This paper proposes a new prediction model for stable control of mobile robot based on chaotic neural networks. Programming mobile robots can be long and difficult task. In this study, we intend to demonstrate the chaotic learning algorithm to improve neural networks' learning efficiency and obtain better prediction. In order to validate the prediction performance of recurrent neural networks, a novel stimulation study and analysis paradigm has been done on the practical data. Finally, through computer simulations, we demonstrate the effectiveness and stability of the proposed controller according to changed working conditions