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Solids and Metals Treatment in Stormwater Control Systems: Laboratory Methods and Field Applications
Luleå University of Technology, Department of Civil, Environmental and Natural Resources Engineering, Architecture and Water.ORCID iD: 0000-0003-2186-453X
2025 (English)Doctoral thesis, comprehensive summary (Other academic)Alternative title
Behandling av partiklar och metaller från dagvatten : Laboratoriemetoder och utvärdering i fält (Swedish)
Abstract [en]

Suspended solids and metals are recognized as key pollutants in stormwater runoff. Thus, stormwater treatment systems have become increasingly vital components of urban infrastructure, playing a key role in reducing pollutant loads entering receiving water bodies. This thesis focuses on evaluating the treatment of solids and metals in stormwater systems, through both controlled laboratory experiments and field-based assessments.

Synthetic stormwater is widely used as a substitute for real runoff in both laboratory and field experiments. Its main advantages are the ability to control influent quality and quantity, as well as to improve the repeatability of experiments. However, no standardized formulation currently exists. A critical review which was conducted to evaluate the use of synthetic stormwater in experimental stormwater research revealed substantial variation among studies. Based on these findings, a narrower set of pollutant concentration ranges was suggested to enhance the comparability, repeatability, and reproducibility of future experiments.

The experiments evaluating design parameters of a suggested Bottom Grid Structure demonstrated that hydraulic modifications of settling areas in the stormwater treatment systems could enhance sedimentation, though the results were not directly scalable to field conditions. Among the variable factors in the experiment, inclined cell walls of the Bottom Grid Structure had the strongest effect, increasing sedimentation by up to 22% compared to control runs. Column studies showed peat and bark to be the most effective filter materials for dissolved Zn removal, although the use of peat is associated with significant drawbacks regarding other pollutants and uncertainties about its long-term performance. Evaluated zeolite filter system treating copper roof runoff achieved high removal of Cu (49–85%) and Zn (48–94%) but exhibited declining performance over time.

A field study examining the performance of two EcoVault facilities revealed relatively low TSS removal (40–46%), substantially below both previous EcoVault studies and manufacturer claims. Dissolved metals were inadequately removed, likely due to elevated hydraulic loading rates and progressive filter clogging. Sedimentation was identified as the dominant treatment mechanism, while the zeolite filter cassettes provided negligible additional metal removal.

The field experiments underscored the importance of site-specific design of stormwater treatment systems, especially in cases where the influent is dominated by dissolved metals. Despite their limited performance, underground treatment systems remain a practical solution in densely built urban environments where surface space is constrained. However, targeted design improvements are essential to enhance treatment efficiency. Furthermore, comparisons with commonly used models for the prediction of the performance of stormwater treatment systems revealed that actual removal rates were approximately 50% lower than estimated values, highlighting the need for additional field-based data to improve model calibration and support the development of more reliable and context-sensitive stormwater treatment strategies.

Place, publisher, year, edition, pages
Luleå: Luleå University of Technology, 2025.
Series
Doctoral thesis / Luleå University of Technology, ISSN 1402-1544
Keywords [en]
Stormwater treatment, Solids, Metals, Urban Water Engineering
National Category
Water Engineering
Research subject
Urban Water Engineering
Identifiers
URN: urn:nbn:se:ltu:diva-114355ISBN: 978-91-8048-873-0 (print)ISBN: 978-91-8048-874-7 (electronic)OAI: oai:DiVA.org:ltu-114355DiVA, id: diva2:1989960
Public defence
2025-09-26, E632, Luleå University of Technology, Luleå, 09:00 (English)
Opponent
Supervisors
Available from: 2025-08-19 Created: 2025-08-19 Last updated: 2025-10-21Bibliographically approved
List of papers
1. Use of synthetic stormwater in the experiments: a review of practices
Open this publication in new window or tab >>Use of synthetic stormwater in the experiments: a review of practices
(English)Manuscript (preprint) (Other academic)
National Category
Water Engineering
Research subject
Urban Water Engineering
Identifiers
urn:nbn:se:ltu:diva-114352 (URN)
Available from: 2025-08-19 Created: 2025-08-19 Last updated: 2025-10-21Bibliographically approved
2. Synthetic stormwater for laboratory testing of filter materials
Open this publication in new window or tab >>Synthetic stormwater for laboratory testing of filter materials
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2023 (English)In: Environmental technology, ISSN 0959-3330, E-ISSN 1479-487X, Vol. 44, no 11, p. 1600-1612Article in journal (Refereed) Published
Abstract [en]

