Change search
CiteExportLink to record
Permanent link

Direct link
Cite
Citation style
  • apa
  • ieee
  • modern-language-association-8th-edition
  • vancouver
  • Other style
More styles
Language
  • de-DE
  • en-GB
  • en-US
  • fi-FI
  • nn-NO
  • nn-NB
  • sv-SE
  • Other locale
More languages
Output format
  • html
  • text
  • asciidoc
  • rtf
Line shape parameters of the first pure rotational R lines of CO in helium baths down to a few kelvins
University Rennes, CNRS, IPR (Institut de Physique de Rennes)-UMR 6251, F-35000 Rennes, France.ORCID iD: 0000-0002-1279-8588
University Rennes, CNRS, IPR (Institut de Physique de Rennes)-UMR 6251, F-35000 Rennes, France.ORCID iD: 0000-0003-2520-7502
University Rennes, CNRS, IPR (Institut de Physique de Rennes)-UMR 6251, F-35000 Rennes, France.ORCID iD: 0000-0003-0066-3376
Luleå University of Technology, Department of Engineering Sciences and Mathematics, Material Science.ORCID iD: 0000-0002-7629-0169
2025 (English)In: Journal of Chemical Physics, ISSN 0021-9606, E-ISSN 1089-7690, Vol. 162, no 9, article id 094305Article in journal (Refereed) Published
Abstract [en]

Close coupling calculations of line shape parameters have been performed for the first pure rotational R0(j = 0–4) lines of CO in helium baths at various temperatures. Besides the usual Lorentzian widths and shifts, we provide the complex Dicke parameters as well as the double power law temperature representation of all four parameters. In addition, we study the speed dependence of these parameters. The R0(0) and R0(1) theoretical thermally averaged collisional widths and shifts between 500 and about 15 K are in excellent agreement with the values reported in the literature. Below this temperature range, we confirm the persistent substantial disagreement that exists since 1985 between experimental and theoretical values. We thus focus on this regime, which is important for astrophysical applications, and we discuss various beyond-Voigt effects at low temperatures to try to understand this mismatch. We show that such mechanisms do not allow experimental widths and shifts to be reconciled with those from theory.  

Place, publisher, year, edition, pages
American Institute of Physics (AIP), 2025. Vol. 162, no 9, article id 094305
National Category
Astronomy, Astrophysics and Cosmology Atom and Molecular Physics and Optics
Research subject
Applied Physics
Identifiers
URN: urn:nbn:se:ltu:diva-112032DOI: 10.1063/5.0253846ISI: 001438181700004PubMedID: 40042372Scopus ID: 2-s2.0-86000345987OAI: oai:DiVA.org:ltu-112032DiVA, id: diva2:1944843
Note

Validerad;2025;Nivå 2;2025-03-17 (u8);

Available from: 2025-03-17 Created: 2025-03-17 Last updated: 2025-10-21Bibliographically approved

Open Access in DiVA

No full text in DiVA

Other links

Publisher's full textPubMedScopus

Authority records

Gustafsson, Magnus

Search in DiVA

By author/editor
Thibault, FranckViel, AlexandraDunseath, Kevin M.Gustafsson, Magnus
By organisation
Material Science
In the same journal
Journal of Chemical Physics
Astronomy, Astrophysics and CosmologyAtom and Molecular Physics and Optics

Search outside of DiVA

GoogleGoogle Scholar

doi
pubmed
urn-nbn

Altmetric score

doi
pubmed
urn-nbn
Total: 52 hits
CiteExportLink to record
Permanent link

Direct link
Cite
Citation style
  • apa
  • ieee
  • modern-language-association-8th-edition
  • vancouver
  • Other style
More styles
Language
  • de-DE
  • en-GB
  • en-US
  • fi-FI
  • nn-NO
  • nn-NB
  • sv-SE
  • Other locale
More languages
Output format
  • html
  • text
  • asciidoc
  • rtf