixture was selected and assessed. the number of mixing steps and the effect of binder dosage on the uniformity of samples were studied. Results of UCS of samples prepared from field and laboratory mixture were compared and evaluated. A field evaluation was conducted to determine the quality of the mixture and how many mixing steps are required to reduce variability between samples. Two different percentages of binder were added to the 5 Tons of soil. The UCS test samples were prepared from the soil-cement mixture in the same way as they were prepared in the laboratory and cured for a specific time. The UCS test was conducted on cured samples. The test results were compared to evaluate the mixture homogeneity in the field.

The results showed that homogeneous mixtures can be obtained in the field with the available equipment. Assessing the sampling strategy showed that increasing the sampling sections from 5 to 12 and preparing single UCS sample from the collected soil provides representative samples from the soil mixture pile. Additionally, it was shown that by increasing mixing steps from 2 to 3, it was possible to eliminate samples with notable lower strength than average UCS. A greater number of mixing steps improves homogeneity while reducing the average UCS. It was found that mixing soil and binder in the laboratory improves strength better than mixing them in the field. When applying laboratory results to field design, this point must be taken into account.

Place, publisher, year, edition, pages
Luleå: Luleå University of Technology, 2023
Series
Licentiate thesis / Luleå University of Technology, ISSN 1402-1757
Keywords
Sulfur-rich soil, Mixing, Sampling, Unconfined compressive strength, stabilization, Porosity, Water content, Consistency limits
National Category
Geotechnical Engineering
Research subject
Soil Mechanics
Identifiers
urn:nbn:se:ltu:diva-93992 (URN)978-91-8048-212-7 (ISBN)978-91-8048-213-4 (ISBN)
Presentation
2023-01-20, E652, Luleå tekniska universitet, Luleå, 10:00 (English)
Opponent
Supervisors
Available from: 2022-11-10 Created: 2022-11-10 Last updated: 2025-02-05Bibliographically approved

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