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Geology, magmatic evolution, and Cu-Au sulfide genesis of the Mundonguara deposit, Manica Greenstone Belt, Mozambique
Luleå University of Technology, Department of Civil, Environmental and Natural Resources Engineering, Geosciences and Environmental Engineering.ORCID iD: 0009-0005-0652-1100
2025 (English)Doctoral thesis, comprehensive summary (Other academic)
Abstract [en]

This thesis presents an integrated geological study of the Mundonguara Cu-Au deposit, located within the Archean Manica Greenstone Belt of western Mozambique, which forms part of the eastern Zimbabwe Craton. The research combines petrography, lithogeochemistry, U-Pb geochronology, mineralogy, mineral chemistry, and stable isotope analysis (S, C, and Oisotopes) to develop a comprehensive genetic model and contribute to the understanding of metallogenic processes in Archean greenstone terranes.

Fieldwork and geochemical analyses reveal that the Macequece Formation, which hosts the Mundonguara Cu-Au deposit, comprises Al-undepleted peridotitic komatiites, pyroxenitic komatiites, ultramafic cumulates, and intrusive mafic to felsic rocks. These units show evidence of a mantle plume origin and were emplaced in a continental rift setting. U-Pb zircon ages from intrusive and extrusive units constrain the timing of a major magmatic event to 2.94-2.91 Ga, placing the Macequece Formation within the Lower Greenstones of the Bulawayan Supergroup. A major unconformity separates it from the overlying M'Beza-Vengo Formation, recording a temporal gap of ca. 170 Ma and indicating a craton-wide tectonic transition. Additional Neoproterozoic ages (578-846 Ma) reveal overprinting by later tectono-thermal events, including those associated with the Rodinia breakup and the Pan-African orogeny.

Sulfur isotope compositions of sulfides (δ³⁴S: -0.40‰ to +4.02‰) support a dominantly magmatic source, with minor crustal input. Carbon and oxygen isotope ratios in gangue carbonates (δ¹³C: -9.61‰ to -4.32‰; δ¹⁸O: +4.93‰ to +13.05‰) define multiple stages of fluid-rock interaction, from early carbonate alteration of komatiites to later Cu-Au mineralization. These isotope signatures reflect the involvement of hybrid fluids of predominantly magmatic-hydrothermal character and with minor crustal contributions.

Mineral chemistry data further support this model. Chalcopyrite trace element patterns are consistent with medium-temperature hydrothermal systems (e.g., IOCG, skarn), while Ni enrichment indicates interaction with komatiitic host rocks. Pyrite compositions define two groups with contrasting Co/Ni ratio, pointing to mixing between magmatic and metamorphic fluid sources. Sphalerite Fe content yields ore formation temperatures between 280 and 335 °C, consistent with low- to medium-temperature hydrothermal systems and overlapping withorogenic gold deposits.

Altogether, the data supports a hybrid genetic model for the Mundonguara deposit, involving dominantly magmatic-hydrothermal fluids, minor metamorphic contributions, and metal input from both mantle-derived and local ultramafic rocks. The system differs from classical IOCG-and orogenic gold deposits and is best interpreted as an orogenic gold deposit with atypical metal association hosted in komatiitic rocks.

Place, publisher, year, edition, pages
Luleå: Luleå University of Technology, 2025.
Series
Doctoral thesis / Luleå University of Technology, ISSN 1402-1544
National Category
Geology
Research subject
Ore Geology
Identifiers
URN: urn:nbn:se:ltu:diva-114370ISBN: 978-91-8048-875-4 (print)ISBN: 978-91-8048-876-1 (electronic)OAI: oai:DiVA.org:ltu-114370DiVA, id: diva2:1990473
Public defence
2025-10-30, C305, Luleå University of Technology, Luleå, 09:00 (English)
Opponent
Supervisors
Funder
Sida - Swedish International Development Cooperation AgencyAvailable from: 2025-08-20 Created: 2025-08-20 Last updated: 2025-10-21Bibliographically approved
List of papers
1. Lithogeochemistry and origin of the komatiites from Mundonguara mine in the Manica greenstone belt, Mozambique
Open this publication in new window or tab >>Lithogeochemistry and origin of the komatiites from Mundonguara mine in the Manica greenstone belt, Mozambique
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2025 (English)In: Journal of African Earth Sciences, ISSN 1464-343X, E-ISSN 1879-1956, Vol. 223, article id 105494Article in journal (Refereed) Published
Abstract [en]

