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Sulfur isotope and trace element signatures of sulfides in the Pahtohavare area, Kiruna mining district, and the role of remobilization on the metal and sulfur budget
Luleå University of Technology, Department of Civil, Environmental and Natural Resources Engineering, Geosciences and Environmental Engineering. (Ore Geology)ORCID iD: 0000-0003-1583-502X
Luleå University of Technology, Department of Civil, Environmental and Natural Resources Engineering, Geosciences and Environmental Engineering. (Ore Geology)ORCID iD: 0000-0001-8682-8180
iCRAG, Department of Geology, Trinity College Dublin, Dublin, Ireland.
iCRAG, Department of Geology, Trinity College Dublin, Dublin, Ireland.
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(English)Manuscript (preprint) (Other academic)
Abstract [en]

The Kiruna mining district, Sweden, is well known for its many iron oxide-apatite (IOA) deposits (Kiruna-type), but also hosts several Cu-bearing ore bodies of different ages. This includes the Pahtohavare area which hosts both a pre-orogenic stratiform Cu (Fe ± Zn) ore body as well as three late-orogenic epigenetic Cu ± Au deposits. The region has undergone multiple phases of deformation, metasomatism, and mineralization during the Svecokarelian orogeny and the effect of each overprinting event on the sulfur and metal budget of later mineralization events remains unclear. Utilizing the structural framework of the Svecokarelian orogeny, Cu- and Fe-sulfides from the Pahtohavare area are classified based on microstructures into early and late generations, which are subsequently analyzed for in situ δ34S and trace element contents and assessed with Linear Mixed Effects (LME) modelling to test for statistical significance. Results indicate that δ34S values from both the early and late mineralization exhibit a wide range from ca. -26‰ to +6‰. Early sulfur fractionation occurred during biogenic sulfate reduction in a system with excess sulfate forming syn-depositional pyrrhotite with δ34S signatures from ca. -22‰ to -21‰. LME modelling indicates a slightly higher δ34S range (ca. -20‰ to +6‰) is associated with the epigenetic mineralization compared to the pre-orogenic mineralization (ca. -26‰ to -5‰) but overlapping signatures suggest mixing occurred between pre-existing sulfur reservoirs leading to inherited signatures for the late mineralizing event. Similarly, at the pre-orogenic deposit, Co/Ni ratios of pyrrhotite in remobilized textures show a strong overlap with pyrrhotite in syn-depositional textures, indicating a local metal source for remobilized sulfides. Pyrite Co/Ni ratios for the pre-orogenic mineralization are lower (c. 0.1-10) in comparison to the epigenetic mineralization (c. 0.1-100) but a mixing trend is interpreted between the deposits. The late mineralization event is therefore characterized by higher Co contents and δ34S values but mixing trends suggest metals and sulfur were also inherited from pre-existing sulfides. 

Keywords [en]
SIMS sulfur isotope, LA-ICP-MS trace element, Kiruna, sulfides, IOCG, remobilization
National Category
Earth and Related Environmental Sciences
Research subject
Ore Geology
Identifiers
URN: urn:nbn:se:ltu:diva-111561OAI: oai:DiVA.org:ltu-111561DiVA, id: diva2:1935527
Funder
EU, Horizon 2020, 776804Available from: 2025-02-07 Created: 2025-02-07 Last updated: 2025-02-07
In thesis
1. Energy, Structures, Metals, and Fluids: A Mineral Systems Study of Cu ± Au Mineralization in the Kiruna Mining District
Open this publication in new window or tab >>Energy, Structures, Metals, and Fluids: A Mineral Systems Study of Cu ± Au Mineralization in the Kiruna Mining District
2025 (English)Doctoral thesis, comprehensive summary (Other academic)
Abstract [en]

In light of the increased demand for raw materials to support the transition away from a fossil-fuel society, mineral exploration for future raw material sources is imperative, requiring a holistic mineral systems approach. This thesis focuses on the Pahtohavare area in the Kiruna mining district where three epigenetic Cu ± Au deposits of unknown age and structural setting occur within 0.5 km of a pre-orogenic stratiform Cu (Fe ± Zn) deposit, 2 km of the Rakkurijärvi iron oxide-copper-gold (IOCG) deposit, and 5 km of the giant Kiirunavaara iron oxide-apatite (IOA) deposit, which may have shared mineral system ingredients during ore formation. The aim of the thesis is to characterize the mineral system ingredients of the epigenetic Pahtohavare deposits utilizing an up-to-date regional tectonic framework and to assess parallels between other mineral systems in the district. The following ingredients were investigated in this study: 1) driving force, using U-Pb zircon geochronology of local igneous intrusions, 2) transport pathways and structural traps, utilizing structural analysis and field mapping, 3) metal sources, based on sulfide trace element and carbonate REE geochemistry, and 4) ligand and fluid sources, using S, Sr, and Nd-isotope analyses.

