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On aluminium transfer at high temperature – Mechanisms and control
Luleå University of Technology, Department of Engineering Sciences and Mathematics, Machine Elements.ORCID iD: 0000-0002-6513-3504
2025 (English)Doctoral thesis, comprehensive summary (Other academic)Alternative title
Om aluminiumöverföring vid hög temperatur – Mekanismer och kontroll (Swedish)
Abstract [en]

Global warming is a main concern for everyone, and it also affects every industry sectors. The current need for reducing greenhouse gas (GHG) emissions calls for a wide range of measures where technological development and innovations play an important role. Domestic transportation represents around a fourth of the total greenhouse gases emissions in the EU, which leads to a need for solutions regarding these new regulations.

Lightweighting vehicles is a solution for reducing fuel consumption as well as CO2 emissions. High strength aluminium alloys show a promising compromise between weight reduction while allowing for passenger safety thanks to their energy absorption capacity and high strength. Aluminium alloys are already employed for cosmetic parts in vehicles, enabling considerable weight reduction, but implementing high strength Al structural parts in the body in white comes with many tribological challenges.

These alloys need to be formed at high temperatures due to strengthening process and poor room temperature formability. However, they are prone to severe adhesion which to date has prevented their mass production. To date, working solutions for preventing adhesion in forming operations at high temperature have not been developed.

This thesis summarises the work on the subject that has been carried out over four years. This summary encompasses the screening and validation in lab-scale experiments of various solutions (lubricants, surface engineering) for the hot aluminium-tool steel contact. The main mechanisms responsible for friction and material transfer at high temperature were studied. Assessment of promising methods (lubricants, surface engineering) to effectively hinder and prevent material transfer were characterised.

The main results in this thesis show that: lubricants and surface engineering techniques must be simultaneously adjusted for effective prevention of aluminium transfer. Roughness of the tool steel plays two adverse roles in the contact: a detrimental one when leading to ploughing of the Al surface and a beneficial one in active retention of lubricants. Various lubricant formulations show promising results for the hot forming applications and should be further researched in real contact conditions.

Place, publisher, year, edition, pages
Luleå tekniska universitet, 2025.
Series
Doctoral thesis / Luleå University of Technology 1 jan 1997 → …, ISSN 1402-1544
Keywords [en]
tribology, hot forming, high temperature, aluminium, tool steel, PVD coating, high temperature lubricant, galling
National Category
Other Mechanical Engineering
Research subject
Machine Elements
Identifiers
URN: urn:nbn:se:ltu:diva-114625ISBN: 978-91-8048-895-2 (print)ISBN: 978-91-8048-896-9 (electronic)OAI: oai:DiVA.org:ltu-114625DiVA, id: diva2:1997153
Public defence
2025-11-17, E231, Lulea University of Technology, Luleå, 09:00 (English)
Opponent
Supervisors
Projects
https://www.vinnova.se/p/tribologi-i-varmformning-av-aluminium/https://www.vinnova.se/en/p/lulea-university-of-technology-and-swedish-industry-group-for-high-performance-tribology-research/https://www.vinnova.se/en/p/advanced-light-weight-design-by-hot-formed-aluminium/
Funder
Vinnova, 2019-02621Available from: 2025-09-11 Created: 2025-09-11 Last updated: 2025-10-27Bibliographically approved
List of papers
1. Influence of Lubrication, Tool Steel Composition and Topography on the High Temperature Tribological Behaviour of Aluminium
Open this publication in new window or tab >>Influence of Lubrication, Tool Steel Composition and Topography on the High Temperature Tribological Behaviour of Aluminium
2021 (English)In: Friction, ISSN 2223-7690, E-ISSN 2223-7704, Vol. 9, no 1, p. 155-168Article in journal (Refereed) Published
Abstract [en]

