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Membrane technologies for treatment of urban wastewater streams and resource recovery
Luleå University of Technology, Department of Civil, Environmental and Natural Resources Engineering, Architecture and Water.ORCID iD: 0000-0003-4983-3903
2025 (English)Doctoral thesis, comprehensive summary (Other academic)
Abstract [en]

Stormwater and blackwater are two urban wastewater streams with potential as valuable resources. The stormwater quality varies depending on catchment, actual rain pattern, pollutants sources, etc. Blackwater contains nutrients and energy that can be recovered. In addition, it contains organics, metals, micropollutants and microorganisms which might affect the efficiency of downstream processes. Efficient removal of contaminants from both stormwater and blackwater is essential for their reuse and recovery of resources, including water and nutrients. 

Membrane technology offers an advanced solution to improve the quality of stormwater and blackwater. While a number of studies have explored the application of membranes for stormwater treatment, the varying quality of stormwater raises questions about membranes’ efficiency in separating pollutants from different qualities of stormwater. More research is needed to understand the reusability of treated stormwater using membranes as well as the recovery of metals in the concentrate. 

The overall aim of this study is to improve the quality of stormwater and source-separated blackwater, which has a direct impact on the reusability of stormwater as water resource and of struvite as a biofertilizer. Nutrient recovery from blackwater after membrane treatment is a new concept requiring further attention. Membrane cleaning is essential for maintaining membrane efficiency. For stormwater, regular backwashing with different durations and chemical combinations were tested, and the fouling layer on the membrane was analyzed, using a scanning electron microscope. Backwash water was characterised. For blackwater, the membrane cleaning method used included backwashing combined with aeration, raising the question about its adequacy.

The ultrafiltration membrane was able to separate total suspended solids, oil, particulate metals, total phosphorus, turbidity and microorganisms from stormwater and effectively reduced organic compounds. After hygenisation, ultrafiltratered stormwater has a significant potential for non-potable uses, and its quality approaches potable standards, based on Swedish Food Agency. The struvite produced from membrane treated digestate resulted in struvite with more uniform struvite crystals, free of organic substances and metals (As, Ca, Cr, Cu, Pb and Si) stepping towards reusing this struvite as biofertilizer. The optimal backwash duration after stormwater treatment, for these set of experiments was 45 s considering membrane productivity. Chemical cleaning with sodium hydroxide, and with or without sodium hypochlorite followed by hydrochloric acid were compared which indicated that addition of sodium hypochlorite did not improve the efficiency of chemical cleaning. Analyses of the backwash water showed a high metal concentration which might indicate the potential for metal recovery.  Combinations of backwash and aeration was an efficient method to preserve membrane initial flux after digestate blackwater treatment. 

 

Place, publisher, year, edition, pages
Luleå tekniska universitet, 2025.
Series
Doctoral thesis / Luleå University of Technology 1 jan 1997 → …, ISSN 1402-1544
National Category
Water Engineering
Research subject
Urban Water Engineering
Identifiers
URN: urn:nbn:se:ltu:diva-111116ISBN: 978-91-8048-724-5 (print)ISBN: 978-91-8048-725-2 (electronic)OAI: oai:DiVA.org:ltu-111116DiVA, id: diva2:1922212
Public defence
2025-03-07, C305, Luleå University of Technology, Luleå, 09:00 (English)
Opponent
Supervisors
Available from: 2024-12-18 Created: 2024-12-18 Last updated: 2025-02-14Bibliographically approved
List of papers
1. Stormwater treatment using an ultrafiltration membrane and pulsatile fluid flow
Open this publication in new window or tab >>Stormwater treatment using an ultrafiltration membrane and pulsatile fluid flow
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2024 (English)In: Urban Water Journal, ISSN 1573-062X, E-ISSN 1744-9006, Vol. 21, no 10, p. 1176-1184Article in journal (Refereed) Published
Abstract [en]

A polymeric ultrafiltration (UF) membrane was used for stormwater treatment, with the focus on evaluating the increase in the membrane process productivity by adding pulsatile fluid flow to UF membrane treatment. Sedimentation and sieving were used as pre-treatment. The result showed that increasing the pulse frequency from 0 to 4 Hz increased productivity from -6.6 to 82 LMH. UF membrane removed suspended solids, oil and turbidity below detection limit. The UF membrane also separated total coliforms, E. coli and P. aeruginosa below detection limit. Total organic carbon (TOC) was reduced by between 70 and 91%. In addition, the UF membrane was able to reduce BOD7 and COD to below 7 mg/L in the permeate. According to the US EPA, WHO, and national regulations in Canada,  Japan, and South Korea, treated stormwater can be used for flushing toilets and streets irrigation and agricultural use. 