The Manica greenstones belt in western Mozambique constitutes the eastern extension of the Odzi-Mutare greenstone belt in Zimbabwe that is one of several Archean greenstone belts within the Zimbabwe Craton. These greenstones are in Mozambique constituting the Manica Group and are subdivided in two main lithostratigraphic units: The Macequece Formation and the Vengo Formation. The former is hosting the Mundonguara Cu-Au mine and is dominated by volcanic rocks, while the younger Vengo Formation is consisting of epiclastic sedimentary rocks. This paper considers the character and origin of the ultramafic, mafic, and felsic rocks within the Macequece Formation. They include peridotitic komatiite, pyroxenitic komatiite, komatiitic cumulate rocks, gabbroic dykes, rhyolitic units, and a granitic rock intruding the komatiites. Samples of these rocks have been collected from outcrops and drill cores and are investigated through petrographic studies of thin sections and whole rock geochemistry including major and trace elements to interpret the geological environment and tectonic setting.The supracrustal rocks are metamorphosed to greenschist facies and the komatiites consists of varying proportions of serpentine, talc, chlorite, and amphibole. Primary features are partly preserved, with spinifex, vesicular, and cumulate textures. The komatiites are variously affected by carbonate alteration and deformation and the rhyolitic rocks are mostly strongly silicified. The komatiites are of the Al-undepleted type, with a MgO content of 25–45 wt %, while the mafic intrusions are tholeiitic in character, varying from gabbronorite to diorite in composition. Trace element diagrams used for interpretation of tectonic setting gives ambiguous results that could be an effect of crustal contamination of the ultramafic and mafic magmas. Using diagrams less sensitive to crustal contamination suggests the mafic and ultramafic magma to have a mantle source Minor rhyolitic rocks are chemically similar to granitic rocks intruding the komatiites and might have a mainly crustal magma source. This suggested that the Manica greenstones belt formed from magmas generated by mantle plume activity in a continental rift setting and were deposited on older Archean continental crust. These rocks are tentatively correlated with the Bends or Brookland formations belonging to the 2.9–2.8 Ga Mtshingwe Group in the Belingwe greenstone belts in Zimbabwe.

Place, publisher, year, edition, pages
Elsevier, 2025
Keywords
Peridotitic komatiite, Pyroxenitic komatiite, Cumulate rocks, Archean greenstone belts, Manica greenstone belt, Zimbabwe craton
National Category
Geology Geochemistry
Research subject
Ore Geology
Identifiers
urn:nbn:se:ltu:diva-110996 (URN)10.1016/j.jafrearsci.2024.105494 (DOI)001724431500001 ()2-s2.0-85210694642 (Scopus ID)
Funder
Sida - Swedish International Development Cooperation Agency, 51140073
Note

Validerad;2025;Nivå 2;2025-03-20 (u4);

Fulltext license: CC BY

Available from: 2024-12-10 Created: 2024-12-10 Last updated: 2026-05-06Bibliographically approved
2. Geochronology of mafic and felsic rocks at the Mundonguara Mine: Insights into the chronostratigraphy of Archean greenstones within the Zimbabwe Craton
Open this publication in new window or tab >>Geochronology of mafic and felsic rocks at the Mundonguara Mine: Insights into the chronostratigraphy of Archean greenstones within the Zimbabwe Craton
(English)Manuscript (preprint) (Other academic)
National Category
Other Earth Sciences
Research subject
Ore Geology
Identifiers
urn:nbn:se:ltu:diva-114366 (URN)
Funder
Sida - Swedish International Development Cooperation Agency
Available from: 2025-08-20 Created: 2025-08-20 Last updated: 2025-10-21Bibliographically approved
3. Sulfur, carbon and oxygen isotope constraints on the origin of the Mundonguara Cu-Au deposit, Manica, Mozambique
Open this publication in new window or tab >>Sulfur, carbon and oxygen isotope constraints on the origin of the Mundonguara Cu-Au deposit, Manica, Mozambique
(English)Manuscript (preprint) (Other academic)
National Category
Geology
Research subject
Ore Geology
Identifiers
urn:nbn:se:ltu:diva-114368 (URN)
Funder
Sida - Swedish International Development Cooperation Agency
Available from: 2025-08-20 Created: 2025-08-20 Last updated: 2025-10-21Bibliographically approved
4. Mineral chemistry constraints on a hybrid magmatic-hydrothermal and metamorphic fluid origin for the Mundonguara Cu–Au deposit, Manica Greenstone Belt, Mozambique
Open this publication in new window or tab >>Mineral chemistry constraints on a hybrid magmatic-hydrothermal and metamorphic fluid origin for the Mundonguara Cu–Au deposit, Manica Greenstone Belt, Mozambique
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(English)Manuscript (preprint) (Other academic)
National Category
Geology
Research subject
Ore Geology
Identifiers
urn:nbn:se:ltu:diva-114367 (URN)
Funder
Sida - Swedish International Development Cooperation Agency
Available from: 2025-08-20 Created: 2025-08-20 Last updated: 2025-10-21

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