The use of high strength aluminium alloys, such as 6XXX and 7XXX series, is continuously increasing for automotive applications in view of their good strength-to-weight ratio. Their formability at room temperature is limited and they are thus often formed at high temperatures to enable production of complex geometries. Critical challenges during hot forming of aluminium are the occurrence of severe adhesion and material transfer onto the forming tools. This negatively affects the tool life and the quality of the produced parts. In general, the main mechanisms involved in the occurrence of material transfer of aluminium alloys at high temperature are still not clearly understood. Therefore, this study is focussed on understanding of the friction and wear behaviour during interaction of Al6016 alloy and three different tool steels in as-received and polished state. The tribotests were carried out under dry and lubricated conditions, with two distinct lubricants, using a reciprocating friction and wear tester. The worn surfaces were analysed using scanning electron microscopy (SEM) and energy dispersive X-ray spectroscopy (EDS). The results showed a high dependence of friction and wear behaviour on the tool steel roughness as well as on the stability of the lubricant films. Tribolayers were found to develop in the contact zone and their capacity to improve the tribological behaviour is seen to be drastically impacted by the surface roughness of the tool steel. When the tribolayers failed, severe adhesion took place and led to high and unstable friction as well as material transfer to the tool steel.

Place, publisher, year, edition, pages
Springer, 2021
Keywords
friction, wear, high temperature tribology, aluminium, lubrication, tribolayer
National Category
Other Mechanical Engineering
Research subject
Machine Elements
Identifiers
urn:nbn:se:ltu:diva-77692 (URN)10.1007/s40544-020-0371-6 (DOI)000565156500001 ()2-s2.0-85090143600 (Scopus ID)
Note

Validerad;2020;Nivå 2;2020-10-08 (alebob)

Available from: 2020-02-13 Created: 2020-02-13 Last updated: 2025-10-22Bibliographically approved
2. High temperature tribological behaviour of PVD coated tool steel and aluminium under dry and lubricated conditions
Open this publication in new window or tab >>High temperature tribological behaviour of PVD coated tool steel and aluminium under dry and lubricated conditions
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2021 (English)In: Friction, ISSN 2223-7690, E-ISSN 2223-7704, Vol. 9, no 4, p. 802-821Article in journal (Refereed) Published
Abstract [en]

Aluminium alloys are commonly used as lightweight materials in the automotive industry. This non-ferrous family of metallic alloys offers a high versatility of properties and designs. To reduce weight and improve safety, high strength-to-weight ratio alloys (e.g. 6XXX and 7XXX), are increasingly implemented in vehicles. However, these alloys exhibit low formability and experience considerable springback during cold forming, and are therefore hot formed. During forming, severe adhesion (i.e. galling) of aluminium onto the die surface takes place. This phenomenon has a detrimental effect on the surface properties, geometrical tolerances of the formed parts and maintenance of the dies. The effect of surface engineering as well as lubricant chemistry on galling has not been sufficiently investigated. Diamond-like carbon (DLC) and CrN physical vapour deposition (PVD) coated steel have been studied to reduce aluminium transfer. However, the interaction between lubricants and PVD coatings during hot forming of aluminium alloys is not yet fully understood. The present study thus aims to characterise the high temperature tribological behaviour of selected PVD coatings and lubricants during sliding against aluminium alloy. The objectives are to first select promising lubricant-coating combinations and then to study their tribological response in a high-temperature reciprocating friction and wear tester. Dry and lubricated tests were carried out at 300 °C using a commercial polymer lubricant. Tests using DLC, CrN, CrTiN, and CrAlN coated tool steel were compared to uncoated tool steel reference tests. The initial and worn test specimen surfaces were analysed with a 3-dimensional (3D) optical profiler, scanning electron microscope (SEM) and energy dispersive X-ray spectroscope (EDS) as to understand the wear mechanisms. The results showed formation of tribolayers in the contact zone, reducing both friction and wear. The stability of these layers highly depends on both the coatings’ roughness and chemical affinity towards aluminium. The DLC and CrN coatings combined with the polymer lubricant were the most effective in reducing aluminium transfer.