U-Pb zircon geochronology of intrusions in the district where Cu-mineralization is spatially proximal yields ages unanimously from the early phase of the Svecokarelian orogeny (ca. 1923-1867 Ma including age uncertainties). These ages suggest magmatism provided a thermal energy drive for the mineral systems developing during this time such as the Kiirunavaara IOA and Rakkurijärvi IOCG.

Structural analysis and petrographic investigation from the Pahtohavare area show that the host rocks for the Pahtohavare deposits are folded into a noncylindrical, SE-plunging anticline and that cleavage measurements mirror the fold geometry. Foliation trails, mylonitic fabrics, and porphyroclasts with pressure shadows characterize the S0/S1 fabric as tectonic and constrains the fold as F2, indicating the folding event occurred during the late phase of the Svecokarelian orogeny (ca. 1.81-1.78 Ga). The epigenetic Pahtohavare deposits sit in brittle-ductile second-order structures that cross cut earlier foliation and the F2 fold, indicating that the deposits formed ca. 80 m.y. after the IOA and IOCG deposits in a distinct tectonic regime.

Petrographic investigation of microstructures identifies remobilization textures linking the pre-orogenic stratiform Cu (Fe ± Zn) and late-orogenic Pahtohavare Cu ± Au deposits. Comparison of Co/Ni ratios between structurally constrained early and late sulfide generations (0.1-10 vs. 0.1-100) indicate the late-orogenic fluids were capable of efficiently transporting and concentrating Co, implying hot and saline conditions. However, a weak Co/Ni ratio mixing trend between the two generations suggest the late-orogenic fluids primarily sourced metals from the pre-existing host rocks and sulfides, rather than an external reservoir. This is supported by flat REE (chondrite normalized) patterns from ore-related carbonate, reflecting a source from the mafic host rocks.

Both the pre- and late-orogenic sulfide generations have overlapping δ34S values ranging between ca. -20‰ and ca. -5‰ to near-zero values. The sulfur source for both mineral systems likely originated from local graphite schist horizons (ca. -22‰ to -21‰) and the volcanic host rocks. 87Sr/86Sr values for ore-related carbonates from the epigenetic Pahtohavare deposits are radiogenic (ca. 0.7095-0.7154) and form a mixing trend with strongly radiogenic (ca. 0.7134-0.7740) non-ore-related syn-sedimentary carbonate in biotite-altered rocks. This suggests a metamorphic fluid derived from crustal and Rb-rich rocks was responsible for the formation of the ore-related carbonate. Therefore, the Pahtohavare epigenetic deposits are suggested to have formed from metamorphic fluids during prograde metamorphism modified by the pre-enriched and altered host rocks in the Pahtohavare area.

The results of this thesis suggest that late-orogenic tectonism played a key role in reactivating mineral system ingredients, highlighting the potential of second-order structures near pre-existing mineral deposits as a strategic exploration target for Cu-mineralization in the region.  

Place, publisher, year, edition, pages
Luleå: Luleå University of Technology, 2025
Series
Doctoral thesis / Luleå University of Technology 1 jan 1997 → …, ISSN 1402-1544
Keywords
Mineral systems, Kiruna mining district, Pahtohavare, Cu-mineralization, IOCG, IOA, structural framework, remobilization, geochronology, structural geology, sulfide trace elements, sulfur isotopes, Sr isotopes, Nd isotopes, carbonates, geochemistry
National Category
Geology
Research subject
Ore Geology
Identifiers
urn:nbn:se:ltu:diva-111563 (URN)978-91-8048-757-3 (ISBN)978-91-8048-758-0 (ISBN)
Public defence
2025-04-04, C305, Luleå University of Technology, Luleå, 09:00 (English)
Opponent
Supervisors
Funder
EU, Horizon 2020, 776804
Available from: 2025-02-07 Created: 2025-02-07 Last updated: 2025-03-14Bibliographically approved

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