Place, publisher, year, edition, pages
Taylor & Francis, 2024
Keywords
PVP/PES, dead end filtration, pulse frequency, water reuse, fouling
National Category
Water Engineering
Research subject
Urban Water Engineering; Centre - Centre for Stormwater Management (DRIZZLE)
Identifiers
urn:nbn:se:ltu:diva-95825 (URN)10.1080/1573062X.2023.2183136 (DOI)000946252400001 ()2-s2.0-85149475630 (Scopus ID)
Funder
Swedish Research Council Formas, 2016-01447Vinnova, 2016-05176
Note

Validerad;2024;Nivå 2;2024-11-29 (joosat);

Full text: CC BY license

Available from: 2023-03-09 Created: 2023-03-09 Last updated: 2025-02-07Bibliographically approved
2. Enhancing stormwater treatment through ultrafiltration: impact of cleaning chemicals and backwash duration on membrane efficiency
Open this publication in new window or tab >>Enhancing stormwater treatment through ultrafiltration: impact of cleaning chemicals and backwash duration on membrane efficiency
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2023 (English)In: Water Reuse, ISSN 2709-6092, Vol. 13, no 4, p. 634-646Article in journal (Refereed) Published
Abstract [en]

The effect of chemical cleaning and regular backwashing on the efficiency of an ultrafiltration membrane fouled during stormwater treatment was studied. Increasing backwash time from 30 to 60 s resulted in an increase in productivity by 20%. However, the productivity was highest when a backwash time of 45 s was used (3% higher than using 60 s). Chemical cleaning was carried out using an alkaline solution (NaOH with or without NaOCl) followed by acid washing with HCl. The addition of NaOCl to the cleaning chemical did not significantly increase the efficiency of chemical cleaning, and the average pure water permeability increase was 97 ± 13 LMH bar−1 after chemical cleaning with NaOH followed by HCl and 117 ± 15 LMH bar−1 after chemical cleaning with NaOH + NaOCl followed by HCl, on average. In addition, reversibility after chemical cleaning was 96 ± 67%, on average. The result from scanning electron microscopy showed that at the end of the experiments, inorganic foulants existed in both the inner layer (feed side) and the outer layer (permeate side) of the membrane.

Place, publisher, year, edition, pages
IWA Publishing, 2023
Keywords
dead-end filtration, fouling, permeability, pulsatile fluid flow, runoff, stormwater treatment
National Category
Water Engineering
Research subject
Urban Water Engineering; Centre - Centre for Stormwater Management (DRIZZLE)
Identifiers
urn:nbn:se:ltu:diva-103058 (URN)10.2166/wrd.2023.106 (DOI)001107293300001 ()2-s2.0-85181444396 (Scopus ID)
Funder
Swedish Research Council Formas, 2016-20075
Note

Validerad;2024;Nivå 2;2024-03-15 (hanlid);

Funder: DRIZZLE Center for Stormwater Management (2016-05176);

License full text: CC BY 4.0

Available from: 2023-11-28 Created: 2023-11-28 Last updated: 2025-02-07Bibliographically approved
3. Treatment of digested blackwater using a submerged microfiltration membrane system or a drum filter
Open this publication in new window or tab >>Treatment of digested blackwater using a submerged microfiltration membrane system or a drum filter
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2025 (English)In: Separation and Purification Technology, ISSN 1383-5866, E-ISSN 1873-3794, Vol. 359, no Part 3, article id 130884Article in journal (Refereed) Published
Abstract [en]

After energy recovery from blackwater via anaerobic digestion, technologies such as struvite precipitation and ammonia stripping can be used to enhance nutrient recovery. However, the presence of suspended solids, organics and metals, can negatively impact the nutrient recovery processes. This study examined the treatment of digested blackwater, applying either a ceramic microfiltration membrane or a drum filter, operating in parallel in a source-separated wastewater plant. The digestate as well as the permeates from the membrane and drum filter were sampled regularly and evaluated. In general, the ceramic membrane proved to be more efficient in improving the quality of digested blackwater in comparison to the drum filter. The ceramic membrane reduced total suspended solids to below the detection limit, while the drum filter achieved 74 % removal. The membrane removed 74 %, 85 % and 76 % of TOC, BOD7 and COD-Cr, respectively, higher than the corresponding treatment with the drum filter, which removed 41 %, 42 % and 34 %, respectively. No significant differences in phosphate and ammonium concentrations (P-value = 0.05), before and after both treatment methods were observed. The membrane removed particulate-bound metals (As, Cd, Cr, Cu, Ni, Pb and Zn) up to 25 %, 95 %, 87 %, 95 %, 66 %, 90 % and 98 %, respectively. The drum filter achieved lower removal for particulate-bound As, Cd, Ni, Pb and Zn for 25 %, 79 %, 44 %, 56 % and 86 %, respectively. The removal of metals is critical to maintain struvite purity and prevent the struvite contamination due to co-precipitate of these metals.

Place, publisher, year, edition, pages
Elsevier, 2025
Keywords
Blackwater, Metal removal, Ceramic membrane, Organic matter, Drum filter, Anaerobic digestion, Nutrient recovery
National Category
Water Engineering Water Treatment
Research subject
Urban Water Engineering
Identifiers
urn:nbn:se:ltu:diva-110998 (URN)10.1016/j.seppur.2024.130884 (DOI)001373309700001 ()2-s2.0-85210713991 (Scopus ID)
Funder
Swedish Water, 21-118
Note

Validerad;2025;Nivå 2;2025-03-19 (u2);

Funder: Stormwater & Sewers;

Fulltext license: CC BY

Available from: 2024-12-09 Created: 2024-12-09 Last updated: 2025-03-19Bibliographically approved

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