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From Waste to Resource: Thermal Recycling and Re-Manufacturing of Carbon Fiber Reinforced Polymers
Luleå University of Technology, Department of Engineering Sciences and Mathematics, Material Science.ORCID iD: 0009-0000-1387-4047
2026 (English)Doctoral thesis, comprehensive summary (Other academic)
Abstract [en]

The increasing demand for high-performance materials must be considered within the context of finite resources and growing sustainability challenges. As the availability of raw materials becomes increasingly constrained, it is necessary to consider not only what is consumed, but also how existing materials can be used more efficiently through advances in processing, recycling, and manufacturing. In this context, resource efficiency is no longer limited to reducing consumption; it also involves extending the useful life of materials already extracted from the environment.

One way to achieve this is by recovering and reusing materials at the end of their service life. Rather than being treated as waste, materials can be reintroduced into the value chain through routes that maximize their retained value while minimizing environmental impact. Recycling therefore becomes more than a waste-management strategy; it becomes a means of improving resource efficiency and supporting the transition toward more circular material systems.

Within this framework, recycled carbon fiber (rCF) emerges as a material of growing interest. Recovered from end-of-life composites and manufacturing waste, rCF offers the possibility of retaining much of the value embedded in carbon fibers while avoiding the environmental burden associated with producing virgin carbon fiber (vCF). However, recycling does not reproduce the original material exactly. The recycling process modifies the fibers through thermal exposure, oxidation, and repeated handling, resulting in changes to their structure, surface condition, and performance. Consequently, rCF should not be considered a direct replacement for vCF, but rather a material with its own characteristics, capabilities, and limitations.

The work presented in this thesis demonstrates that carbon fibers can be recovered with high quality through thermal recycling when pyrolysis and oxidation are carefully controlled. The results show that stiffness can be largely preserved, whereas strength is more sensitive to oxidation damage and the accumulation of surface defects. Studies on repeated recycling further reveal that the properties of rCF evolve with recycling history, highlighting the importance of considering recycled fibers as a distinct material system with its own performance window rather than as a degraded version of virgin fibers.

A thorough characterization of recycled fibers is therefore essential. While mechanical properties remain central for structural applications, the performance of rCF cannot be understood solely through stiffness and strength. Surface chemistry, wettability, and fiber–matrix interactions also play a critical role in determining the quality of the composites manufactured from recovered fibers. The findings of this thesis show that recycling affects the fiber surface more significantly than the bulk structure and that these surface modifications strongly influence interfacial behavior. Although re-sizing treatments can improve wettability, they cannot fully compensate for damage introduced during recycling, emphasizing the importance of carefully controlling recycling conditions.

The practical value of rCF ultimately depends on how it is used in new products. Because recycled fibers are typically discontinuous, their most promising applications are found in short-fiber composite systems where the limitations imposed by fiber length are less critical. The manufacturing studies presented in this thesis demonstrate that wet-laid processing provides an effective route for producing homogeneous mats and reproducible laminates from virgin, recycled, and hybrid fiber systems. The resulting composites show that recycled fibers can retain significant stiffness, while hybrid architectures combining virgin and recycled fibers can recover a substantial portion of the strength losses associated with recycling and provide a balance between performance and sustainability.

This thesis lies at the intersection of recycling, characterization, remanufacturing, and environmental assessment. Its overarching objective is to improve the understanding of how recycled carbon fibers can be recovered, characterized, processed, and evaluated to support their integration into more circular and resource-efficient composite systems. The results demonstrate that rCF should not be viewed simply as a lower-performance alternative to virgin carbon fiber, but rather as an emerging material system with its own technical, manufacturing, and sustainability profile. By preserving much of the intrinsic value of carbon fibers while reducing the environmental burden associated with new material production, rCF creates opportunities for new material and product concepts that balance performance, resource efficiency, and sustainability. Ultimately, the findings show that the successful use of recycled carbon fibers depends not only on how closely they replicate virgin materials, but also on understanding and exploiting their own unique capabilities, limitations, and potential contributions to future composite design.

Place, publisher, year, edition, pages
Luleå: Luleå University of Technology, 2026.
Series
Doctoral thesis / Luleå University of Technology, ISSN 1402-1544
Keywords [en]
Carbon Fiber Reinforced Polymers (CFRP), Thermal Recycling, Recycled Carbon Fibers (rCF), Composite Re-Manufacturing, Circular Economy
National Category
Composite Science and Engineering
Research subject
Polymeric Composite Materials
Identifiers
URN: urn:nbn:se:ltu:diva-119839ISBN: 978-91-8142-138-5 (print)ISBN: 978-91-8142-139-2 (electronic)OAI: oai:DiVA.org:ltu-119839DiVA, id: diva2:2103168
Public defence
2026-11-12, E632, Luleå University of Technology, Luleå, 10:00 (English)
Opponent
Supervisors
Available from: 2026-09-21 Created: 2026-09-21 Last updated: 2026-10-15Bibliographically approved
List of papers
1. The impact of thermal treatment parameters on the preservation of carbon fiber mechanical properties after reclamation
Open this publication in new window or tab >>The impact of thermal treatment parameters on the preservation of carbon fiber mechanical properties after reclamation
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2024 (English)In: Current Research in Green and Sustainable Chemistry, E-ISSN 2666-0865, Vol. 9, article id 100431Article in journal (Refereed) Published
Abstract [en]