Place, publisher, year, edition, pages
Springer, 2021
Keywords
high temperature tribology, aluminium, lubrication, physical vapour deposition (PVD) coatings, material transfer, adhesion
National Category
Other Mechanical Engineering
Research subject
Machine Elements
Identifiers
urn:nbn:se:ltu:diva-81956 (URN)10.1007/s40544-020-0435-7 (DOI)000595394000005 ()2-s2.0-85097031328 (Scopus ID)
Funder
Vinnova, 2015-01352
Note

Validerad;2021;Nivå 2;2021-04-13 (alebob);

Finansiär: RISE

Available from: 2020-12-11 Created: 2020-12-11 Last updated: 2025-10-22Bibliographically approved
3. Effect of Surface Engineered Tool Steel and Lubrication on Aluminium Transfer at High Temperature
Open this publication in new window or tab >>Effect of Surface Engineered Tool Steel and Lubrication on Aluminium Transfer at High Temperature
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2021 (English)In: Wear, ISSN 0043-1648, E-ISSN 1873-2577, Vol. 477, article id 203879Article in journal (Refereed) Published
Abstract [en]

Hot stamping is characterised by severe contact conditions, especially when forming aluminium components. In order to improve the tool lifetime, process economy, and component quality, understanding the initiation mechanisms behind aluminium transfer onto the tool surface at high temperatures is critical. To date, the tribological interaction between tools and aluminium sheets at high temperature has received limited attention. Lubricants, combined with surface engineering techniques (e.g. coatings, nitriding and surface topography control), show great potential for reducing the severity of material transfer at high temperatures. However, there is still, limited knowledge about their interaction and performance in this tribological context. In this study, high temperature tribological tests were carried out to characterise the synergetic effects of surface coatings/treatments with and without lubrication on friction and wear. A commercially available lubricant was evaluated when used in combination with uncoated, nitrided and CrWN- or DLC ta-C-based PVD coated tool steel. The tests were carried out on a hot strip drawing tribometer, employing an open contact configuration representative of the hot stamping contact conditions at two different temperatures. The counter-material was a 6082 aluminium alloy, heated up following a thermal cycle relevant for the hot stamping process. The results showed that the tribological response was highly dependent on the retention of the lubricant in the contact and the type of surface modification technique. The results show that bonding of the lubricant to the tool surface is critical. In the case of lubricant failure, severe adhesive wear and aluminium transfer onto the tool surface occurred, correlated with an increase in friction. The use of different surface engineering methods led to different results: lower friction levels could be reached when combining use of lubricant and PVD coatings compared to using uncoated or plasma nitrided tool steel. In this study, the best combination to minimise aluminium transfer and friction is the association of the lubricant with CrWN PVD coating in this study.

Place, publisher, year, edition, pages
Elsevier, 2021
Keywords
hot stamping, aluminium, lubrication, PVD coating
National Category
Other Mechanical Engineering
Research subject
Machine Elements
Identifiers
urn:nbn:se:ltu:diva-83720 (URN)10.1016/j.wear.2021.203879 (DOI)000681184400002 ()2-s2.0-85104145312 (Scopus ID)
Conference
23rd International Conference on Wear of Materials, Online, 26-29 April, 2021
Funder
Vinnova, 2017-05229
Note

Godkänd;2021;Nivå 0;2021-08-11 (alebob);Konferensartikel i tidskrift

Available from: 2021-04-16 Created: 2021-04-16 Last updated: 2025-10-21Bibliographically approved
4. Tribological evaluation of different lubricant formulations for hot forming of aluminium
Open this publication in new window or tab >>Tribological evaluation of different lubricant formulations for hot forming of aluminium
Show others...
(English)Manuscript (preprint) (Other academic)
National Category
Other Mechanical Engineering
Research subject
Machine Elements
Identifiers
urn:nbn:se:ltu:diva-114624 (URN)
Projects
https://www.vinnova.se/p/tribologi-i-varmformning-av-aluminium/
Funder
Vinnova
Available from: 2025-09-11 Created: 2025-09-11 Last updated: 2025-10-21Bibliographically approved

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Decrozant-Triquenaux, Justine

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