Synthetic stormwater was tested to determine the ageing effects on dissolved metal concentrations and used in a column experiment to determine efficiency of four different filter materials (milkweed, bark, peat, polypropylene) in removing total and dissolved metals. Synthetic stormwater was created by adding metal salts, oil and collected stormwater sediment to tap water. Two ageing experiments were performed to determine the change of synthetic stormwater quality over time. One experiment lasted for 11 days and another focused on rapid concentration changes one day after preparation. The one-day ageing experiment showed rapid decrease in dissolved concentration of certain metals, specifically Cu. To consider this change, correction coefficients for each metal were developed and used to estimate the average dissolved metal concentration in the synthetic stormwater during the experiment to determine filter treatment efficiency. During the 11-day experiment on metal concentrations, no noticeable quality changes were observed for at least six days after the preparation of synthetic stormwater. Furthermore, a column experiment was run with duplicate filter columns. Inflow and outflow samples were analysed for total and dissolved metals, turbidity, particle size distribution, and pH. High removal of total metal concentrations was noticed in all tested filter media (58-94%). Dissolved metal concentration removal varied among different filter media. In general, columns with bark and peat media were able to treat dissolved metals better than polypropylene and milkweed. The level of treatment of dissolved metals between the different filter media columns were bark > peat > milkweed > polypropylene.

Place, publisher, year, edition, pages
Taylor & Francis, 2023
Keywords
stormwater filters, column test, metals, sediment, stormwater ageing
National Category
Water Engineering
Research subject
Urban Water Engineering; Centre - Centre for Stormwater Management (DRIZZLE)
Identifiers
urn:nbn:se:ltu:diva-83876 (URN)10.1080/09593330.2021.2008516 (DOI)000733679200001 ()34839790 (PubMedID)2-s2.0-85121767957 (Scopus ID)
Note

Validerad;2023;Nivå 2;2023-06-30 (joosat);

Artikeln har tidigare förekommit som manuskript i avhandling.

Licens fulltext: CC BY-NC-ND License

Available from: 2021-04-21 Created: 2021-04-21 Last updated: 2025-10-21Bibliographically approved
3. Performance of a Zeolite Filter treating Copper Roof Runoff
Open this publication in new window or tab >>Performance of a Zeolite Filter treating Copper Roof Runoff
2022 (English)In: Urban Water Journal, ISSN 1573-062X, E-ISSN 1744-9006, Vol. 19, no 5, p. 499-508Article in journal (Refereed) Published
Abstract [en]

Copper is a common roofing material used in urban environments, yet it poses a threat to the ecosystem. Space requirements for stormwater treatment in urban areas are often problematic. This study investigated the treatment efficiency of a filter system containing zeolite as filter medium and treatment of copper roof runoff in field conditions. Emphasis was placed on copper and zinc treatment, while the release of sodium and aluminium was also evaluated. The filter system was monitored over a period of 16 months (7 sampling events). The filter reduced the total and dissolved copper by 52–82% and 48–85%, respectively. Although the average observed treatment efficiency of copper and zinc was high, considerable decline in filter efficiency was noticed, indicating potential saturation of the filter medium. Moreover, the copper concentrations in the outlet were still high, 350–600 μg/l, and significantly higher than the concentrations recommended by the relevant authorities.

Place, publisher, year, edition, pages
Taylor & Francis, 2022
Keywords
Urban water, stormwater treatment, zeolite, copper, zinc
National Category
Water Engineering
Research subject
Urban Water Engineering; Centre - Centre for Stormwater Management (DRIZZLE)
Identifiers
urn:nbn:se:ltu:diva-83875 (URN)10.1080/1573062X.2022.2031230 (DOI)000763240800001 ()2-s2.0-85126058681 (Scopus ID)
Funder
Vinnova, DRIZZLE – Centre for Stormwater Management (grant no.-2016–05176)
Note

Validerad;2022;Nivå 2;2022-06-02 (sofila);

Funder: Swedish Water and Wastewater Association; Swedish Innovation Agency (grant no. 2016–20075)

Available from: 2021-04-21 Created: 2021-04-21 Last updated: 2025-10-21Bibliographically approved
4. Enhancing stormwater sediment settling at detention pond inlets by a bottom grid structure (BGS)
Open this publication in new window or tab >>Enhancing stormwater sediment settling at detention pond inlets by a bottom grid structure (BGS)
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2020 (English)In: Water Science and Technology, ISSN 0273-1223, E-ISSN 1996-9732, Vol. 81, no 2, p. 274-282Article in journal (Refereed) Published
Abstract [en]