Carbon fiber, despite its exceptional properties, remains underutilized due to monetary and environmental concerns. Concurrently, the imminent challenge associated with rising quantities of End-of-Life CFRP (carbon fiber reinforced polymer) demands the further development of recycling strategies. This study focuses on optimizing the recycling process parameters of pyrolysis and oxidation thermal treatment to maximize the retention of mechanical properties in the recycled fibers in the shortest process time. To assess the result of the pyrolysis, single fiber tensile tests were executed to measure strength and stiffness. Additionally, microscopy and spectroscopy studies were carried out to evaluate fiber geometry as well as surface quality. At the laboratory scale, experiments demonstrated that the combination of pyrolysis and oxidation yields clean, reusable fibers with mechanical properties suitable for secondary applications. The influence of various treatment parameters on the strength and stiffness of the recycled fibers was explored, establishing a clear correlation. The outcome is a set of optimized parameters that contribute to mechanical property retention, including a novel recycling method that allows for reduced processing times, as short as 10 min. This work paves the way for a more eco-friendly and cost-effective approach to harnessing the potential of carbon fiber in a wide range of applications while mitigating environmental concerns associated with landfill disposal.

Place, publisher, year, edition, pages
Elsevier B.V., 2024
Keywords
Pyrolysis, Carbon fiber, Composite recycling, CFRP, Polymer composites, Sustainability
National Category
Materials Engineering Chemical Engineering
Research subject
Polymeric Composite Materials; Energy Engineering; Experimental Physics
Identifiers
urn:nbn:se:ltu:diva-110652 (URN)10.1016/j.crgsc.2024.100431 (DOI)2-s2.0-85207274252 (Scopus ID)
Note

Validerad;2024;Nivå 1;2024-11-26 (sarsun);

Full text license: CC BY 4.0;

Available from: 2024-11-06 Created: 2024-11-06 Last updated: 2026-09-21Bibliographically approved
2. Evolution of carbon fiber properties during repetitive recycling via pyrolysis and partial oxidation
Open this publication in new window or tab >>Evolution of carbon fiber properties during repetitive recycling via pyrolysis and partial oxidation
2025 (English)In: Carbon Trends, E-ISSN 2667-0569, Vol. 18, article id 100438Article in journal (Refereed) Published
Abstract [en]

The potential of recycling carbon fiber reinforced polymers (CFRP) as a sustainable solution for waste management is yet to be fully understood. This study reports on the evolution of mechanical, and chemical properties of reclaimed carbon fibers when recycled multiple times via pyrolysis and partial oxidation. The performed work aims at filling the knowledge gap related to repetitive recycling when moving towards a circular flow of resources. A recycling process existing at industrial scale is used to ensure the relevance and usefulness of the results in the current industry scene. Two sets of three identical model composites are recycled using distinct recycling parameters, and their properties are characterized at the end of each recycling cycle. Results show that recycling can lead to an increase in stiffness but can have a negative impact on strength of recovered fibers. Mechanical behaviour shows recovered fibers suitable for secondary applications with medium performance requirements after two recycling cycles. The findings highlight the importance of understanding the material properties evolution during recycling processes. This research contributes to the development of sustainable waste management strategies and a more environmentally friendly future.

Place, publisher, year, edition, pages
Elsevier, 2025
Keywords
Pyrolysis, Carbon fiber, Composites recycling, CFRP, Polymer composites, Sustainability
National Category
Construction Management Environmental Management
Research subject
Energy Engineering; Experimental Physics; Polymeric Composite Materials
Identifiers
urn:nbn:se:ltu:diva-111158 (URN)10.1016/j.cartre.2024.100438 (DOI)001388520900001 ()2-s2.0-85211744749 (Scopus ID)
Note

Validerad;2025;Nivå 1;2025-01-01 (signyg);

Full text license: CC BY

Available from: 2024-12-30 Created: 2024-12-30 Last updated: 2026-09-21Bibliographically approved

Open Access in DiVA

The full text will be freely available from 2026-10-22 09:00
Available from 2026-10-22 09:00

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Corvo Alguacil, Marina

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7891011121310 of 24
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Citation style
  • apa
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Language
  • de-DE
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Output format
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