Stormwater sediments of various sizes and densities are recognised as one of the most important stormwater quality parameters that can be conventionally controlled by settling in detention ponds. The bottom grid structure (BGS) is an innovative concept proposed in this study to enhance removal of stormwater sediments entering ponds and reduce sediment resuspension. This concept was studied in a hydraulic scale model with the objective of elucidating the effects of the BGS geometry on stormwater sediment trapping. Towards this end, the BGS cell size and depth, and the cell cross-wall angle were varied for a range of flow rates, and the sediment trapping efficiency was measured in the model. The main value of the observed sediment trapping efficiencies, in the range from 13 to 55%, was a comparative assessment of various BGS designs. In general, larger cells (footprint 10 × 10 cm) were more effective than the smaller cells (5 × 5 cm), the cell depth exerted small influence on sediment trapping, and the cells with inclined cross-walls proved more effective in sediment trapping than the vertical cross-walls. However, the BGS with inclined cross-walls would be harder to maintain. Future studies should address an optimal cell design and testing in an actual stormwater pond.

Place, publisher, year, edition, pages
London, UK: IWA Publishing, 2020
Keywords
hydraulic scale modelling, sediment settling, sediment trapping efficiency, stormwater ponds
National Category
Water Engineering
Research subject
Urban Water Engineering; Centre - Centre for Stormwater Management (DRIZZLE)
Identifiers
urn:nbn:se:ltu:diva-78470 (URN)10.2166/wst.2020.101 (DOI)000529870200008 ()32333660 (PubMedID)2-s2.0-85084030768 (Scopus ID)
Funder
Swedish Research Council Formas, 2016-20075Swedish Research Council Formas, 2016-01447Vinnova, 2017-04390
Note

Validerad;2020;Nivå 2;2020-05-05 (alebob)

Available from: 2020-04-14 Created: 2020-04-14 Last updated: 2025-10-22Bibliographically approved
5. Field Performance of an EcoVault Facility for Stormwater Quality Treatment
Open this publication in new window or tab >>Field Performance of an EcoVault Facility for Stormwater Quality Treatment
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2026 (English)In: Journal of Sustainable Water in the Built Environment, E-ISSN 2379-6111, Vol. 12, no 1, article id 04025015Article in journal (Refereed) Published
Abstract [en]

As urbanization accelerates, stormwater management in cities has shifted from focusing strictly on water quantity to addressing water quality. Traditionally implemented systems, such as stormwater ponds, while offering effective solutions, often require large land areas to implement, making them impractical for dense urban environments. Underground stormwater systems, like EcoVault, offer a more compact solution; however, they lack scientific studies under real-world conditions to prove their effectiveness in treating pollutants. This study evaluates the treatment performance of two parallel EcoVault systems with the same design, consisting of a sedimentation step and a filtration step. These facilities were retrofitted into two different stormwater sewer networks draining two urban catchments. The systems were assessed for their ability to treat total suspended solids, metals, nutrients, and organic pollutants from urban runoff. Over 15 rain events, the average total suspended solids (TSS) removal rate was 40% for EcoVault A and 46% for EcoVault B. The removal rates for metals varied, with EcoVault B showing better performance for average metal treatment (53% for Cu and 58% for Zn). However, neither EcoVault system removed dissolved metals, often with an increase of dissolved metal concentration in the effluent. The filtration step did not contribute to pollutant treatment, likely due to clogging and high hydraulic loading rates. The study highlighted the potential of underground stormwater treatment in areas with limited space availability, while identifying challenges such as treatment of dissolved pollutants.

Place, publisher, year, edition, pages
American Society of Civil Engineers (ASCE), 2026
Keywords
Stormwater treatment, Underground vault system, Total suspended solids, Metal removal, Zeolite
National Category
Water Engineering
Research subject
Urban Water Engineering
Identifiers
urn:nbn:se:ltu:diva-114353 (URN)10.1061/JSWBAY.SWENG-650 (DOI)001656606600001 ()2-s2.0-105019037580 (Scopus ID)
Funder
Vinnova, 2016-05176Vinnova, 2022–03092Swedish Environmental Protection Agency, 05934-22Swedish Water, 21-118
Note

Validerad;2025;Nivå 1;2025-11-11 (u2);

Full text: CC BY license;

This article has previously appeared as a manuscript in a thesis.

Available from: 2025-08-19 Created: 2025-08-19 Last updated: 2026-04-07Bibliographically approved

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